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The Journal of Organic Chemistry, ISSN 0022-3263, 03/2018, Volume 83, Issue 6, pp. 3013 - 3022
The use of combined Heck carbometalation and cross-coupling remains one of the most powerful ways for the difunctionalization of unactivated olefins with... 
ORGANOBORONIC ACIDS | REGIOSELECTIVE 1,2-DICARBOFUNCTIONALIZATION | TRANSIENT METALLACYCLES | NITROGEN ASSISTANCE | RADICAL CYCLIZATION | CHEMISTRY, ORGANIC | CATALYZED TANDEM CYCLIZATION | ANION CAPTURE PROCESSES | SITU GENERATED VINYLSTANNANES | TERMINAL ALKENES | ALKYL-HALIDES
Journal Article
The Chemical Record, ISSN 1527-8999, 09/2018, Volume 18, Issue 9, pp. 1314 - 1340
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2018, Volume 140, Issue 25, pp. 7782 - 7786
We disclose a [(PhO)3P]/NiBr2-catalyzed regioselective β,δ-diarylation of unactivated olefins in ketimines with aryl halides and arylzinc reagents. This... 
ALKENYL CARBONYL-COMPOUNDS | ARYL BORONIC ACIDS | 3-COMPONENT COUPLING REACTION | RADICAL CYCLIZATION | HECK REACTIONS | BOND ACTIVATION | ALKYL BROMIDES | QUATERNARY CENTERS | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | INTERMOLECULAR CYANOTRIFLUOROMETHYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2018, Volume 140, Issue 31, pp. 9801 - 9805
We report a Ni-catalyzed regioselective alkylarylation of vinylarenes with alkyl halides and arylzinc reagents to generate 1,1-diarylalkanes. The reaction... 
ALKENYL CARBONYL-COMPOUNDS | ARYL GRIGNARD-REAGENTS | CROSS-COUPLING REACTIONS | TRANSIENT METALLACYCLES | ASYMMETRIC-SYNTHESIS | HECK REACTIONS | UNACTIVATED OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | ALKYL-HALIDES | INTERMOLECULAR CYANOTRIFLUOROMETHYLATION
Journal Article
Chemical science, ISSN 2041-6520, 01/2018, Volume 9, Issue 4, pp. 904 - 909
We report a Ni-catalysed diarylation of unactivated olefins in dimethylpyridylvinylsilane by intercepting Heck C(sp )-NiX intermediates, derived from aryl... 
Journal Article
The Journal of organic chemistry, 02/2018
The use of combined Heck carbometalation and cross-coupling remains one of the most powerful ways for the difunctionalization of unactivated olefins with... 
Journal Article
ORGANIC PROCESS RESEARCH & DEVELOPMENT, ISSN 1083-6160, 08/2019, Volume 23, Issue 8, pp. 1686 - 1694
We report a five-step synthesis of the biologically important 1,1-diarylalkane 1, a potential 5-lipoxygenase activating protein (FLAP) inhibitor that was... 
ACIDS | CHEMISTRY, ORGANIC | three-component | REDUCTIVE DICARBOFUNCTIONALIZATION | UNACTIVATED OLEFINS | alkenes | ZINC | ALKYL-HALIDES | DIFUNCTIONALIZATION | 1,1-diarylalkanes | CROSS-COUPLING REACTIONS | FLAP inhibitor | dicarbofunctionalization | ARYL | CHEMISTRY, APPLIED | alkylarylation | TERMINAL ALKENES | CYCLIZATION
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 12/2019, Volume 9, Issue 12, pp. 10887 - 10893
We disclose a transmetalation-initiated Ni(I)-catalyzed regioselective beta,delta-vinylarylation of gamma,delta-alkenyl alpha-cyanocarboxylic esters with vinyl... 
nickel enolates | beta,delta-vinylarylation | 3-COMPONENT COUPLING REACTION | nickel-catalyzed | ACIDS | CHEMISTRY, PHYSICAL | REDUCTIVE DICARBOFUNCTIONALIZATION | UNACTIVATED OLEFINS | regioselective | ALKYL-HALIDES | PD | BONDS | metallacycle contraction | NI | TERMINAL ALKENES | CYCLIZATION | transmetalation
Journal Article
Indian Journal of Plastic Surgery, ISSN 0970-0358, 01/2012, Volume 45, Issue 1, pp. 016 - 021
ABSTRACT Background: The surgical management of advanced, incurable, malignant disease presents particular ethical and technical challenges. The clear goal is... 
Original Article | Futility | palliation | quality of life | surgery | Care and treatment | Tumors | Intervention | Professional standards | Postoperative period | Consent | Surgery | Palliative care | Quality of life | Original | futility
Journal Article
Clinical Orthopaedics and Related Research, ISSN 0009-921X, 3/2013, Volume 471, Issue 3, pp. 762 - 773
Joint-preserving surgery is performed in select patients with bone sarcomas of extremities and allows patients to retain the native joint with better joint... 
Surgical Orthopedics | Medicine & Public Health | Sports Medicine | Orthopedics | Surgery | Conservative Orthopedics | Medicine/Public Health, general | SURGERY | KNEE | LIMB | SARCOMAS | OSTEOSARCOMA | MARGINS | BONE | EXCISION | ORTHOPEDICS | Osteotomy - adverse effects | Chondrosarcoma - surgery | Humans | Middle Aged | Male | Tomography, X-Ray Computed | Prosthesis Design | Bone Neoplasms - pathology | Young Adult | Surgery, Computer-Assisted - adverse effects | Time Factors | Prosthesis Implantation - adverse effects | Chondrosarcoma - pathology | Female | Joints - surgery | Reconstructive Surgical Procedures - instrumentation | Retrospective Studies | Chondrosarcoma - diagnostic imaging | Child | Radiographic Image Interpretation, Computer-Assisted | Osteosarcoma - diagnostic imaging | Bone Neoplasms - diagnostic imaging | Neoplasm Recurrence, Local | Prosthesis Implantation - instrumentation | Reconstructive Surgical Procedures - methods | Surgery, Computer-Assisted - instrumentation | Joints - pathology | Treatment Outcome | Bone Neoplasms - surgery | Magnetic Resonance Imaging | Osteosarcoma - surgery | Adolescent | Reconstructive Surgical Procedures - adverse effects | Prosthesis Implantation - methods | Computer-Aided Design | Osteosarcoma - pathology | Osteotomy - methods | Sarcoma | Implants, Artificial | Prosthesis | Health aspects | Consulting services | Symposium | Papers Presented at the 2011 ISOLS Meeting in Beijing, China
Journal Article
Clinical Orthopaedics and Related Research, ISSN 0009-921X, 3/2013, Volume 471, Issue 3, pp. 750 - 761
Journal Article
Journal Article
ISSN 2041-6520, 1/2018, Volume 9, Issue 4, pp. 94 - 99
We report a Ni-catalysed diarylation of unactivated olefins in dimethylpyridylvinylsilane by intercepting Heck C(sp 3 )-NiX intermediates, derived from aryl... 
Journal Article
01/2019, ISBN 9781687998774
Alkenes serve as one of the most important feedstocks for organic synthesis, having two vicinal sites for bond formation. In alkenes, both vicinal sites can be... 
Organic chemistry | Chemistry
Dissertation
Journal Article