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Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 17, pp. 4853 - 4857
para‐Selective C−H borylation of benzamides and pyridines has been achieved by cooperative iridium/aluminum catalysis. A combination of iridium catalysts... 
iridium | regioselectivity | Lewis acids | C-H activation | boronate esters | ROOM-TEMPERATURE | ARYLATION | BOND FUNCTIONALIZATION | NICKEL/LEWIS ACID CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | MONOSUBSTITUTED ARENES | PHENOLS | LIGAND | ELECTRON-RICH ARENES | DERIVATIVES | Synthesis | Pyridine | Catalysis | Organic compounds | Aluminum | Lewis acid | Pyridines | Catalysts | Regioselectivity | Aromatic compounds | Iridium | Intermediates
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2014, Volume 136, Issue 21, pp. 7567 - 7570
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2012, Volume 18, Issue 14, pp. 4179 - 4184
Taking control of boron: A highly regio‐ and stereoselective copper‐catalyzed hydroboration of unsymmetrical internal alkynes has been developed. The... 
copper | internal alkynes | homogeneous catalysis | hydroboration | alkynes | REAGENTS | TRISUBSTITUTED ALKENES | COMPLEXES | EFFICIENT SYNTHESIS | CATECHOLBORANE | PINACOLBORANE | CHEMISTRY, MULTIDISCIPLINARY | ACYCLIC SYSTEMS | COUPLING REACTIONS | STEREOCHEMICAL CONTROL | ESTERS | Boron | Hydroboration | Catalysts | Hydrides | Catalysis | Copper | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2011, Volume 50, Issue 2, pp. 523 - 527
Getting a fix: The copper‐catalyzed hydrocarboxylation of alkynes using carbon dioxide in the presence of a hydrosilane, which serves as a reducing agent, has... 
silanes | carbon dioxide | copper | N‐heterocyclic carbene | hydrocarboxylation | N-heterocyclic carbene | CO2 | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CYCLOADDITION | DIRECT CARBOXYLATION | ALKENYLBORONIC ESTERS | METAL-COMPLEXES | DIYNES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2013, Volume 19, Issue 22, pp. 7125 - 7132
The highly selective copper‐catalyzed hydroboration of allenes has been developed. Allylboranes and alkenylboranes were selectively prepared by the judicious... 
allenes | copper | hydroboration | dienes | ligand effects | CROSS-COUPLING REACTION | CONJUGATED DIENES | ENANTIOSELECTIVE DIBORATION | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ALLYLIC ALCOHOLS | BIS(PINACOLATO)DIBORON | 1-ALKENYL HALIDES | STEREOSELECTIVE-SYNTHESIS | PLATINUM-CATALYZED DIBORATION | BORYLATION | Copper | Diffraction | X rays | Crystals | Hydroboration | Allene | X-rays | Ligands | Hydrides | Derivatives
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2016, Volume 55, Issue 21, pp. 6275 - 6279
A method for the reductive cross‐coupling of conjugated arylalkenes and aryl bromides with hydrosilanes by cooperative palladium/copper catalysis was... 
cross-coupling | copper | palladium | alkenes | alkynes | ASYMMETRIC HYDROSILYLATION | STYRENES | HYDROBORATION | REAGENTS | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | SYNERGISTIC CATALYSIS | TIN | DUAL CATALYSIS | Catalysis | Alkenes | Aromatic compounds | Bromides | Palladium | Coupling | Copper | Biological activity | Molecular chains | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2014, Volume 53, Issue 34, pp. 9007 - 9011
Borylative allyl–allyl coupling using allenes, bis(pinacolato)diboron, and allyl phosphates has been developed in the presence of a copper catalyst bearing an... 
allenes | copper | boron | allylic compounds | CC coupling | C-C coupling | SUBSTITUTION | PALLADIUM COMPLEXES | INDUCED ELIMINATION | ATE COMPLEXES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | 1,5-DIENES | PHOSPHATES | OXIDATIVE CYCLIZATION | GRIGNARD-REAGENTS | Phosphates | Copper | Catalysts | Ligands | Joining | Derivatives | Carbenes | Bearing
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 12/2017, Volume 90, Issue 12, pp. 1340 - 1343
A versatile method for the arylboration of internal alkynes with aryl chlorides or bromides and bis(pinacolato)diboron has been developed. This method... 
ALKENES | COUPLING REACTIONS | SYNERGISTIC CATALYSIS | ORGANOZIRCONIUM REAGENTS | COMPLEXES | ARYL | ALKENYLBORONIC ESTERS | DUAL CATALYSIS | BOND | CHEMISTRY, MULTIDISCIPLINARY | 3-COMPONENT CARBOBORATION | Substitutes | Regioselectivity | Aromatic compounds | Bromides | Palladium | Catalysis | Functional groups | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 4, pp. 929 - 932
We report meta‐ and para‐selective linear alkylation reactions of anilides with alkenes by nickel/N‐heterocyclic carbene (NHC) and aluminum catalysis. With a... 
C−H functionalization | nickel | aluminum | alkenes | cooperative catalysis | COMPLEXES | ARYLATION | N-HETEROCYCLIC CARBENES | HYDROAMINATION | C-H functionalization | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | AROMATIC-AMINES | LIGANDS | ANILINES | HYDROARYLATION | Olefins | Catalysis | Nickel | Alkenes | Aluminum | Alkylation
Journal Article
Tetrahedron, ISSN 0040-4020, 02/2019, Volume 75, Issue 6, pp. 709 - 719
In this review, cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on catalytically generated organocopper nucleophiles are summarized.... 
Cooperative catalysis | Palladium | Nickel | Cross-coupling | Copper | ROOM-TEMPERATURE | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | INTERNAL ALKYNES | ALKYNYLZINC REAGENTS | ANTI-MARKOVNIKOV OXIDATION | ENANTIOSELECTIVE ARYLBORATION | SELECTIVE SYNTHESIS | STEREOSELECTIVE-SYNTHESIS | SONOGASHIRA REACTIONS | DUAL CATALYSIS
Journal Article
Organic Letters, ISSN 1523-7060, 08/2016, Volume 18, Issue 16, pp. 3956 - 3959
A method for the arylboration of 1-arylalkenes with bis­(pinacolato)­diboron and aryl chlorides or tosylates by cooperative Ni/Cu catalysis has been developed,... 
ALKENES | ENANTIOSELECTIVE SYNTHESIS | SYNERGISTIC CATALYSIS | ARYL HALIDES | CHEMISTRY, ORGANIC | BORONIC ESTERS | CO-CATALYSIS | STEREOSELECTIVE-SYNTHESIS | ALKYNES | CARBON-DIOXIDE | 3-COMPONENT CARBOBORATION
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 5/2014, Volume 4, Issue 6, pp. 1699 - 179
This review summarizes the transformation of alkynes using a copper hydride (Cu-H) or boryl copper (Cu-B) species as the active species. The semihydrogenation,... 
TRANSITION-METAL-COMPLEXES | COUPLING REACTIONS | CHEMISTRY, PHYSICAL | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | TERMINAL ALKYNES | DIBORON REAGENTS | N-HETEROCYCLIC CARBENES | INTERNAL ALKYNES | STEREOSELECTIVE-SYNTHESIS | TRANSFER SEMIHYDROGENATION | TRANSFER-HYDROGENATION | Hydroboration | Synthesis | Alkenes | Transformations | Hydrides | Catalysis | Copper | Alkynes
Journal Article
ISSN 1359-7345, 10/2018, Volume 54, Issue 81, pp. 11463 - 11466
A method for the carboallylation of electron-deficient alkenes with tetraorganosilicon reagents and allylic carbonates based on Pd/Cu catalysis has been... 
Journal Article