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Angewandte Chemie - International Edition, ISSN 1433-7851, 03/2012, Volume 51, Issue 12, pp. 2981 - 2984
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2011, Volume 50, Issue 52, pp. 12636 - 12638
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2012, Volume 51, Issue 12, pp. 2981 - 2984
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 11/2015, Volume 2015, Issue 31, pp. 5171 - 5187
The reductive complexation of aldimines is one of the promising synthetic tools to obtain titanaaziridines by reaction of the corresponding titanium halides... 
Titanium | C–C coupling | Insertion | Titanaaziridines | Metallacycles | C-C coupling | MECHANISM | INTERCONVERSION | ALKYNES | H ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR | ALLYLIC ALCOHOLS | AMINES | ALPHA-ALKYLATION | CHEMISTRY | HYDROAMINOALKYLATION | METAL-COMPLEXES | Schiff bases | Nitriles | Chemical properties | Aniline | Nitrogen | Carbon-carbon composites | Complexation | Imines | Chemical reactions | Joining | Magnesium | Fragmentation
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 11/2013, Volume 2013, Issue 33, pp. 7583 - 7592
A new (aminopyrimidinato)titanium complex has been synthesised from inexpensive and easily accessible 2‐(tert‐butylamino)pyrimidine and [Ti(NMe2)4] and used as... 
Alk­ynes | Amines | Nitrogen heterocycles | Alkenes | Hydroamination | Titanium | Synthetic methods | Alkynes | ACTIVATION | INTRAMOLECULAR HYDROAMINATION | CHEMISTRY, ORGANIC | IV METAL-COMPLEXES | ALPHA | TITANIUM COMPLEXES | INTERMOLECULAR HYDROAMINATION | ASYMMETRIC HYDROAMINATION | HYDROAMINOALKYLATION | AMINOPYRIDINATO LIGANDS | PRECATALYST | Telomerase | Olefins
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 12/2013, Volume 2013, Issue 35, pp. 8022 - 8032
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2013, Volume 19, Issue 12, pp. 3833 - 3837
Ti me kangaroo down: Conjugated dienes undergo intermolecular hydroaminoalkylation in the presence of Ti catalyst [Ind2TiMe2] (Ind=η5‐indenyl). This new... 
amines | CH activation | homogeneous catalysis | alkenes | titanium | C-H activation | STYRENES | MECHANISM | ALKYLATION | UNACTIVATED OLEFINS | HYDROAMINATION | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | CH activation | NITROGEN ATOM | SECONDARY-AMINES | AMIDATE COMPLEXES | Titanium | Amines | Catalysts | Dienes
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 11/2016, Volume 2016, Issue 33, pp. 5242 - 5249
In titanium imine complexes the ligand can exhibit several bonding modes. While η2‐imine complexes are intermediates in several catalytic transformations and... 
Titanium | Schiff bases | N ligands | Metallacycles | C–N coupling
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2013, Volume 2013, Issue 28, pp. 6291 - 6297
The conversion of methoxyamides based on iminic 1,4‐benzothiazines has led to three different products depending on the substitution pattern. On the one hand,... 
Heterocycles | Schiff bases | Lactams | Electrophilic reactions | Rearrangement | CARBON | SERIES | IMINE | CHEMISTRY, ORGANIC | BETA | Sulfides
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 11/2015, Volume 641, Issue 14, pp. 2543 - 2548
The synthesis of a hexacoordinate triorganoaluminum compound Al(NapSiH)3 (6) (NapSiH = 8‐dimethylsilylnaphthyl) is reported. Three additional Si–H···Al... 
Silane activation | DFT calculation | XRD | Aluminum
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2011, Volume 17, Issue 39, pp. 10979 - 10984
The reactivity of aryl‐substituted stannylenes, Ar2Sn (4), towards silylarenium borates, [R3SiArH][B(C6F5)4] (3), was investigated. The reaction with... 
tin | carbene homologues | cations | X‐ray diffraction | NMR spectroscopy | X-ray diffraction | METALLOCENE POLYMERIZATION CATALYSTS | CRYSTAL-STRUCTURE | CB11ME12 | ETHER COMPLEXES | ISOMER-SHIFTS | DISTANNENE | CHEMISTRY, MULTIDISCIPLINARY | TRIETHYLSILYL CATIONS | SILYL CATION | GERMANIUM | CHEMISTRY
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 05/2015, Volume 54, Issue 10, pp. 4811 - 4820
Whereas reaction of [(η(5)-Cp*)Ti(IV)Cl3](0) (1) with 2 equiv of neutral 2,2'-bipyridine (bpy) and 1.5 equiv of magnesium in tetrahydrofuran affords the... 
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 11/2016, Volume 2016, Issue 33, pp. 5242 - 5249
In titanium imine complexes the ligand can exhibit several bonding modes. While eta super(2)-imine complexes are intermediates in several catalytic... 
Schiff bases | Imines | Chlorides | Nitrogen atoms | Titanium | Ligands | Coordination compounds | Chelates
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 03/2014, Volume 2014, Issue 8, pp. 1289 - 1302
Journal Article
Synlett, ISSN 0936-5214, 09/2012, Volume 23, Issue 14, pp. 2098 - 2102
Abstract A new dinuclear titanium sulfamide complex was synthesized from N , N ′-diphenylsulfamide and Ti(NMe 2 ) 4 and used as a precatalyst for the... 
letter | amines | sulfur | homogeneous catalysis | alkenes | titanium | MECHANISM | INTRAMOLECULAR HYDROAMINATION | CHEMISTRY, ORGANIC | SULFONAMIDE | ALPHA | UNACTIVATED OLEFINS | C-H ACTIVATION | SECONDARY-AMINES | CATALYZED HYDROAMINOALKYLATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2015, Volume 54, Issue 14, pp. 4383 - 4387
Titanaaziridines or η2‐imine titanium complexes are considered key intermediates of the titanium‐catalyzed hydroaminoalkylation of alkenes. Herein, we present... 
titanaaziridine | CH activation | alkene titanium | amine | C-H activation | AGOSTIC INTERACTIONS | IMINES | REACTIVITY | TITANIUM | IN-SITU GENERATION | CHEMISTRY, MULTIDISCIPLINARY | ZIRCONOCENE COMPLEXES | ALKENES | ALLYLIC AMINES | FORMALDEHYDE ANILINE CONDENSATION | CATALYZED HYDROAMINOALKYLATION | Killing | Molecular structure | Alkenes | Ambient temperature | Titanium | Activation | Formations | Stone | Versatility
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 12/2013, Volume 2013, Issue 35, pp. 8022 - 8032
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2013, Volume 135, Issue 28, pp. 10353 - 10361
Journal Article
Chemistry, ISSN 0947-6539, 03/2013, Volume 19, Issue 12, p. 3833
  Ti me kangaroo down: Conjugated dienes undergo intermolecular hydroaminoalkylation in the presence of Ti catalyst [Ind2 TiMe2 ] (Ind=η(5) -indenyl). This new... 
Journal Article
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