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Chemistry : a European journal, ISSN 0947-6539, 2016, Volume 22, Issue 25, pp. 8603 - 8609
The regioselective syntheses of 1,2‐azaborinines is achieved using an unsymmetrical iminoborane through both catalytic and stepwise modular routes. The... 
azaborete ligands | isosterism | heterocycles | azaborinines | boron | POLYMERS | PI-ELECTRON MATERIALS | RING EXPANSION | OPTICAL-PROPERTIES | CHEMISTRY, MULTIDISCIPLINARY | BN ISOSTERES | REDOX SYSTEMS | INDOLE | IMINOBORANES | LATE-STAGE FUNCTIONALIZATION | Electrochemistry | Electrochemical reactions | Access control | Synthesis | Catalysts | Fluorescence | Voltammetry | Oxidation | Modular | Catalysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 13, pp. 3500 - 3504
A new catalytic synthetic route to functionalized 1,2‐azaborinines has been developed by the [2+2]/[2+4] cycloaddition reactions of di‐tert‐butyliminoboranes... 
isosterism | heterocycles | boron | cyclization | rhodium | ELECTROPHILIC AROMATIC-SUBSTITUTION | B-N | MOLECULAR-STRUCTURE | COMPLEXES | CRYSTAL | HETEROAROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | FLUORIDE | C-C | ELECTRONIC-STRUCTURE | Telomerase | Iron compounds | Metallocenes | Cycloaddition | Rhodium | Catalysts | Strategy | Esters | Formations | Derivatives | Alkynes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 5, pp. 1662 - 1665
The first examples of adducts of cyclic alkyl(amino) carbenes (CAAC) and N‐heterocyclic carbenes (NHCs) with iminoboranes have been synthesized and isolated at... 
carbenes | iminoborane adducts | boron | rearrangement | Iminoborane adducts | Boron | Carbenes | Rearrangement | STABLE CARBENE | COMPOUND | COORDINATION | N-HETEROCYCLIC CARBENES | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | SILYLENES | SUBSTITUTED 1,2-AZABOROLIDINES | CHEMISTRY | BOND | Telomerase | Imines | Clothing | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2017, Volume 56, Issue 3, pp. 889 - 892
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 1, pp. 266 - 273
A series of NHC‐supported 1,2‐dithienyldiborenes was synthesized from the corresponding (dihalo)thienylborane NHC precursors. NMR and UV/Vis spectroscopic... 
spectroscopy | boron | diborenes | electron donors | N-heterocyclic carbenes | INSERTION | AB-INITIO | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | POTENTIAL CURVES | BORON MULTIPLE BONDS | CHALCOGENS | LIGANDS | BORYLENE | GENERATION | Coplanarity | Stability | Nuclear magnetic resonance--NMR | Crystallography | Destabilization | Electrons
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 38, pp. 12275 - 12279
The first spontaneous, metal‐free, room‐temperature hydrogen transfer from ammonia borane to an iminoborane is reported. Mechanistic studies of the reaction... 
main-group elements | boron | hydrogen transfer | hydrogenation | amine boranes | STORAGE | CATALYTIC DEHYDROGENATION | REGENERATION | COORDINATION | RELEASE | THERMAL-DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | REDISTRIBUTION | AMINOBORANES | CARBENE COMPLEXES | EFFICIENT | Ammonia | Amines | Hydrogen | Activation energy | Hydrogenation | Hydrogen storage | Dehydrogenation | Metals | Boranes
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2017, Volume 23, Issue 25, pp. 5953 - 5956
A remarkably mild, catalyst‐free cyclopropanation reaction is confirmed by low‐temperature isolation of a fused bicyclic cyclopropane intermediate. This... 
carbenes | cyclopropane | C−H activation | cyclopropanation | iminoboranes | Catalysts | Cascade chemical reactions
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 27, pp. 7975 - 7979
Although the metathesis of metal–boron double bonds with elemental chalcogenides is an established process, no similar reactivity has been observed with... 
borylenes | density functional calculations | iminoboranes | boron heterocycles | nitrenes | HYDROBORATION | INSERTION | BORON | REACTIVITY | PLATINUM | TERMINAL BORYLENE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | BASIS-SETS | ARYLBORYLENE COMPLEX | METAL-COMPLEXES | Nitrogen | Chalcogenides | Boron | Cycloaddition | Metathesis | Decomposition reactions | Chemical bonds
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 26, pp. 6843 - 6847
A family of doubly isonitrile‐stabilized terphenyl borylenes could be obtained by addition of three equivalents of isonitrile to the corresponding Cr and W... 
borylenes | imine ligands | boron | Lewis bases | transition-metal complexes | BORON BONDS | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | MULTIPLE COMPLEXATION | ELEMENTS | INFRARED-SPECTRA | REDUCTION | LIGANDS | CARBENES | AMINOBORYLENE | Substitution reactions | Chromium | Carbon monoxide | Tungsten | Phosphines | Carbonyls
Journal Article