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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 96 - 115
Recent years have seen rapid advances in the chemistry of small molecules containing electron‐precise boron–boron bonds. This Review provides an overview of... 
main-group chemistry | boron | organoboron chemistry | multiple bonding | transition metals | METAL-PROMOTED REACTIONS | HETEROCYCLIC CARBENE | MOLECULAR-STRUCTURE | AB-INITIO | CHEMISTRY, MULTIDISCIPLINARY | POTENTIAL CURVES | BORYL ANION | DIBORANE COMPOUND | TRANSITION-METAL | DIBORON TETRACHLORIDE | BORON TRIPLE BOND | Control methods | Chemical bonds | Boron
Journal Article
Chemical Society reviews, ISSN 0306-0012, 02/2016, Volume 45, Issue 4, pp. 1112 - 1128
Metal amidoborane compounds of the alkali- and alkaline earth metals have in recent years found applications in diverse disciplines, notably as hydrogen... 
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2/2016, Volume 45, Issue 4, pp. 1112 - 1128
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 48, pp. 15896 - 15901
Sterically unencumbered diborenes based on a benzylphosphine chelate undergo diboration reactions with bis(catecholato)diboron in the absence of a catalyst to... 
low-valent compounds | chain structures | diboration | isomers | boron | HYDROBORATION | TETRACHLORIDE | REACTIVITY | DIBORON COMPOUNDS | BORANE | CHEMISTRY, MULTIDISCIPLINARY | BORATION | BONDS | CHEMISTRY | Phosphine | Chelates
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 15, pp. 4098 - 4102
Cyclic diboranes(4) based on a chelating monoanionic benzylphosphine linker were prepared through boron–silicon exchange between arylsilanes and B2Br4.... 
borylenes | multiple bonds | boron | DFT calculations | rearrangements | CIS-CONFIGURATION | REACTIVITY | TRIPLE BOND | COORDINATION | BORANE | ARYLSILANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Chelation | Cation exchanging | Boron | Boron compounds | Mathematical analysis
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2019, Volume 25, Issue 8, pp. 2025 - 2034
[(BDI)Mg+][B(C6F5)4−] (1; BDI=CH[C(CH3)NDipp]2; Dipp=2,6‐diisopropylphenyl) was prepared by reaction of (BDI)MgnPr with [Ph3C+][B(C6F5)4−]. Addition of... 
Lewis acidity | magnesium | cations | frustrated Lewis pair | alkyne ligands | ALKENES | ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | Raman spectroscopy | Raman spectra | Nuclear magnetic resonance--NMR | Phosphine | Ligands | Cations | Magnesium | Phosphines | Alkynes
Journal Article
Organometallics, ISSN 0276-7333, 01/2016, Volume 35, Issue 2, pp. 207 - 217
The highly Lewis acidic, cationic aluminum species [DIPP-nacnacAlMe]+[B­(C6F5)4]− (1, DIPP-nacnac = [HC­{C­(Me)­N­(2,6- i Pr2C6H3)}2]−) has been shown to... 
CYCLOADDITION REACTIONS | ACTIVATION | DIKETIMINATE ALKYL COMPLEXES | REDUCTION | MOLECULAR-STRUCTURE | CO2 | REACTIVITY | CHEMISTRY, ORGANIC | ADDUCTS | ETHYLENE POLYMERIZATION | C-H | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2013, Volume 52, Issue 43, pp. 11356 - 11359
Carbyne formation: Treatment of a molybdenum ethylene complex with B(C6F5)3 induces ditopic activation of an ethylene ligand and acceptor‐assisted ethane... 
Lewis acids | carbyne ligands | dehydrogenation | multiple bonds | alkene ligands | FREE HYDROGEN ACTIVATION | NOBEL LECTURE | ACTIVE-SITES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL COMPLEXES | TRIAMIDOAMINE LIGANDS | OLEFIN-METATHESIS | CATALYSTS | METAL-CARBON BONDS | PAIRS | Chemical plants | Dehydrogenation | Molybdenum | Ethylene | Lewis acid | Olefins | Ligands | Activation | Carbyne | Ethane
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 01/2018, Volume 140, Issue 2, pp. 848 - 853
The heteroarene 1,4-bis(CAAC)-1,4-diborabenzerie (1; CAAC = cyclic (alkyl)(amino)carbene) reacts with [(MeCN)(3)M(CO)(3)] (M = Cr, Mo, W) to yield... 
TRANSITION-METAL CARBONYLS | DIANIONS | TRIPLET | CRYSTAL-STRUCTURE | PYRIDINE | TRICARBONYL | BORABENZENE | CHEMISTRY | MAGNETIC-RESONANCE SPECTRA | CHROMIUM | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2019, Volume 141, Issue 37, pp. 14898 - 14903
A compound with a boron–boron triple bond is shown to undergo stepwise hydroboration reactions with catecholborane to yield an unsymmetrical... 
DEPROTONATION | BORON | NEUTRAL DIBORENE | REDUCTION | CHEMISTRY, MULTIDISCIPLINARY | COMPOUND
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 05/2018, Volume 57, Issue 21, pp. 6347 - 6351
Herein we report the discovery that two bottleable, neutral, base-stabilized diborane(5) compounds are able to bind strongly to a number of copper(I) complexes... 
ACTIVATION | sigma-complexes | MOLYBDENUM | COMPLEXES | RUTHENIUM | MONOBORANE | diboranes | TRANSITION-METALS | CHEMISTRY, MULTIDISCIPLINARY | BORANE ADDUCT | COORDINATION-COMPOUNDS | density functional theory | BONDS | copper | boron
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2018, Volume 54, Issue 65, pp. 9015 - 9018
A carbene-stabilised neutral boryl radical and a boryl anion are isolated via selective one- and two-electron reduction of a diamidocarbene (DAC) adduct of... 
BORYL ANION | TRIARYLBORON ANIONS | BORON-STABILIZED CARBANION | TRIMESITYLBORON | REACTIVITY | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANE | 1,3,2,5-DIAZADIBORININE | RADICAL-ANION | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
Chemical science (Cambridge), ISSN 2041-6539, 2020, Volume 11, Issue 5, pp. 1335 - 1341
Compounds containing boron–boron double and triple bonds are shown to undergo uncatalysed hydrophosphination reactions with diphenylphosphine. Five compounds... 
PHOSPHORUS | HYDROBORATION | ACTIVATION | ANALOGS | PHOSPHINES | CHEMISTRY | COORDINATION | PHOSPHINOBORANES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2019, Volume 48, Issue 11, pp. 3547 - 3550
AsCl and AsBr are shown to undergo oxidative addition to Pt(0) complexes. With AsCl , a single As–Cl oxidative addition step selectively yields... 
D-BLOCK | COMPLEXES | REACTIVITY | CHEMISTRY | COORDINATION | BISMUTH | BOND | PHOSPHAALKENES | ANTIMONY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 10/2012, Volume 31, Issue 19, pp. 6960 - 6965
An ionic chromium(III) species, [CrCl2(THF)4][Al(OC4F9)4] (2), has been synthesized and is shown to react with a variety of bidentate diphosphine ligands to... 
TETRAMERIZATION | OXIDATION | DIPHOSPHINE LIGANDS | MECHANISM | COMPLEXES | CHEMISTRY, ORGANIC | ETHENE TRIMERIZATION | CHROMIUM | CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article