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CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 06/2017, Volume 23, Issue 34, pp. 8295 - 8303
For (pentafluoroethyl) phenylstannanes, (C2F5)(4-n)SnPhn (n=1-3), and dimethylbis(pentafluoroethyl)stannane, (C2F5)(2)SnMe2, a high yield synthesis was... 
halogens | stannanes | TIN | perfluoroalkyl | CHEMISTRY, MULTIDISCIPLINARY | pentafluoroethyl | fluorine
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 05/2019, Volume 55, Issue 34, pp. 4985 - 4988
All-cis-1,3,5-triethynyl-1,3,5-triorganyl-1,3,5-trisilacyclohexanes (organyl R = Me, Ph) offer flexible scaffolds with three concordantly oriented ethynyl... 
WEAK | MERCURY | C-13 | REDISTRIBUTION | SILICON | RADII | EXCHANGE REACTIONS | CRYSTAL | LEWIS-ACIDS | COMPLEXATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 03/2018, Volume 24, Issue 17, pp. 4412 - 4422
In this contribution we report on the synthesis of bis(pentafluoroethyl)stannane, H2Sn(C2F5)(2). In the reaction with donor molecules a ready elimination of... 
subvalent compounds | ANALOGS | stannanes | DIARYLSTANNYLENE | perfluoroalkyl | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE | METAL ALKYLS | GERMANIUM | TIN(II) HYDRIDES | TIN | CHEMISTRY | stannylene | X-RAY STRUCTURES | DERIVATIVES | fluorine
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 03/2018, Volume 24, Issue 17, pp. 4336 - 4342
The tin-tin bond cleavage of hexaorganodistannanes by nucleophiles is a long-known reaction and widely used for stannate formation or stannyl group transfer.... 
isolobal relationship | PENTAFLUOROETHYLLITHIUM | ANION | pseudohalides | I-3(-) | NMR spectroscopy | CHEMISTRY, MULTIDISCIPLINARY | distannanes | tristannates
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 05/2018, Volume 24, Issue 27, pp. 6975 - 6982
Acetonitrile is deprotonated by a combination of the strong Lewis acid (C2F5)(3)PF2 and triethylamine. The resulting cyanomethyl function is bound to the... 
ION BATTERIES | NICKEL-CATALYST | LIQUID | COMPLEXES | Lewis acids | C-H ACTIVATION | SALTS | CHEMISTRY, MULTIDISCIPLINARY | hydroamination | nitriles | gas separation | EQUILIBRIUM | CARBONATE-BASED ELECTROLYTES | SEPARATION | phosphorus
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 11/2016, Volume 22, Issue 46, pp. 16460 - 16466
This paper gives an account on hypervalent fluoro- and chloro(pentafluoroethyl)germanium compounds. The selective synthesis of the... 
PENTACOORDINATED GERMANIUM | COMPLEXES | Lewis acids | fluoride ion affinity | germanate | CHEMISTRY, MULTIDISCIPLINARY | pentafluoroethyl | fluorine
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 11/2016, Volume 22, Issue 48, pp. 17460 - 17467
As recently shown, the introduction of pentafluoroethyl functionalities into silicon compounds is of general interest due to an enhanced Lewis acidity of the... 
halogens | silicon | Lewis acids | CHEMISTRY | perfluoroalkyl | CHEMISTRY, MULTIDISCIPLINARY | fluorine
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 26, pp. 8938 - 8942
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 10/2017, Volume 56, Issue 43, pp. 13259 - 13263
Three compounds with phenyl and pentafluorophenyl rings bridged by (CH2)(3) and (CH2)(2)SiMe2 units were synthesized by hydrosilylation and C-C coupling... 
CATALYSIS | intermolecular pi stacking | BENZENE | CRYSTAL-STRUCTURE | AB-INITIO CALCULATIONS | intramolecular pi stacking | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | LONDON DISPERSION | SINGLE-CRYSTAL | dispersion interactions | bridged arenes | DIMER | CHEMISTRY | gas electron diffraction | HEXAFLUOROBENZENE
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2018, Volume 54, Issue 67, pp. 9294 - 9297
The thermally unstable alpha-fluoroalcohol undecafluorocyclohexanol (c-C6F11OH) was prepared by addition of hydrogen fluoride to the corresponding ketone.... 
COMPLEX | PHASE | TRIFLUOROMETHANOL | WEAKLY COORDINATING ANIONS | GAS ELECTRON-DIFFRACTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 17, pp. 4765 - 4768
One‐electron reduction of C2‐arylated 1,3‐imidazoli(ni)um salts (IPrAr)Br (Ar=Ph, 3 a; 4‐DMP, 3 b; 4‐DMP=4‐Me2NC6H4) and (SIPrAr)I (Ar=Ph, 4 a; 4‐Tol, 4 b)... 
X-ray diffraction | density functional calculations | radicals | EPR spectroscopy | N-heterocyclic carbenes | PERSISTENT | BORON | CATALYZED DIRECT C2-ARYLATION | NHC | IMIDAZOLIUM | CHEMISTRY, MULTIDISCIPLINARY | MAIN-GROUP CHEMISTRY | LIGANDS | DIRADICALS | CYCLIC (ALKYL)(AMINO) CARBENES | IMIDAZOL-2-YLIDENES | Heterocyclic compounds | Salts | Aromatic compounds | Carbenes | Radicals
Journal Article
Journal of Applied Polymer Science, ISSN 0021-8995, 01/2020, Volume 137, Issue 3, pp. 48235 - n/a
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 13, pp. 3244 - 3247
Para-quinodimethane (pQDM) is a fundamental structural component in many -conjugated organic molecules and materials. The incorporation of phosphorus atom into... 
carbenes | main-group elements | heterocycles | quinodimethane | diphosphorus | COORDINATION CHEMISTRY | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2017, Volume 23, Issue 38, pp. 9044 - 9047
Four‐membered biradicaloid compounds containing a N2E2 (E=main group element) framework have been thoroughly investigated; however, the synthesis of stable... 
carbenes | heterocycles | vinylidenes | phosphorus | NON-KEKULE | CARBENE | CHEMISTRY, MULTIDISCIPLINARY | VALENCE ISOMERIZATION | LIGANDS | DIRADICALS | SNAPSHOTS | 1,3-DIPHOSPHACYCLOBUTANE-2,4-DIYL | 4-MEMBERED RING | RADICALS | ACCESS | Heterocyclic compounds | Vinylidene | Phosphorus | Nuclear magnetic resonance--NMR | Temperature effects | Diamagnetism
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 09/2019, Volume 55, Issue 70, pp. 10408 - 10411
The synthesis and characterization of the crystalline diphosphene radical cations [{(NHC)C(Ph)}P](2)(GaCl4) (NHC = IPr = C{(NDipp)CH}(2)3, SIPr =... 
PERSISTENT | ACTIVATION | ANION | CARBENES | CHEMISTRY | IONS | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 22, pp. 4970 - 4976
The direct double carbenylation of 1,4-diiodobenzene and 4,4'-dibromobiphenyl with a classical N-heterocyclic carbene, SIPr (1) (SIPr = :... 
BIS(TRIARYLAMINE) DICATIONS | SHELL SINGLET | CHICHIBABINS | BIRADICALS | CATALYZED DIRECT C2-ARYLATION | CHARACTER | PLANAR NICKEL-COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | VALENCE | ELECTRONIC-STRUCTURE | MOLECULES
Journal Article
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