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Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2019, Volume 880, pp. 68 - 74
Abstraction of chloride from [Fe(CO)4(PPh2Cl)] (1) in the presence of PPh3 leads to [Fe(CO)4(PPh2(PPh3))][AlCl4] (2), an iron complex of a... 
Iron | Electrophilic aromatic substitution | Phosphine | Phosphenium ion | Ferrocene | MONOXIDE | COMPLEXES | CHEMISTRY, ORGANIC | LIGAND | EXCHANGE | CATIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 12/2018, Volume 37, Issue 24, pp. 4699 - 4710
While alkyne insertion into metal–carbon­(sp2) bonds is common in transition metal chemistry, direct alkyne insertions into E–C­(sp2) bonds are very rare in... 
ELECTROPHILIC AROMATIC-SUBSTITUTION | PHOSPHIRENE | C-C | CHEMISTRY, ORGANIC | CARBON SIGMA-BONDS | TUNGSTEN(II)-CATALYZED REARRANGEMENTS | OXIDES | MAIN-GROUP ELEMENTS | DERIVATIVES | ELECTROLUMINESCENCE | ALKENYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ACS Omega, ISSN 2470-1343, 11/2017, Volume 2, Issue 11, pp. 7849 - 7861
Abstraction of chloride from [W­(CO)5{PPhCl2}] with AgOSO2CF3 leads to the phosphine triflate complex [W­(CO)5{PPhCl­(OSO2CF3)}] which undergoes electrophilic... 
N-HETEROCYCLIC PHOSPHENIUM | ASYMMETRIC-SYNTHESIS | EFFECTIVE CORE POTENTIALS | MOLECULAR-ORBITAL METHODS | BIDENTATE DIPHOSPHINE LIGANDS | COMPLEXES | X-RAY | BOND FORMATION | BASIS-SET | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHORUS-COMPOUNDS
Journal Article
Organometallics, ISSN 0276-7333, 07/2016, Volume 35, Issue 14, pp. 2367 - 2377
The complex [W­(CO)5{PClPh2}] reacts with AlCl3 to form a mixture of the phosphenium complex [W­(CO)5{PPh2}]­[AlCl4] and an isocarbonyl, with GaCl3 to form... 
PERTURBATION-THEORY | MOLECULAR CALCULATIONS | PHOSPHINE | LIGANDS | EFFECTIVE CORE POTENTIALS | LEWIS-ACID | CHEMISTRY, ORGANIC | PHOSPHENIUM COMPLEXES | CATION | METAL-COMPLEXES | MONOVALENT PHOSPHORUS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 05/2015, Volume 44, Issue 19, pp. 8788 - 8791
In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 05/2015, Volume 44, Issue 19, pp. 8788 - 8791
In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with... 
LEWIS-ACID | MOLYBDENUM | 2-COORDINATE PHOSPHORUS CATIONS | REACTIVITY | TUNGSTEN | PHOSPHITE | IONS | PHOSPHENIUM COMPLEXES | SUBSTITUTION REACTIONS | 14 ELEMENT LIGAND | CHEMISTRY, INORGANIC & NUCLEAR | Substitution reactions | Methodology | Bonding | Chlorides | Phosphines | Unsaturated
Journal Article
ISSN 1477-9226, 5/2015, Volume 44, Issue 19, pp. 8788 - 8791
In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with... 
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 03/2015, Volume 44, Issue 12, pp. 5555 - 5568
The chemistry of the heterobinuclear platinum-iridium complex [PtIr(CO)3(μ-dppm)2][PF6], 1, dppm = Ph2PCH2PPh2, is described. The reaction of a hydride with 1... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 03/2015, Volume 44, Issue 12, pp. 5555 - 5568
The chemistry of the heterobinuclear platinum-iridium complex [PtIr(CO)(3)(mu-dppm)(2)][PF6], 1, dppm = Ph2PCH2PPh2, is described. The reaction of a hydride... 
HETEROBINUCLEAR COMPLEXES | REVERSIBLE DISPLACEMENT | METAL-METAL BOND | MOLECULAR A-FRAMES | RAY CRYSTAL-STRUCTURES | X-RAY | REDUCTIVE ELIMINATION-REACTIONS | DIPLATINUM COMPLEXES | OXIDATIVE ADDITION | HETEROBIMETALLIC COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Synthesis (chemistry) | Luminescence | Ligands | Derivatives | Iridium | Displacement | Alkynes
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 07/2014, Volume 761, pp. 84 - 92
Journal Article
Organometallics, ISSN 0276-7333, 01/2014, Volume 33, Issue 2, pp. 522 - 530
The phosphirenyl cation complex [W(CO)5{PC(Ph)C(Ph)}]+ (2) is formed by chloride abstraction from the chlorophosphirene complex [W(CO)5{P(Cl)C(Ph)C(Ph)}] (1)... 
DENSITY | PHOSPHORUS | LIGANDS | CRYSTAL-STRUCTURE | COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | CATIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 11/2013, Volume 745-746, pp. 347 - 355
The electrophilic terminal aminophosphinidene complex [CpFe(CO)2P{N-i-Pr2}][X] (Cp = cyclopentadienyl, i-Pr = isopropyl, X = AlCl4 or NaBPh4), generated from... 
Phosphinidene | Cycloaddition | Phosphorus heterocycle | Metal-mediated synthesis | TRANSITION-METAL-COMPLEXES | MOLYBDENUM | REACTIVITY | CHEMISTRY, ORGANIC | RUTHENIUM | IRON | CRYSTAL | CHEMISTRY, INORGANIC & NUCLEAR | RING | PLATINUM(II) | CHEMISTRY | DERIVATIVES | Azo compounds
Journal Article
Leader Post, ISSN 0839-2870, 05/2013
Newspaper Article
Star - Phoenix, ISSN 0832-4174, 03/2013
Predictions that the prairies will experience increasingly extreme weather, including both drought and flooding, means that the future may hold conditions... 
Public access | Colleges & universities | Pastures | Drought | Environmental protection | Biological diversity
Newspaper Article
Organometallics, ISSN 0276-7333, 02/2013, Volume 32, Issue 3, pp. 745 - 747
Reaction of K2[W(CO)5] with Cl2PN-i-Pr2 in the presence of diphenylacetylene leads to the tungsten aminophosphirene complex [W(CO)5{P(N-i-Pr2)C(Ph)C(Ph)}] (1),... 
RHODIUM | LIGANDS | ELECTROPHILIC PHOSPHINIDENE COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | METAL MULTIPLE BONDS | IONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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