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Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 41, pp. 12727 - 12731
The first example of intermolecular olefination of cyclobutanone oximes with alkenes via selective C−C bond cleavage leading to the synthesis of nitriles in... 
copper | radicals | cyclobutanone | oximes | olefination | TERT-CYCLOBUTANOLS | BENZOCYCLOBUTENONES | ACTIVATION | BETA-CARBON ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | ALKYL-HALIDES | VISIBLE-LIGHT | KETONES | RING-CLEAVAGE | DERIVATIVES | Copper | Nitriles | Carbon-carbon composites | Oximes | Cyanide | Salts | Alkenes | Cleavage | Cyanides | Coupling | Chemical synthesis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2012, Volume 51, Issue 37, pp. 9220 - 9222
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 14, pp. 1676 - 1685
Recent advances in transition metal-catalyzed selective C–H functionalization of indoles have garnered tremendous attention. Great efforts have been devoted to... 
Regioselectivity | Indoles
Journal Article
Angewandte Chemie (International ed. in English), 01/2019
Transition-metal-mediated metallation of an aromatic C-H bond that is adjacent to a tertiary phosphine group in arylphosphines via a four-membered chelate ring... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 30, pp. 8718 - 8722
A nickel/N‐heterocyclic carbene catalytic system has been established for decarbonylative borylation of amides with B2nep2 by C−N bond activation. This... 
nickel | amides | decarbonylation | structure elucidation | boron | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTION | ARYL CARBOXYLATES | CLEAVAGE | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | H ARYLATION | DIRECTED ASYMMETRIC HYDROGENATION | ACID-CHLORIDES | SP CARBON | ESTERS | Amides | Nickel | Chemical properties | Analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2016, Volume 138, Issue 28, pp. 8734 - 8737
The first example of direct and site-selective arylation of indoles at the C6 position has been reported. The key to this high regioselectivity is the... 
FUNCTIONALIZATION | MILD | ROOM-TEMPERATURE | ACTIVATION | ARENES | H BOND ARYLATION | DIARYLIODONIUM SALTS | N-PIVALOYLINDOLES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Arylation | Research | Chemical properties | Catalysis | Copper | Indole
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 3966 - 3971
An effective and practical strategy has been established for the direct and site‐selective arylation of indoles at the C4 and C5 positions with the aid of a... 
regioselectivity | copper | palladium | indoles | arylation | ROOM-TEMPERATURE | DIAZONAMIDE-A | DIARYLIODONIUM SALTS | 2ND TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | MILD CONDITIONS | BOND ARYLATION | REGIOSELECTIVE SYNTHESIS | N-PIVALOYLINDOLES | CATALYZED DIRECT ARYLATION | Chemical synthesis | Palladium | Transformation | Indoles | Indole | Functional groups
Journal Article
ISSN 1359-7345, 4/2017, Volume 53, Issue 28, pp. 3945 - 3948
An exclusive catalytic C4-selective fluoroalkylation of indoles with highly active (1 H , 1 H -perfluoroalkyl)mesityliodonium triflate has been described. The... 
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2019, Volume 84, Issue 20, pp. 12764 - 12772
Journal Article
Chemical Science, ISSN 2041-6520, 02/2013, Volume 4, Issue 2, pp. 829 - 833
Biologically interesting fluorenone, xanthone and anthrone derivatives have been prepared via an intramolecular oxidative acylation process. This novel direct... 
CROSS-COUPLINGS | ALDOXIME ETHERS | COUPLING REACTIONS | CATALYZED ORTHO-ARYLATION | HOMOLYTIC ACYLATION | N BOND FORMATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | ARYLBORONIC ACIDS | ELECTRON-DEFICIENT OLEFINS
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 3/2012, Volume 41, Issue 8, pp. 3381 - 343
Journal Article
中国科技教育, ISSN 1671-4350, 2017, Issue 8, pp. 30 - 31
选题来源 如今,越来越多的3D初创公司试图挤进当前尚小但是却在不断扩展的增材制造(即3D打印)领域,但3D实物扫描设备的昂贵价格却让人望而却步。在创客教学的课堂上,也需要一个3D扫描的演示装置,让学生更好地领会3D扫描原理。 
3D | 打印 | 立体 | 扫描设备 | 演示装置
Journal Article
Nature Communications, ISSN 2041-1723, 05/2017, Volume 8, Issue 1, p. 14993
Amide and olefins are important synthetic intermediates with complementary reactivity which play a key role in the construction of natural products,... 
AZOLES | DECARBONYLATIVE BORYLATION | ACTIVATION | COUPLING REACTIONS | ARYL ESTERS | MULTIDISCIPLINARY SCIENCES | BONDS | DEHYDROHALOGENATION | CHEMOSELECTIVITY | SILYLATION | HYDROFORMYLATION
Journal Article