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Science, ISSN 0036-8075, 03/2016, Volume 351, Issue 6280, pp. 1421 - 1424
The C-H bonds of methane are generally more kinetically inert than those of other hydrocarbons, reaction solvents, and methane functionalization products.... 
ACTIVATION | ORIGINS | MULTIDISCIPLINARY SCIENCES | BONDS | COMPLEXES | CHEMISTRY | REGIOSPECIFIC FUNCTIONALIZATION | ALKANES | INSIGHTS | Methane | Hydrocarbon research | Ethanes | Research | Metal catalysts | Catalysis | Catalysts | Reaction kinetics
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 4, pp. 1452 - 1455
This report describes a method for the deoxyfluorination of phenols with sulfuryl fluoride (SO2F2) and tetramethylammonium fluoride (NMe4F) via aryl... 
REPLACEMENT | ROOM-TEMPERATURE | PHARMACEUTICALS | CHEMISTRY | FLUORINE | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | Phenols | Molecular dynamics | Usage | Chemical properties | Organosulfur compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2013, Volume 135, Issue 44, pp. 16292 - 16295
This Communication describes the Cu(OTf)2-mediated fluorination of aryltrifluoroborates with KF. The reaction proceeds under mild conditions (at 60 °C over 20... 
Hydrocarbons, Fluorinated - chemical synthesis | Fluorides - chemistry | Boranes - chemistry | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Mesylates - chemistry | Potassium Compounds - chemistry
Journal Article
Synlett, ISSN 0936-5214, 09/2016, Volume 27, Issue 15, pp. 2279 - 2284
Abstract This paper describes the Cu(OTf) 2 -mediated coupling of aryl and heteroaryl trifluoroborates with tetrabutylammonium or alkali metal salts to form... 
letter | carboxylation | coupling | copper | halogenation | azides | CUPRIC ACETATE | SODIUM-AZIDE | C-N | CHEMISTRY, ORGANIC | ARYLBORONIC ACIDS | BORONIC ACIDS | TETRABUTYLAMMONIUM TRIBROMIDE | IODIDES | CROSS-COUPLING REACTIONS | FACILE SYNTHESIS | CARBOXYLIC-ACIDS
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 11/2013, Volume 135, Issue 44, pp. 16292 - 16295
This Communication describes the Cu(OTf)(2)-mediated fluorination of aryltrifluoroborates with KF. The reaction proceeds under mild conditions (at 60 degrees C... 
CATALYZED FLUORINATION | PALLADIUM | ARENE | COPPER-MEDIATED FLUORINATION | ROUTES | CONVERSION | DIARYLIODONIUM SALTS | ARYL | CHEMISTRY, MULTIDISCIPLINARY | PET | Usage | Research | Copper | Fluorination | Potassium fluoride | Analysis
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 55, pp. 7669 - 7672
The homogeneous dehydrative decarbonylation of fatty acid methyl esters (FAMEs) to form olefins is reported. In order to facilitate cleavage of the unactivated... 
ORGANOBORON COMPOUNDS | HYDROCARBON FUELS | TRANSITION-METAL-COMPLEXES | COUPLING REACTION | OLEIC-ACID | TRIRUTHENIUM DODECACARBONYL | ACYL-OXYGEN BONDS | DECARBOXYLATION | ALIPHATIC CARBOXYLIC-ACIDS | CHEMISTRY, MULTIDISCIPLINARY | LINEAR ALPHA-OLEFINS | Esters | Catalysis | Transesterification | Alkenes | Dehydration | Fatty acids
Journal Article
Organic Letters, ISSN 1523-7060, 04/2015, Volume 17, Issue 8, pp. 1866 - 1869
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2018, Volume 83, Issue 18, pp. 11178 - 11190
This paper describes a detailed study of the deoxyfluorination of aryl fluorosulfonates with tetramethyl­ammonium fluoride (NMe4F) and ultimately identifies... 
PD-CATALYZED FLUORINATION | MEDICINAL CHEMISTRY | ROOM-TEMPERATURE | NUCLEOPHILIC AROMATIC FLUORINATION | TETRAMETHYLAMMONIUM FLUORIDE | SITU GENERATION | ANHYDROUS TETRABUTYLAMMONIUM FLUORIDE | CHEMISTRY, ORGANIC | SULFURYL FLUORIDE | ARYL FLUORIDES | REDUCTIVE ELIMINATION
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2015, Volume 80, Issue 24, pp. 12137 - 12145
This paper describes the room-temperature SNAr fluorination of aryl halides and nitroarenes using anhydrous tetramethylammonium fluoride (NMe4F). This reagent... 
MEDICINAL CHEMISTRY | SUBSTITUTION | NUCLEOPHILIC AROMATIC FLUORINATION | HALOGEN EXCHANGE | PHENOLS | ACTIVATED DIPHENYL SULFONES | DEOXYFLUORINATION | CHEMISTRY, ORGANIC | FLUORODENITRATION | TETRABUTYLAMMONIUM FLUORIDE | SALTS
Journal Article
Organic Letters, ISSN 1523-7060, 03/2019, Volume 21, Issue 5, pp. 1350 - 1353
A method for the room temperature Wdeoxyfluorination of benzaldehydes and alpha-ketoesters using sulfuryl fluoride and Me4NF is described. A large scope of... 
IODIDES | PALLADIUM-CATALYZED DIFLUOROMETHYLATION | COPPER-MEDIATED DIFLUOROMETHYLATION | ARYL HALIDES | CHLORIDES | CHEMISTRY, ORGANIC | BROMIDES
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 12/2015, Volume 80, Issue 24, p. 12137
Journal Article
Journal of Inorganic Biochemistry, ISSN 0162-0134, 02/2013, Volume 119, pp. 28 - 37
While an increasing number of (hexacarbonyldicobalt)alkynes have been found to possess antiproliferative activity against a number of cancer cell lines, the... 
Journal Article
The Journal of organic chemistry, 09/2018, Volume 83, Issue 18, p. 11178
This paper describes a detailed study of the deoxyfluorination of aryl fluorosulfonates with tetramethylammonium fluoride (NMe F) and ultimately identifies... 
Journal Article
The Journal of organic chemistry, 12/2015, Volume 80, Issue 24, p. 12137
This paper describes the room-temperature S(N)Ar fluorination of aryl halides and nitroarenes using anhydrous tetramethylammonium fluoride (NMe4F). This... 
Journal Article
ChemInform, ISSN 0931-7597, 08/2015, Volume 46, Issue 34, pp. no - no
SNAr fluorination of chloro‐ and nitro arenes is accomplished using acyl azolium fluorides, generated from acyl fluorides and an N‐heterocyclic carbene. 
denitration | substitution reactions | halogenation | halogen compounds (benzene compounds) | Substitution reactions | Fluorides
Journal Article
ChemInform, ISSN 0931-7597, 04/2016, Volume 47, Issue 18, pp. no - no
Optimized conditions are elaborated in detail for the title process and NMe4F is found to be generally more cost‐effective than CsF. 
halogenation | pyridine derivatives | quinoline derivatives | halogen compounds (benzene compounds) | Quinoline | Pyridine
Journal Article
ChemInform, ISSN 0931-7597, 04/2014, Volume 45, Issue 16, pp. no - no
Copper plays a dual role: to coordinate both the aryl and fluoride ligands and to serve as an oxidant generating the reactive Cu(III) key intermediate. 
halogenation | halogen compounds (benzene compounds)
Journal Article
07/2019
Disclosed is a fluorination method comprising providing an aryl fluorosulfonate and a fluorinating reagent to a reaction mixture; and reacting the aryl... 
METALLURGY | STEROIDS | ORGANIC CHEMISTRY | CHEMISTRY | HETEROCYCLIC COMPOUNDS | ACYCLIC OR CARBOCYCLIC COMPOUNDS
Patent
03/2019
Disclosed is a fluorination method comprising providing an aryl fluorosulfonate and a fluorinating reagent to a reaction mixture; and reacting the aryl... 
METALLURGY | ORGANIC CHEMISTRY | CHEMISTRY | ACYCLIC OR CARBOCYCLIC COMPOUNDS
Patent
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