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Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 26, pp. 8867 - 8871
One of the major challenges in organic synthesis is the activation or deconstructive functionalization of unreactive C(sp3)–C(sp3) bonds, which requires using... 
piperidines | deconstructive functionalization | pyrrolidinones | Baeyer–Villiger oxidation | nitrogen heterocycles | Baeyer-Villiger oxidation | OXIDATION | ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | Transition metal compounds | Metal catalysts | Chemical industry | Transition metals | Catalysts | Deamination | Metals | Oxidation | Catalysis | Intermediates
Journal Article
Beilstein journal of organic chemistry, ISSN 1860-5397, 2018, Volume 14, Issue 1, pp. 547 - 552
An electrochemical version of the Corey–Winter reaction was developed giving excellent results in aqueous methanol media (MeOH/H O (80:20) with AcOH/AcONa... 
6-pentyl-2H-pyran-2-ones | Electrosynthesis | Reduction | Thiocarbonates | Corey-Winter reaction | electrosynthesis | TRICHODERMA | CHEMISTRY, ORGANIC | thiocarbonates | reduction | ORGANIC ELECTROSYNTHESIS | Electrodes | Temperature requirements | Winter | Metabolites | Efficiency | Silver chloride | Voltammetry | High temperature | Carbon | Methanol | Corey–Winter reaction
Journal Article
Molecules, ISSN 1420-3049, 03/2017, Volume 22, Issue 3, p. 361
... *, Jacinto Sandoval-Lira * and Fernando Sartillo-Piscil * Centro de Investigación de la Facultad de Ciencias Químicas, and Centro de Química de la Benemérita Universidad... 
C-h⋯o interaction | Chiral lactams | α-methylbenzylamine | MP2 | Quantum Theory | Hydrogen Bonding | Models, Chemical | Lactams - chemical synthesis | Models, Molecular | Phenethylamines - chemistry | Lactams - chemistry | H infinity | Polarization | Amides | Hydrogen bonds | Asymmetric synthesis | Hydrogen ion concentration | C−H···O interaction | chiral lactams
Journal Article
Synthesis, ISSN 0039-7881, 08/2018, Volume 50, Issue 15, pp. 2878 - 2886
Abstract An asymmetric total synthesis of stereoisomers of a putative structure of 3-hydroxy-2-piperidone alkaloid derivative is described. This route is not... 
feature | C-H oxidation | 3-hydroxypiperidin-2-ones | alkaloids | environmentally friendly | TEMPO | total synthesis | sodium chlorite | SECONDARY ALCOHOLS | OXIDATION | ACID | OXIDANT | CHEMISTRY, ORGANIC
Journal Article
Letters in Organic Chemistry, ISSN 1570-1786, 05/2017, Volume 14, Issue 4, pp. 261 - 266
Journal Article
Synlett, ISSN 0936-5214, 04/2013, Volume 24, Issue 7, pp. 878 - 882
Abstract Recently, the first direct method for preparing 2,3-epoxyamides (glycidic amides) was disclosed. Now in this letter, the enantiopure synthesis of both... 
letter | tandem oxidation | 2,3-epoxyamides | glycidic amides | balasubramide | norbalasubramide | sodium chlorite | ASYMMETRIC EPOXIDATION | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE DARZENS REACTION | CONDENSATION | STEREOSELECTIVE-SYNTHESIS | HIGHLY EFFICIENT
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2020, Volume 26, Issue 21, p. n/a
The C−H functionalization of unreactive sp3 carbon atoms under transition‐metal‐free conditions contribute, not only to the invention of novel methodologies... 
piperidines | C−H oxidation | tandem conjugated additions/electrophilic trapping | synthetic methods | alkaloids | Substitutes | Alkaloids | Organic chemistry | Chemical reactions | Organic chemicals | Cascade chemical reactions | Sustainable development
Journal Article
European journal of organic chemistry, ISSN 1434-193X, 2017, Volume 2017, Issue 28, pp. 4104 - 4110
A diastereoconvergent approach to (–)‐paroxetine from diastereomeric 3,4‐epoxy‐2‐piperidones is reported. For this synthesis, a regioselective and... 
Alkaloids | Nitrogen heterocycles | Asymmetric synthesis | Epoxides | Ring opening | Total synthesis | ASYMMETRIC-SYNTHESIS | REAGENTS | FORMAL SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | HYDROGEN-BOND | CHEMISTRY, ORGANIC | PAROXETINE PAXIL | CONSTRUCTION | SUBSTITUTED PIPERIDINES | CARBON BOND FORMATIONS | CONJUGATE ADDITIONS | Paroxetine | Epoxy resins
Journal Article
Journal of organic chemistry, ISSN 0022-3263, 2016, Volume 81, Issue 18, pp. 8625 - 8632
The first chemical method for selective dual sp(3) C-H functionalization at the alpha-and beta positions of cyclic amines to their corresponding 3-alkoxyamine... 
SODIUM-CHLORITE | ENANTIOSELECTIVE SYNTHESIS | BIOSYNTHESIS | ENANTIOMERS | SECONDARY | CARBONYL | CHEMISTRY, ORGANIC | AEROBIC OXIDATION | ALDEHYDES | PRIMARY ALCOHOLS | CARBOXYLIC-ACIDS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2015, Volume 80, Issue 5, pp. 2601 - 2608
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 1, pp. 77 - 88
The substrate-controlled asymmetric total synthesis and absolute configurational assignment of biologically active 3α,4α-epoxy-5β-pipermethystine is reported.... 
Stereoselectivity | Carbohydrates | Chiron | Amines | Synthesis | Biotransformation | Epoxidation | Oxidation | Active control | Substrates | Biological activity
Journal Article
Journal of organic chemistry, ISSN 1520-6904, 2020, Volume 85, Issue 5, pp. 3949 - 3953
Starting from 3-hydroxy piperidines, a novel transition-metal-free strategy to 5-hydroxy-5,6-dihydro-2(1H)pyridones is reported. This unprecedented approach,... 
1ST TOTAL-SYNTHESIS | ASSIGNMENT | CHEMISTRY, ORGANIC | KAVA | ENANTIOMERS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2018, Volume 83, Issue 24, pp. 15333 - 15346
By using cheap and innocuous reagents, such as NaClO2, NaOCl, and catalytic amounts of TEMPO, a new environmentally friendly protocol for the selective and... 
FUNCTIONALIZATION | ALCOHOLS | AMINES | CHEMISTRY, ORGANIC | INHIBITORS | ANTAGONISTS | DERIVATIVES
Journal Article
Acta crystallographica. Section E, Structure reports online, ISSN 1600-5368, 2010, Volume 66, Issue 6, pp. o1317 - o1317
In the title compound, C11H15FN2O5, the five-membered ring has an envelope conformation, while the six-membered ring is essentially planar, with a maximum... 
HEPATITIS | CRYSTALLOGRAPHY
Journal Article
Tetrahedron letters, ISSN 0040-4039, 2019, Volume 60, Issue 5, pp. 423 - 426
[Display omitted] •Photoredox reaction in the synthesis of a bioactive alkaloid.•New synthetic strategy to C-methyl glycosides.•Use of the stereoselective... 
Chiron approach | C-glycosylation | Free radicals | Photoredox reaction | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, ORGANIC | STEREOSPECIFIC SYNTHESIS | TETRAHYDROFURANS | DEOXYGENATION | PHARMACOLOGY | UBER MUSCARIN | ANOMERIC POSITION | DERIVATIVES | PRECURSORS | ALKALOIDS
Journal Article
Angewandte Chemie, ISSN 1521-3757, 2019, Volume 131, Issue 26, pp. 8959 - 8963
One of the major challenges in organic synthesis is the activation or deconstructive functionalization of unreactive C(sp3)–C(sp3) bonds, which requires using... 
Stickstoff-Heterocyclen | Dekonstruktive Funktionalisierung | Piperidine | Baeyer-Villiger-Oxidation | Pyrrolidinone | Transition metal compounds | Metal catalysts | Chemical industry | Transition metals | Catalysts | Deamination | Metals | Oxidation | Catalysis | Intermediates
Journal Article
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