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Molecules, ISSN 1420-3049, 12/2018, Volume 23, Issue 12, p. 3325
It has been established that an electron-deficient cationic Cp-E-rhodium(III) complex catalyzes the non-oxidative [2+2+2] annulation of N-(1-naphthyl)acetamide... 
C–H bond cleavage | Rhodium | Cyclopentadienyl complexes | [2+2+2] annulation | N-(1-naphthyl)acetamide | Alkynes | C–N bond cleavage | ACTIVATION | BIOCHEMISTRY & MOLECULAR BIOLOGY | alkynes | ARENES | cyclopentadienyl complexes | CHEMISTRY, MULTIDISCIPLINARY | CYCLOADDITION | C-N bond cleavage | CHEMISTRY | HOMOLOGATION | C-H bond cleavage | rhodium | BENZOIC-ACIDS
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2013, Volume 2013, Issue 29, pp. 6506 - 6509
Biologically attractive trifluoromethyl‐2‐isoxazoline N‐oxides were synthesized in good yields for the first time by the... 
Heterocycles | Fluorine | Organocatalysis | N–O coupling | Hypervalent compounds | Iodine | N-O coupling | TARGET | ISOXAZOLINES | ANTIBACTERIAL | CHEMISTRY, ORGANIC | EPOXIDATION | INHIBITORS | DERIVATIVES | DIARYLPYRROLINES | Oxides | Fluorides | Enantiomers | Benzene
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2018, Volume 54, Issue 64, pp. 8881 - 8884
The highly C-selective difluoromethylation of -ketoesters was achieved by combining TMSCF2Br/LiOH/N,N,N-trimethylhexadecan-1-ammonium bromide. Compared to... 
BETA-KETOESTERS | ALKYLATION | O-DIFLUOROMETHYLATION | DIAZO-COMPOUNDS | SOFT ACIDS | INHIBITORS | FLUOROALKYLATION REACTIONS | DIFLUOROCARBENE REAGENT | EFFICIENT DIFLUOROMETHYLATION | CHEMISTRY, MULTIDISCIPLINARY | 1,3-DIONES
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 64, pp. 8881 - 8884
The highly C-selective difluoromethylation of β-ketoesters was achieved by combining TMSCF2Br/LiOH/N,N,N-trimethylhexadecan-1-ammonium bromide. Compared to... 
Lithium | Lithium hydroxides | Regioselectivity | Ammonium bromides | Base metal | Alkali metals
Journal Article
ACS Catalysis, ISSN 2155-5435, 04/2013, Volume 3, Issue 4, pp. 704 - 712
Over the past few years, iridium complexes have been widely used in the direct functionalization of unactivated bonds. In the presence of iridium catalysts,... 
iridium | alkylation | alcohols | alkenes | carbonates | ORGANIC-SYNTHESIS | HETEROCYCLIC CARBENE | ASTERISK-IR COMPLEX | ALLYLIC ALKYLATION | CHEMISTRY, PHYSICAL | PRIMARY ALCOHOLS | MILD REACTION CONDITIONS | ASYMMETRIC HYDROAMINATION | ALPHA-ALKYLATION | CARBON-CARBON
Journal Article
The Journal of organic chemistry, ISSN 0022-3263, 07/2019, Volume 84, Issue 20, pp. 12773 - 12783
An efficient method for the asymmetric synthesis of 4-imidazolidinones via an iodine-catalyzed intramolecular N-H/C(sp )-H activation of readily available and... 
ORGANIC CATALYSIS | FUNCTIONALIZATION | AMINATION | IMIDAZOLIDIN-4-ONES | HOFMANN-LOEFFLER TYPE | CHEMISTRY, ORGANIC | SULFONAMIDES | RADICALS | CYCLIZATION | CYCLIC AMINES | STRATEGIES
Journal Article
Organic Letters, ISSN 1523-7060, 03/2007, Volume 9, Issue 7, pp. 1215 - 1218
A cationic rhodium(I)/dppb complex catalyzed direct intermolecular hydroacylation of N,N-dialkylacrylamides with both aliphatic and aromatic aldehydes has been... 
CONVENIENT SYNTHESIS | ALKENES | ALKYNE HYDROACYLATION | 4+2 CARBOCYCLIZATION | 4-ALKYNALS | C-H BOND | INTRAMOLECULAR HYDROACYLATION | KINETIC RESOLUTION | CHEMISTRY, ORGANIC | OLEFINS | CYCLOPENTENONES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2013, Volume 52, Issue 21, pp. 5575 - 5579
The cupreidinium salt 1 catalyzes the highly enantioselective conjugate addition of nitromethane to β‐aryl‐β‐trifluoromethyl aryl enones (2). The biologically... 
enantioselectivity | organocatalysis | heterocycles | synthetic methods | fluorine | ALPHA,BETA-UNSATURATED KETONES | ALKYLATION | QUATERNARY AMMONIUM-SALT | CHEMISTRY, MULTIDISCIPLINARY | BOND DONORS | NITROALKANES | CHALCONES | GUANIDINE | ASYMMETRIC MICHAEL ADDITION | BIFUNCTIONAL CINCHONA ORGANOCATALYSTS | PHASE-TRANSFER CATALYSTS
Journal Article
ISSN 1359-7345, 8/2018, Volume 54, Issue 64, pp. 8881 - 8884
The highly C-selective difluoromethylation of β-ketoesters was achieved by combining TMSCF 2 Br/LiOH/ N , N , N -trimethylhexadecan-1-ammonium bromide.... 
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2014, Volume 356, Issue 7, pp. 1516 - 1520
The cationic rhodium‐catalyzed alkenylation proceeds at the C‐8 position of quinoline N‐oxides. Regioselective CH bond activation was achieved by the... 
alkenylation | CH activation | N‐oxides | rhodium catalysts | directing group | C-H activation | N-oxides | PALLADIUM | COMPLEX | ACTIVATION | DIRECT ARYLATION | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | AZINE | CHEMISTRY, APPLIED | Synthesis | Catalysts | Cationic | Quinoline | Activation | Catalysis | Bonding
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 06/2017, Volume 359, Issue 11, pp. 1849 - 1853
The intramolecular reaction of 3‐acetyl‐N‐alkynylindoles proceeded via C−H bond cleavage at the C2 position. Iridium and rhodium catalysts selectively promoted... 
Iridium | C−H activation | Indoles | Rhodium | Alkenylation | NS5B POLYMERASE | ACTIVATION | IRIDIUM CATALYST | HYDROSILYLATION | CHEMISTRY, ORGANIC | ALKYNES | FUNCTIONALIZATION | C-H activation | INDOLE | BIOLOGICAL-ACTIVITY | CHEMISTRY, APPLIED | HYDROHETEROARYLATION | HYDROARYLATION | Cleavage | Hydrogen bonds | Catalysts
Journal Article
APPLIED PHYSICS LETTERS, ISSN 0003-6951, 04/2015, Volume 106, Issue 14
We report the fabrication of high quality thin films for semiconducting organic donor-acceptor charge-transfer (CT) compounds, (diC(8)BTBT)(F(n)TCNQ)... 
PHYSICS, APPLIED | CRYSTALS | ORGANIC SEMICONDUCTORS | FIELD-EFFECT TRANSISTORS
Journal Article
Synthesis, ISSN 0039-7881, 08/2016, Volume 48, Issue 16, pp. 2664 - 2670
Abstract Various planar-chiral 1, n -dioxa[ n ]paracyclophanes possessing a phenolic hydroxyl group have been synthesized via enantioselective ortho... 
special topic | planar chirality | phosphites | paracyclophanes | chiral ligands | 1,4-addition | allylic alkylation | ORTHO-LITHIATION | TADDOL | 4-addition | HYDROGENATION | ARYLATION | CHEMISTRY, ORGANIC | CATALYZED ASYMMETRIC HYDROBORATION | PHOSPHORUS LIGANDS | ENONES | SPIRO PHOSPHORAMIDITE | ALLYLIC SUBSTITUTION | DERIVATIVES
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 03/2018, Volume 13, Issue 5, pp. 496 - 499
α‐Aminoalkylation of N‐arylacrylamides with amino acid derivatives was achieved by silver‐catalysis in moderate to high yields. The reaction provides an... 
oxindoles | aminoalkylation | pyrroloindolines | silver | C−H activation | amino acids | ELECTRON | NICKEL CATALYSIS | RADICAL CATIONS | CHEMISTRY, MULTIDISCIPLINARY | ACTIVATED ALKENES | C-H activation | HETEROCYCLES | COUPLING REACTIONS | LIGHT PHOTOREDOX CATALYSIS | GENERATION | BOND | CARBOXYLIC-ACIDS
Journal Article
Tetrahedron, ISSN 0040-4020, 2012, Volume 68, Issue 5, pp. 1407 - 1416
The asymmetric induction of planar chirality in 1, -dioxa[ ]paracyclophane derivatives via asymmetric -lithiation is described. Enantioselective -lithiation of... 
ortho-Lithiation | Paracyclophane | Enantioselective | Planar chirality | N-BOC PYRROLIDINE | MIXED DIMER | CHEMISTRY, ORGANIC | LITHIUM-AMIDE | GAS-CHROMATOGRAPHY | (+)-SPARTEINE SURROGATE | MESO-EPOXIDES | BRIDGED NADH MODELS | COMPUTER-SIMULATION | CATALYTIC ENANTIOSELECTIVE DEPROTONATION | PARACYCLOPHANES | Enantiomers
Journal Article
Organic Letters, ISSN 1523-7060, 05/2010, Volume 12, Issue 9, pp. 1980 - 1983
Highly enantioselective ortho-lithiation and dilithiation of 1,n-dioxa[n]paracyclophanes were realized with the use of sec-butyllithium and a catalytic or... 
DEPROTONATION | N-BOC PYRROLIDINE | GAS-CHROMATOGRAPHY | (+)-SPARTEINE SURROGATE | MIXED DIMER | MESO-EPOXIDES | CHEMISTRY, ORGANIC | BRIDGED NADH MODELS | COMPUTER-SIMULATION | LITHIUM-AMIDE | FERROCENES | Stereoisomerism | Ethers, Cyclic - chemistry | Catalysis
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 02/2018, Volume 2018, Issue 8, pp. 1067 - 1070
We have developed a method for the synthesis of dihydroquinoxalinones via intramolecular N–H/C–H coupling using hypervalent iodine. The starting materials were... 
Amino acids | Dihydroquinoxalinones | Hypervalent iodine | C–N coupling | C–H functionalization
Journal Article