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1. Full Text Copper‐Catalyzed Intermolecular Heck‐Like Coupling of Cyclobutanone Oximes Initiated by Selective C−C Bond Cleavage
by Zhao, Binlin and Shi, Zhuangzhi
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 41, pp. 12727 - 12731
The first example of intermolecular olefination of cyclobutanone oximes with alkenes via selective C−C bond cleavage leading to the synthesis of nitriles in... 
copper | radicals | cyclobutanone | oximes | olefination | TERT-CYCLOBUTANOLS | BENZOCYCLOBUTENONES | ACTIVATION | BETA-CARBON ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | ALKYL-HALIDES | VISIBLE-LIGHT | KETONES | RING-CLEAVAGE | DERIVATIVES | Copper | Nitriles | Carbon-carbon composites | Oximes | Cyanide | Salts | Alkenes | Cleavage | Cyanides | Coupling | Chemical synthesis
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2. Full Text Efficient and Versatile Synthesis of Indoles from Enamines and Imines by Cross‐Dehydrogenative Coupling
by Shi, Zhuangzhi and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2012, Volume 51, Issue 37, pp. 9220 - 9222
Complement for Fischer: An efficient palladium‐catalyzed indole synthesis proceeds by the intramolecular cross‐dehydrogenative coupling of N‐aryl imines under... 
CH activation | imines | indoles | enamines | dioxygen | C-H activation | N-ARYL ENAMINES | C BOND FORMATION | ANILINES | OXIDANT | C?H activation | OXIDATIVE CYCLIZATION | CHEMISTRY, MULTIDISCIPLINARY | Amines - chemistry | Imines - chemistry | Ketones - chemistry | Oxygen - chemistry | Indoles - chemical synthesis | Aniline Compounds - chemistry | Catalysis | Indoles - chemistry | Palladium - chemistry | Schiff bases | Coupling (molecular) | Sole | Synthesis | Ketones | Imines | Oxidants | Complement | Indoles
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3. Regioselective direct arylation of indoles on the benzenoid moiety
by Youqing Yang and Zhuangzhi Shi
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 14, pp. 1676 - 1685
Recent advances in transition metal-catalyzed selective C–H functionalization of indoles have garnered tremendous attention. Great efforts have been devoted to... 
Regioselectivity | Indoles
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4. Full Text Rh-Catalyzed P(III)-Directed ortho C-H Borylation of Arylphosphines
by Shi, Zhuangzhi
Angewandte Chemie (International ed. in English), 01/2019
Transition-metal-mediated metallation of an aromatic C-H bond that is adjacent to a tertiary phosphine group in arylphosphines via a four-membered chelate ring... 
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5. Full Text Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N‑Oxides from Oximes and Diazo Compounds
by Shi, Zhuangzhi and Koester, Dennis C and Boultadakis-Arapinis, Mélissa and Glorius, Frank
Journal of the American Chemical Society, ISSN 0002-7863, 08/2013, Volume 135, Issue 33, pp. 12204 - 12207
Multisubstituted isoquinoline and pyridine N-oxides have been prepared by Rh(III)-catalyzed cycliz­ation of oximes and diazo compounds via aryl and vinylic C–H... 
FUNCTIONALIZATION | ACTIVATION | DIRECT ARYLATION | ONE-POT SYNTHESIS | RHODIUM(III)-CATALYZED SYNTHESIS | REGIOSELECTIVE SYNTHESIS | ALPHA,BETA-UNSATURATED KETOXIMES | ARYL | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | Azo Compounds - chemistry | Oximes - chemistry | Isoquinolines - chemistry | Pyridines - chemistry | Stereoisomerism | Substrate Specificity | Catalysis | Rhodium - chemistry | Thermal properties | Measurement | Rhodium | Analysis | Chemical properties | Ring formation (Chemistry) | Activation energy
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6. Full Text Nickel‐Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C−N Bond Activation
by Hu, Jiefeng and Zhao, Yue and Liu, Jingjing and Zhang, Yemin and Shi, Zhuangzhi
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 30, pp. 8718 - 8722
A nickel/N‐heterocyclic carbene catalytic system has been established for decarbonylative borylation of amides with B2nep2 by C−N bond activation. This... 
nickel | amides | decarbonylation | structure elucidation | boron | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTION | ARYL CARBOXYLATES | CLEAVAGE | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | H ARYLATION | DIRECTED ASYMMETRIC HYDROGENATION | ACID-CHLORIDES | SP CARBON | ESTERS | Amides | Nickel | Chemical properties | Analysis
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7. Full Text Cu-Catalyzed Direct C6-Arylation of Indoles
by Yang, Youqing and Li, Ruirui and Zhao, Yue and Zhao, Dongbing and Shi, Zhuangzhi
Journal of the American Chemical Society, ISSN 0002-7863, 07/2016, Volume 138, Issue 28, pp. 8734 - 8737
The first example of direct and site-selective arylation of indoles at the C6 position has been reported. The key to this high regioselectivity is the... 
FUNCTIONALIZATION | MILD | ROOM-TEMPERATURE | ACTIVATION | ARENES | H BOND ARYLATION | DIARYLIODONIUM SALTS | N-PIVALOYLINDOLES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Arylation | Research | Chemical properties | Catalysis | Copper | Indole
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8. Full Text Regiocontrolled Direct C−H Arylation of Indoles at the C4 and C5 Positions
by Yang, Youqing and Gao, Pan and Zhao, Yue and Shi, Zhuangzhi
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 3966 - 3971
An effective and practical strategy has been established for the direct and site‐selective arylation of indoles at the C4 and C5 positions with the aid of a... 
regioselectivity | copper | palladium | indoles | arylation | ROOM-TEMPERATURE | DIAZONAMIDE-A | DIARYLIODONIUM SALTS | 2ND TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | MILD CONDITIONS | BOND ARYLATION | REGIOSELECTIVE SYNTHESIS | N-PIVALOYLINDOLES | CATALYZED DIRECT ARYLATION | Chemical synthesis | Palladium | Transformation | Indoles | Indole | Functional groups
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9. Full Text Rhodium(III)‐Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes
by Shi, Zhuangzhi and Schröder, Nils and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2012, Volume 51, Issue 32, pp. 8092 - 8096
Your CHOice! An efficient RhIII‐catalyzed dehydrogenative Heck reaction (DHR) of salicylaldehydes with different classes of olefins extends the oxidative Heck... 
CH functionalization | heterocycles | salicylaldehydes | dehydrogenative Heck reaction | rhodium | C-H functionalization | C-H BOND | PD(II)-CATALYZED OLEFINATION | INTERNAL ALKYNES | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | ACTIVATION REACTIONS | ORTHO-ALKENYLATION | OXIDATIVE OLEFINATION | ALKENES | CATALYST SYSTEM | BENZOIC-ACIDS | Ketones - chemical synthesis | Ketones - chemistry | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Hydrogenation | Rhodium - chemistry | Aldehydes - chemistry | Rhodium | Substitution reactions | Biocompatibility | Reaction mechanisms | Aldehydes | Natural products | Dehydrogenation | Olefins
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10. Full Text Palladium-catalyzed regioselective C-H fluoroalkylation of indoles at the C4-positionElectronic supplementary information (ESI) available: Detailed experimental procedures, characterization of starting materials and products and crystallographic data. CCDC 1533305. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc01274h
by Borah, Arun Jyoti and Shi, Zhuangzhi
ISSN 1359-7345, 4/2017, Volume 53, Issue 28, pp. 3945 - 3948
An exclusive catalytic C4-selective fluoroalkylation of indoles with highly active (1 H , 1 H -perfluoroalkyl)mesityliodonium triflate has been described. The... 
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11. Full Text Rhodium-Catalyzed Selective C–H Trideuteromethylation of Indole at C7 Position Using Acetic-d6 Anhydride
by Han, Xiaowei and Yuan, Yu and Shi, Zhuangzhi
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2019, Volume 84, Issue 20, pp. 12764 - 12772
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12. Full Text Synthesis of fluorenones via quaternary ammonium salt-promoted intramolecular dehydrogenative arylation of aldehydes
by Shi, Zhuangzhi and Glorius, Frank
Chemical Science, ISSN 2041-6520, 02/2013, Volume 4, Issue 2, pp. 829 - 833
Biologically interesting fluorenone, xanthone and anthrone derivatives have been prepared via an intramolecular oxidative acylation process. This novel direct... 
CROSS-COUPLINGS | ALDOXIME ETHERS | COUPLING REACTIONS | CATALYZED ORTHO-ARYLATION | HOMOLYTIC ACYLATION | N BOND FORMATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | ARYLBORONIC ACIDS | ELECTRON-DEFICIENT OLEFINS
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13. Full Text Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant
by Shi, Zhuangzhi and Zhang, Chun and Tang, Conghui and Jiao, Ning
Chemical Society Reviews, ISSN 0306-0012, 3/2012, Volume 41, Issue 8, pp. 3381 - 343
For green and sustainable chemistry, molecular oxygen is considered as an ideal oxidant due to its natural, inexpensive, and environmentally friendly... 
ALPHA-DIAZOCARBONYL COMPOUNDS | HECK-TYPE REACTION | AEROBIC OXIDATIVE AMINATION | PRIMARY AROMATIC-AMINES | CROSS-COUPLING REACTION | SYMMETRICAL 1,4-DISUBSTITUTED 1,3-DIYNES | TERMINAL ALKYNES | CARBON TRIPLE BOND | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | WACKER-TYPE OXIDATION | Transition Elements - chemistry | Oxidants - chemistry | Catalysis | Oxidation-Reduction | Oxygen - chemistry
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14. Full Text 3D立体扫描演示装置
by 朱石明
中国科技教育, ISSN 1671-4350, 2017, Issue 8, pp. 30 - 31
选题来源 如今，越来越多的3D初创公司试图挤进当前尚小但是却在不断扩展的增材制造（即3D打印）领域，但3D实物扫描设备的昂贵价格却让人望而却步。在创客教学的课堂上，也需要一个3D扫描的演示装置，让学生更好地领会3D扫描原理。 
3D | 打印 | 立体 | 扫描设备 | 演示装置
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15. Full Text Nickel-catalysed retro-hydroamidocarbonylation of aliphatic amides to olefins
by Hu, Jiefeng and Wang, Minyan and Pu, Xinghui and Shi, Zhuangzhi
Nature Communications, ISSN 2041-1723, 05/2017, Volume 8, Issue 1, p. 14993
Amide and olefins are important synthetic intermediates with complementary reactivity which play a key role in the construction of natural products,... 
AZOLES | DECARBONYLATIVE BORYLATION | ACTIVATION | COUPLING REACTIONS | ARYL ESTERS | MULTIDISCIPLINARY SCIENCES | BONDS | DEHYDROHALOGENATION | CHEMOSELECTIVITY | SILYLATION | HYDROFORMYLATION
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