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iridium (11) 11
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-dichroanone (1) 1
-taiwaniaquinol-b (1) 1
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Synlett, ISSN 0936-5214, 12/2018, Volume 29, Issue 19, pp. 2481 - 2492
Abstract Our lab has long been interested in the development of methods for the creation of enantioenriched all-carbon quaternary stereocenters. Historically,... 
account | iridium | asymmetric catalysis | quaternary stereocenters | allylic alkylation | umpolung | enantioselective | ACID DERIVATIVES | ASYMMETRIC-SYNTHESIS | ENANTIO | MASKED ACYL CYANIDES | PHOSPHORAMIDITE LIGANDS | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE CONSTRUCTION | DIASTEREO | ESTERS | REGIO
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 38, pp. 11545 - 11548
The first highly enantioselective iridium‐catalyzed allylic alkylation that provides access to products bearing an allylic all‐carbon quaternary stereogenic... 
iridium | quaternary stereocenter | carboxylic acid derivatives | allylic alkylation | umpolung | SUBSTITUTION | REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | DIASTEREO | ORIGINS | STEREOCENTERS | CONSTRUCTION | ESTERS | REGIO | ARYL
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 9/2017, Volume 56, Issue 38, pp. 11545 - 11548
The first highly enantioselective iridium-catalyzed allylic alkylation providing access to products bearing an allylic all-carbon quaternary stereogenic center... 
Quaternary Stereocenter | Umpolung | Carboxylic Acid Derivatives | Allylic Alkylation | Iridium
Journal Article
Angewandte Chemie, ISSN 0044-8249, 12/2016, Volume 128, Issue 52, pp. 16326 - 16329
The development of the first enantio‐, diastereo‐, and regioselective iridium‐catalyzed allylic alkylation reaction of prochiral enolates to form an all‐carbon... 
Allylische Alkylierungen | Iridium | Quartäre Stereozentren | Enantioselektive Synthesen | Vicinale Stereozentren | Enolates | Utilities | Chlorides | Transformations | Selectivity | Nucleophiles | Alkylation | Bearing
Journal Article
Angewandte Chemie, ISSN 0044-8249, 2018, Volume 130, Issue 28, pp. 8800 - 8803
The development of the first enantioselective transition‐metal‐catalyzed allylic alkylation providing access to acyclic products bearing vicinal all‐carbon... 
Übergangsmetallkatalyse | Iridium | Quartäre Stereozentren | Enantioselektive Synthese | Allylische Alkylierung | Nitriles | Chemotherapy | Enantiomers | Cancer
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 7, pp. 1527 - 1529
The first enantioselective iridium-catalyzed allylic alkylation reaction of a masked acyl cyanide (MAC) reagent has been developed. The transformation allows... 
CROSS-COUPLINGS | REAGENTS | AMINO-ACID DERIVATIVES | ESTERS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALDEHYDES | DIASTEREO
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 38, pp. 11703 - 11706
The first highly enantioselective iridium‐catalyzed allylic alkylation that provides access to products bearing an allylic all‐carbon quaternary stereogenic... 
Allylische Alkylierungen | Umpolung | Iridium | Quartäre Stereozentren | Carbonsäurederivate | Stereoisomerism | Carboxylic Acids - chemical synthesis | Carboxylic Acids - chemistry | Allyl Compounds - chemistry | Molecular Structure | Catalysis | Iridium - chemistry | Alkylation
Journal Article
Organic Process Research and Development, ISSN 1083-6160, 08/2015, Volume 19, Issue 8, pp. 974 - 981
This account describes our laboratory's efforts in the development of a palladium-catalyzed asymmetric conjugate addition of arylboronic acids to cyclic... 
ALKENYLBORONIC ACIDS | QUATERNARY STEREOGENIC CENTERS | N-HETEROCYCLIC CARBENE | ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | DIALKYLZINC REAGENTS | TRISUBSTITUTED ENONES | CHEMISTRY, APPLIED | GRIGNARD-REAGENTS | ARYL ALUMINUM REAGENTS | MELDRUMS ACIDS | palladium | catalysis | asymmetric | conjugate addition
Journal Article
Organic Letters, ISSN 1523-7060, 12/2014, Volume 16, Issue 24, pp. 6362 - 6365
A catalytic, enantioselective formal synthesis of (+)-dichroanone and (+)-taiwaniaquinone H is reported. The all-carbon quaternary stereocenter was constructed... 
DITERPENES | TAIWANIA-CRYPTOMERIOIDES | CONSTANTS | ASYMMETRIC CONJUGATE ADDITION | BARK | EFFICIENT ROUTE | (+/-)-DICHROANONE | CHEMISTRY, ORGANIC | THUJA-STANDISHII | ARYLBORONIC ACIDS | (+/-)-TAIWANIAQUINOL-B | Molecular Structure | Catalysis | Stereoisomerism | Diterpenes - chemical synthesis | Palladium - chemistry | Diterpenes - chemistry | Letter
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2017, Volume 58, Issue 34, pp. 3341 - 3343
[Display omitted] •Rapid access to enantioenriched spirocycles possessing a 1,4-dicarbonyl moiety spanning an all-carbon quaternary stereogenic spirocenter was... 
Allylic alkylation | Spirocycle | Masked bromomethyl vinyl ketone | Palladium catalysis | Asymmetric catalysis | SCOPE | CONSTRUCTION | CHEMISTRY, ORGANIC | N-HETEROCYCLES | MOLECULES | Palladium | Synthesis | Catalysis | Enantiomers | Organic compounds
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2017, Volume 56, Issue 38, p. 11545
The first highly enantioselective iridium-catalyzed allylic alkylation that provides access to products bearing an allylic all-carbon quaternary stereogenic... 
Amides | Esters | Enantiomers | Organic acids | Cyanide | Quaternary | Cyanides | Carboxylic acids | Iridium | Chemical synthesis | Alkylation
Journal Article
Angewandte Chemie, ISSN 0044-8249, 07/2018, Volume 130, Issue 28, pp. 8800 - 8803
The development of the first enantioselective transition‐metal‐catalyzed allylic alkylation providing access to acyclic products bearing vicinal all‐carbon... 
Stereoselectivity | Quaternary | Malononitrile | Iridium | Nucleophiles | Enantiomers | Chemical synthesis | Carbon | Alkylation
Journal Article
ChemInform, ISSN 0931-7597, 10/2016, Volume 47, Issue 45, pp. no - no
...ChemInform Abstract [33 refs.].   J. Caleb Hethcox , Samantha E. Shockley , Brian M. Stoltz , Iridium‐Catalyzed Diastereo‐, Enantio‐, and Regioselective... 
organic chemistry, review | catalysis, phase‐transfer catalysis | diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) | regioselective reactions | C‐C bond formation | Catalysis | Enolates
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 38, p. 11703
The first highly enantioselective iridium-catalyzed allylic alkylation that provides access to products bearing an allylic all-carbon quaternary stereogenic... 
Amides | Esters | Enantiomers | Organic acids
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 38, p. 11703
The first highly enantioselective iridium-catalyzed allylic alkylation that provides access to products bearing an allylic all-carbon quaternary stereogenic... 
Cyanide | Quaternary | Esters | Amides | Cyanides | Carboxylic acids | Iridium | Enantiomers | Chemical synthesis | Alkylation
Journal Article
ChemInform, ISSN 0931-7597, 10/2015, Volume 46, Issue 42, p. no
Review: [32 refs. 
Palladium | Catalysis
Journal Article
Organic Syntheses, ISSN 0078-6209, 2016, Volume 92, pp. 247 - 266
Journal Article
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