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Organometallics, ISSN 0276-7333, 12/2018, Volume 37, Issue 24, pp. 4699 - 4710
While alkyne insertion into metal–carbon­(sp2) bonds is common in transition metal chemistry, direct alkyne insertions into E–C­(sp2) bonds are very rare in... 
ELECTROPHILIC AROMATIC-SUBSTITUTION | PHOSPHIRENE | C-C | CHEMISTRY, ORGANIC | CARBON SIGMA-BONDS | TUNGSTEN(II)-CATALYZED REARRANGEMENTS | OXIDES | MAIN-GROUP ELEMENTS | DERIVATIVES | ELECTROLUMINESCENCE | ALKENYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 07/2016, Volume 35, Issue 14, pp. 2367 - 2377
The complex [W­(CO)5{PClPh2}] reacts with AlCl3 to form a mixture of the phosphenium complex [W­(CO)5{PPh2}]­[AlCl4] and an isocarbonyl, with GaCl3 to form... 
PERTURBATION-THEORY | MOLECULAR CALCULATIONS | PHOSPHINE | LIGANDS | EFFECTIVE CORE POTENTIALS | LEWIS-ACID | CHEMISTRY, ORGANIC | PHOSPHENIUM COMPLEXES | CATION | METAL-COMPLEXES | MONOVALENT PHOSPHORUS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2019, Volume 880, pp. 68 - 74
Abstraction of chloride from [Fe(CO)4(PPh2Cl)] (1) in the presence of PPh3 leads to [Fe(CO)4(PPh2(PPh3))][AlCl4] (2), an iron complex of a... 
Iron | Electrophilic aromatic substitution | Phosphine | Phosphenium ion | Ferrocene | MONOXIDE | COMPLEXES | CHEMISTRY, ORGANIC | LIGAND | EXCHANGE | CATIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 09/2009, Volume 28, Issue 17, pp. 4906 - 4908
Coordination of bis-phosphino diyne substrates to mixed platinum and tungsten metal templates results in a templated 4 + 2 alkyne−diyne cycloaddition reaction... 
SINGLE-CRYSTAL TRANSFORMATION | CIS-PHOSPHINOACETYLENE COMPLEXES | COORDINATION POLYMER | ASYMMETRIC-SYNTHESIS | PLATINUM(II) COMPLEXES | DIELS-ALDER REACTION | CHEMISTRY, ORGANIC | ACETYLENES HELD PROXIMATE | PT-C6F5 BOND | SOLID-STATE | CYCLOAROMATIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 01/2014, Volume 33, Issue 2, pp. 522 - 530
The phosphirenyl cation complex [W(CO)5{PC(Ph)C(Ph)}]+ (2) is formed by chloride abstraction from the chlorophosphirene complex [W(CO)5{P(Cl)C(Ph)C(Ph)}] (1)... 
DENSITY | PHOSPHORUS | LIGANDS | CRYSTAL-STRUCTURE | COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | CATIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 02/2013, Volume 32, Issue 3, pp. 745 - 747
Reaction of K2[W(CO)5] with Cl2PN-i-Pr2 in the presence of diphenylacetylene leads to the tungsten aminophosphirene complex [W(CO)5{P(N-i-Pr2)C(Ph)C(Ph)}] (1),... 
RHODIUM | LIGANDS | ELECTROPHILIC PHOSPHINIDENE COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | METAL MULTIPLE BONDS | IONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 06/2011, Volume 30, Issue 11, pp. 2933 - 2938
Reaction of the chloroisopropylphosphido complex [Cp*Mo(CO)3{P(Cl)i-Pr}] (1) with AlCl3 generates the transient cationic alkylphosphinidene complex... 
INSERTION | MOLYBDENUM | RING | BOND-FORMING REACTIONS | PHOSPHORUS ANALOGS | PHOSPHIRENE COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | TUNGSTEN | ACCESS | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 05/2015, Volume 44, Issue 19, pp. 8788 - 8791
In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with... 
LIGANDS | MOLYBDENUM | CATIONIC PHOSPHENIUM COMPLEXES | REACTIVITY | PHOSPHITE | SUBSTITUTION REACTIONS | CHEMISTRY, INORGANIC & NUCLEAR | Substitution reactions | Methodology | Bonding | Chlorides | Phosphines | Unsaturated
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 05/2015, Volume 44, Issue 19, pp. 8788 - 8791
In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with... 
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 11/2013, Volume 745-746, pp. 347 - 355
The electrophilic terminal aminophosphinidene complex [CpFe(CO)2P{N-i-Pr2}][X] (Cp = cyclopentadienyl, i-Pr = isopropyl, X = AlCl4 or NaBPh4), generated from... 
Phosphinidene | Cycloaddition | Phosphorus heterocycle | Metal-mediated synthesis | TRANSITION-METAL-COMPLEXES | MOLYBDENUM | REACTIVITY | CHEMISTRY, ORGANIC | RUTHENIUM | IRON | CRYSTAL | CHEMISTRY, INORGANIC & NUCLEAR | RING | PLATINUM(II) | CHEMISTRY | DERIVATIVES | Azo compounds
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 03/2015, Volume 44, Issue 12, pp. 5555 - 5568
The chemistry of the heterobinuclear platinum-iridium complex [PtIr(CO)3(μ-dppm)2][PF6], 1, dppm = Ph2PCH2PPh2, is described. The reaction of a hydride with 1... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 03/2015, Volume 44, Issue 12, pp. 5555 - 5568
The chemistry of the heterobinuclear platinum-iridium complex [PtIr(CO)(3)(mu-dppm)(2)][PF6], 1, dppm = Ph2PCH2PPh2, is described. The reaction of a hydride... 
HETEROBINUCLEAR COMPLEXES | REVERSIBLE DISPLACEMENT | METAL-METAL BOND | MOLECULAR A-FRAMES | RAY CRYSTAL-STRUCTURES | X-RAY | REDUCTIVE ELIMINATION-REACTIONS | DIPLATINUM COMPLEXES | OXIDATIVE ADDITION | HETEROBIMETALLIC COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Synthesis (chemistry) | Luminescence | Ligands | Derivatives | Iridium | Displacement | Alkynes
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 07/2014, Volume 761, pp. 84 - 92
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY A, ISSN 1089-5639, 05/2011, Volume 115, Issue 19, pp. 4951 - 4958
Quantum chemistry calculations are used to provide insight into the cycloaddition of two dialkyne chains in initially monocyclic organoplatinum dimers of the... 
CIS-PHOSPHINOACETYLENE COMPLEXES | AROMATICITY | STATES | SYMMETRY | ALKYNE-ALKYNE INTERACTIONS | PERICYCLIC-REACTIONS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY | CHEMISTRY, PHYSICAL | DIYNE | ACETYLENES HELD PROXIMATE | MOLECULES | Ring formation (Chemistry) | Chemical properties | Quantum chemistry | Analysis | Organometallic compounds
Journal Article
Organometallics, ISSN 0276-7333, 01/2010, Volume 29, Issue 2, pp. 484 - 490
The terminal electrophilic phosphinidene complex [CpFe(CO)2{PN-i-Pr2}][AlCl4] (2), generated via chloride abstraction from [CpFe(CO)2{P(Cl)N-i-Pr2}] (1),... 
CARBONYL-COMPLEXES | MOLYBDENUM | PHOSPHORUS ANALOGS | X-RAY | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | TERMINAL-PHOSPHINIDENE | TUNGSTEN | FORMING REACTIONS | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal Article
Organometallics, ISSN 0276-7333, 02/2007, Volume 26, Issue 4, pp. 925 - 937
Reaction of the terminal electrophilic phosphinidene complexes [Cp*M(CO)3{PN(i-Pr)2}][AlCl4] (3, M = Mo; 4, M = W) with PEt3 results in replacement of a metal... 
AMINOPHOSPHINIDENE COMPLEXES | COORDINATION CHEMISTRY | TRANSITION-METAL-COMPLEXES | CARBENE-LIKE CHEMISTRY | SILYLPHOSPHANES | CRYSTAL-STRUCTURE | RICH PHOSPHANES | X-RAY | CHEMISTRY, ORGANIC | STRUCTURAL-CHARACTERIZATION | RUTHENIUM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2005, Volume 127, Issue 14, pp. 5038 - 5039
Reaction of [Pt(CH3)2(COD)] (COD = 1,5-cyclooctadiene) with Ph2PC⋮CC⋮CPPh2 led to a mixture of [{Pt(CH3)2}2(μ-Ph2PC4PPh2)2] (1) and... 
8-MEMBERED RING COMPOUNDS | CHEMISTRY | CIS-PHOSPHINOACETYLENE COMPLEXES | ALKYNE-ALKYNE INTERACTIONS | CHEMISTRY, MULTIDISCIPLINARY | ACETYLENES HELD PROXIMATE | Butadiene | Chemical properties
Journal Article
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