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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2014, Volume 53, Issue 2, pp. 370 - 374
Risky business? The use of dative bonds to describe the electronic structure of main‐group compounds has come into vogue in recent years. But where are the... 
dative bonds | coordinative bonds | covalent bonds | p‐block coordination compounds | p-block coordination compounds | HETEROCYCLIC CARBENE | CARBON | COMPLEXES | REACTIVITY | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | INFRARED-SPECTRUM | CHEMISTRY | CATION | Electronic structure | Business
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 07/2019, Volume 48, Issue 41, pp. 15577 - 15582
A neutral tetrasubstituted Ge9 cluster with a covalently bound transition metal substituent was synthesized successfully via a salt metathesis reaction.... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 24, pp. 6047 - 6048
Is a meatball an animal praline? The authors of the Essay Dative Bonds in Main‐Group Compounds: A Case for Fewer Arrows! respond to the criticism of Gernot... 
dative bonds | p‐block coordination compounds | bond theory | p-block coordination compounds | CHEMISTRY, MULTIDISCIPLINARY | BONDS | Grammar
Journal Article
Chemical Society reviews, ISSN 0306-0012, 05/2007, Volume 36, Issue 5, pp. 745 - 758
Metalloid cluster compounds of group 14 of the general formulae E(n)R(m) with n > m (E = Si, Ge, Sn and Pb, tetrel elements; R = ligand), where "naked" tetrel... 
Journal Article
EPJ Web of Conferences, ISSN 2100-014X, 2019, Volume 214, p. 3053
The GridKa Tier 1 data and computing center hosts a significant share of WLCG processing resources. Providing these resources to all major LHC and other VOs... 
Batch processing | Resource management | Middleware | Optimization
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2007, Volume 36, Issue 5, pp. 745 - 758
Metalloid cluster compounds of group 14 of the general formulae EnRm with n > m (E = Si, Ge, Sn and Pb, tetrel elements; R = ligand), where "naked'' tetrel... 
ELEMENTS | GERMANIUM | PHOTOLUMINESCENCE | CAGE | DELTAHEDRAL ZINTL IONS | POLYHEDRA | SILICON | CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry (Weinheim an der Bergstrasse, Germany), ISSN 0947-6539, 07/2016, Volume 22, Issue 31, pp. 10748 - 10753
The reaction of a metastable SiCl2 solution with the sterically less-demanding carbene N,N-diisopropylimidazo-2-ylidene (IPr) yields the salt [(IPr3 Si3 Cl5... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 393 - 396
The reduction of (Ph3P)AuCl with NaBH4 in the presence of HSC(SiMe3)3, leads to one of the largest metalloid gold clusters: Au108S24(PPh3)16 (1). Within 1 an... 
gold | thiol | metalloid clusters | nanoparticles | Gold | Metals | Clusters | Reduction (metal working)
Journal Article
Chemistry: A European Journal, ISSN 0947-6539, 07/2016, Volume 22, Issue 31, pp. 10748 - 10753
The reaction of a metastable SiCl sub(2) solution with the sterically less-demanding carbene N,N-diisopropylimidazo-2-ylidene (IPr) yields the salt [(IPr... 
Backbone | Quantum chemistry | Halides | Mathematical analysis | Reagents | Silicon | Cations | Nuclear magnetic resonance
Journal Article
Zeitschrift fur anorganische und allgemeine Chemie, ISSN 0044-2313, 02/2019, Volume 645, Issue 3, p. 335
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 02/2019, Volume 645, Issue 3, pp. 335 - 339
Journal Article
Structure and Bonding, ISSN 0081-5993, 03/2017, Volume 174, pp. 135 - 200
Metalloid cluster compounds of the general formulae MnRm (n>m; M=metal like Al, Au, Sn, etc.; R=ligand like S-C6H4-COOH, N(SiMe3)(2), etc.) represent a novel... 
Nanoscale | Tin | Germanium | Gallium | Metal | Aluminum | GERMANIUM CLUSTERS | HIGH-PRESSURE | GALLIUM CLUSTERS | CRYSTAL-STRUCTURE | CHEMISTRY, PHYSICAL | X-RAY-DIFFRACTION | STRUCTURAL-CHARACTERIZATION | CHEMISTRY, INORGANIC & NUCLEAR | TIN CLUSTER | DELTAHEDRAL ZINTL IONS | FREE GERMYL CATION | ORGANOMETALLIC CHEMISTRY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2002, Volume 41, Issue 19, pp. 3532 - 3554
As members of the same group in the periodic table, the industrially significant elements aluminum and gallium exhibit strong similarities in the majority of... 
cluster compounds | aluminum | gallium | structure elucidation | metal–metal interactions | Gallium | Aluminum | Structure elucidation | Cluster compounds | Metal-metal interactions
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2019, Volume 25, Issue 1, pp. 144 - 157
Classical halides of the heavier Group 14 homologues germanium, tin, and lead are common precursors for the synthesis of exciting compounds, such as polyhedral... 
cluster compounds | germanium | halides | Group 14 elements | co-condensation | Group 14 elements | APPROXIMATION | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | CLUSTER COMPOUND | NANOCLUSTERS | MIXED-VALENCE FLUORIDE | METALLOID CLUSTERS | CHEMISTRY | BASIS-SETS | GALLIUM | Disproportionation | Polyhedra | Homology | Condensation | Synthesis | Reviews | Halides | Precursors | Lead | Clusters | Tin | Germanium | Oxidation
Journal Article
EPJ Web of Conferences, ISSN 2100-014X, 2019, Volume 214, p. 8009
Demand for computing resources in high energy physics (HEP) shows a highly dynamic behavior, while the provided resources by the Worldwide LHC Computing Grid... 
Resource scheduling | Resource management | Computation | Peak load
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2019, Volume 25, Issue 29, pp. 7210 - 7217
The reaction system GeCl2⋅dioxane/LiSTsi (Tsi=C(SiMe3)3) opens a fruitful area in germanium chemistry, depending on the stoichiometry and solvent used during... 
carbene homologues | insertion | C−H activation | germanium | metathesis | Stoichiometry | Solvents | Organic chemistry | Germanium chlorides | Toluene | Insertion | Germanium | Activation | Acetylene
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 9, pp. 3216 - 3219
The oxidation of [Ge9(Hyp)3]− (Hyp=Si(SiMe3)3) with an FeII salt leads to Ge18(Hyp)6 (1), the largest Group 14 metalloid cluster that has been structurally... 
quantum-chemical calculations | clathrates | metalloid clusters | germanium | solid-state structures | Clathrate compounds
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 10/2010, Volume 34, Issue 1, pp. 279 - 292
Metalloid cluster compounds of germanium of the general formulae Ge n R m with n > m (R = ligand), where naked as well as ligand bound germanium atoms are... 
SOL-GEL METHOD | SUPERCONDUCTIVITY | PHOTOLUMINESCENCE | FREE GERMYL CATION | BUILDING-BLOCKS | CHEMISTRY | CRYSTAL-STRUCTURES | ATOMS | MAIN-GROUP ELEMENTS | C6H3-2,6-MES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
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