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chemistry, inorganic & nuclear (25) 25
catalysis, catalysis (22) 22
iridium (18) 18
index medicus (14) 14
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chemistry, organic (11) 11
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chemical sciences (4) 4
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[ chim.cata ] chemical sciences/catalysis (2) 2
[ chim.inor ] chemical sciences/inorganic chemistry (2) 2
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Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 47, pp. 16588 - 16593
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 9/2012, Volume 109, Issue 39, pp. 15651 - 15656
Photodriving the activity of water-oxidation catalysts is a critical step toward generating fuel from sunlight. The design of a system with optimal energetics... 
Solvents | CHEMICAL APPROACHES TO ARTIFICIAL PHOTOSYNTHESIS: SOLAR FUELS SPECIAL FEATURE | Charge separation | Electron transfer | Fluorescence | Ligands | Dyadic relations | Oxidation | Iridium | Kinetics | Absorption spectra | Ultrafast optical spectroscopy | Solar fuels | Water oxidation | Photoinduced electron transfer | ENERGY | DYES | solar fuels | BUILDING-BLOCKS | MULTIDISCIPLINARY SCIENCES | ARTIFICIAL PHOTOSYNTHESIS | COMPLEXES | CHARGE-TRANSPORT | DIMERS | SINGLET | ultrafast optical spectroscopy | water oxidation | FLUORESCENCE | photoinduced electron transfer | TRIPLET EXCITED-STATE | Perylene - analogs & derivatives | Electron Transport | Oxidants, Photochemical - chemistry | Perylene - chemistry | Oxidation-Reduction | Pyridines - chemistry | Water - chemistry | Catalysis | Iridium - chemistry | Photochemical Processes | Electrochemistry | Chromophores | Research | Observations | Identification and classification | Photocatalysis | catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), bio-inspired, hydrogen and fuel cells, electrodes - solar, defects, charge transport, spin dynamics, membrane, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly) | Physical Sciences | Chemical Approaches to Artificial Photosynthesis
Journal Article
ISSN 1359-7345, 2/2017, Volume 53, Issue 13, pp. 213 - 2133
... intermediates† Yuanyuan Zhang and Nathan D. Schley* A cationic iridium complex bearing a pendant ether ligand is shown to be in equilibrium with the corresponding... 
Journal Article
ISSN 1477-0520, 2/2019, Volume 17, Issue 7, pp. 1744 - 1748
Catalysts capable of heterolytic silane activation have been successfully applied to the conversion of alkyl ethers to silyl ethers via C-O bond cleavage. The... 
Journal Article
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1860-5397, 08/2019, Volume 15, Issue 1, pp. 1856 - 1863
As a synthesis technique, halide metathesis (n RM + M'X-n -> RnM' + n MX) normally relies for its effectiveness on the favorable formation of a metal halide... 
caesium | entropy | mechanochemistry | potassium | metathesis | CRYSTAL-STRUCTURE | CHEMISTRY, ORGANIC | intermolecular forces | METAL-COMPLEXES | SOLID-STATE | Chemistry | Fluorides | Potassium | Metals | Alkali metals
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2018, Volume 140, Issue 46, pp. 15934 - 15942
Ball milling a mixture of the bulky allyl K­[A′] {[A′] = [1,3-(SiMe3)2C3H3]−} and SnCl2 in a 2:1 ratio for 5 min leads to the tris­(allyl) stannate [SnA′3K]∞,... 
HEXAPHENYLETHANE | PHASE | STEREOSELECTIVITY | BOND ORDER | CYCLOPENTADIENYL | MILLING REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | IN-SITU | REAL-TIME | ALLYL COMPOUNDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2019, Volume 141, Issue 1, pp. 618 - 625
Cyclic carbamates are a common feature of small-molecule therapeutics, offering a constrained hydrogen bond acceptor that is both polar and sterically small.... 
ALKENES | CARBON-DIOXIDE FIXATION | OXAZOLIDINONE | BRONSTED ACIDS | CHIRAL PROTON CATALYSIS | STEREOSELECTIVE-SYNTHESIS | CO2 FIXATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | BROMOAMINOCYCLIZATION | DESYMMETRIZATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2014, Volume 4, Issue 1, pp. 99 - 108
Fourteen Cp*IrIII complexes, bearing various combinations of N- and C-spectator ligands, are assayed in hydrogen-transfer catalysis from isopropyl alcohol to... 
monohydride mechanism | Ir complexes | transfer hydrogenation | homogeneous catalysis | kinetics | N-heterocyclic carbenes
Journal Article
Physical Chemistry Chemical Physics, ISSN 1463-9076, 02/2014, Volume 16, Issue 5, pp. 1814 - 1819
The domain structure of an amorphous, "blue layer'' iridium-oxide water-oxidation catalyst film (BL) electrodeposited from the soluble precursor complex,... 
OXYGEN | PHOSPHATE | ACTIVATION | COMPLEXES | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY | CHEMISTRY, PHYSICAL | INTERMEDIATE | DIFFRACTION | MECHANISMS | ATOMIC-SCALE STRUCTURE | COBALT | Amorphous structure
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2011, Volume 50, Issue 23, pp. 11938 - 11946
Ruthenium polypyridyl complexes have seen extensive use in solar energy applications. One of the most efficient dye-sensitized solar cells produced to date... 
COST | SOLAR-CELLS | DFT | LIGANDS | CRYSTAL-STRUCTURE | CHARGE-TRANSFER SENSITIZERS | BONDING MODE | CHEMISTRY, INORGANIC & NUCLEAR | Solar cells | X-ray crystallography | Usage | Composition | Ruthenium | Solar batteries | Isomerization | Analysis | Density functionals | Chemical properties | Isomerism
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2010, Volume 132, Issue 45, pp. 16017 - 16029
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 04/2020, Volume 2020, Issue 13, pp. 1192 - 1198
We demonstrate the synthesis and characterization of regioisomeric late transition metal‐aluminum heterobimetallic complexes containing 3‐ and 4‐oxypyridine... 
Electronic structure | Synthesis design | Iridium | Aluminum | Heterometallic complexes | ACTIVATION | HYDROGENATION | TRANSITION-METAL-COMPLEXES | PALLADIUM COMPLEXES | DATIVE SIGMA-BOND | REACTIVITY | COORDINATION | POLYMERIZATION | AL | CHEMISTRY, INORGANIC & NUCLEAR | NICKEL | Transition metals | Synthesis | Rhodium | Dichloromethane | Ligands | Coordination compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2011, Volume 133, Issue 27, pp. 10473 - 10481
Molecular water-oxidation catalysts can deactivate by side reactions or decompose to secondary materials over time due to the harsh, oxidizing conditions... 
Water | Heterogeneous catalysis | Oxidation-reduction reaction | Iridium | Chemical properties | Analysis
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2008, Volume 6, Issue 23, pp. 4442 - 4445
Primary alcohols can be coupled with secondary benzylic alcohols by an air-stable catalytic system involving terpyridine ruthenium or iridium complexes. 
SECONDARY ALCOHOLS | HYDROGEN | IRIDIUM(III) | LIGANDS | BETA-ALKYLATION | RUTHENIUM(II) | HYDROSILYLATION REACTIONS | ASYMMETRIC CYCLOPROPANATION | CHEMISTRY, ORGANIC | ELECTROPHILES | METAL-COMPLEXES
Journal Article
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