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1. Full Text A "renaissance" in radical trifluoromethylation
by Studer, Armido
Angewandte Chemie - International Edition, ISSN 1433-7851, 09/2012, Volume 51, Issue 36, pp. 8950 - 8958
This Minireview highlights recent developments in radical trifluoromethylation reactions. The trifluoromethyl group belongs to the privileged moieties in... 
radical reactions | trifluoromethylation | aromatic substitution | synthetic methods | ALPHA-TRIFLUOROMETHYLATION | ALKYL RADICALS | CARBON MULTIPLE BONDS | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | COPPER-CATALYZED TRIFLUOROMETHYLATION | SILYL ENOL ETHERS | PHOTOCHEMICAL TRIFLUOROMETHYLATION | PERFLUOROALKYL IODIDES | ELECTROPHILIC TRIFLUOROMETHYLATION | CF3-TRANSFER REAGENTS | Alkenes - chemistry | Oxidation-Reduction | Free Radicals - chemistry | Pharmaceutical Preparations - chemistry | Hydrocarbons, Fluorinated - chemistry | Catalysis | Methylation | Ruthenium - chemistry | Pharmaceutical industry | Drugs | Agricultural chemicals | Covering | Alkenes | Aromatic compounds | Radicals
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2. Full Text Iminyl‐Radicals by Oxidation of α‐Imino‐oxy Acids: Photoredox‐Neutral Alkene Carboimination for the Synthesis of Pyrrolines
by Jiang, Heng and Studer, Armido
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 40, pp. 12273 - 12276
The visible‐light‐promoted decarboxylation of α‐imino‐oxy propionic acids for the generation of iminyl radicals has been accomplished through the use of... 
decarboxylation | radicals | heterocycles | photochemistry | synthetic methods
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3. Full Text Catalysis of Radical Reactions: A Radical Chemistry Perspective
by Studer, Armido and Curran, Dennis P
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 1, pp. 58 - 102
The area of catalysis of radical reactions has recently flourished. Various reaction conditions have been discovered and explained in terms of catalytic... 
reaction mechanisms | kinetics | reactive intermediates | radical anions | radical cations | ARYL GRIGNARD-REAGENTS | HYDROGEN-ATOM ABSTRACTION | BOND-FORMING REACTIONS | TRANSFER CYCLIZATION REACTIONS | SINGLE-ELECTRON TRANSMETALATION | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | C-C BOND | SECONDARY ALKYL-HALIDES | POLARITY-REVERSAL CATALYSIS | AROMATIC-SUBSTITUTION BHAS | Thermodynamics | Molecular Structure | Catalysis | Kinetics | Free Radicals - chemistry | Organic Chemicals - chemistry | Tomatoes | Rodents | Color | Catalysts | Reaction kinetics | Chemical reactions | Substrates | Lenses
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4. Full Text The electron is a catalyst
by Studer, Armido and Curran, Dennis P
Nature Chemistry, ISSN 1755-4330, 2014, Volume 6, Issue 9, pp. 765 - 773
The electron is an efficient catalyst for conducting various types of radical cascade reaction that proceed by way of radical and radical ion intermediates.... 
TERT-BUTOXIDE | ORGANIC-SYNTHESIS | METAL-FREE CONDITIONS | C-H-ARYLATION | CHAIN REACTIONS | ARYL HALIDES | ADDITION-REACTIONS | ACYL RADICALS | LIVING RADICAL POLYMERIZATIONS | CHEMISTRY, MULTIDISCIPLINARY | HOMOLYTIC AROMATIC-SUBSTITUTION | Free Radicals | Catalysis | Electrons
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5. Full Text Nitroxides: Applications in Synthesis and in Polymer Chemistry
by Tebben, Ludger and Studer, Armido
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2011, Volume 50, Issue 22, pp. 5034 - 5068
This Review describes the application of nitroxides to synthesis and polymer chemistry. The synthesis and physical properties of nitroxides are discussed... 
oxidation | polymerization | functional materials | radical chemistry | synthetic methods | TERTIARY ALLYLIC ALCOHOLS | TEMPO-MEDIATED OXIDATION | X-RAY-STRUCTURE | FREE-RADICAL POLYMERIZATION | SUPERCRITICAL CARBON-DIOXIDE | GRAPHITE FELT ELECTRODE | SPIN CAPTURING POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | POLY(METHYL METHACRYLATE)/POLYSTYRENE BRUSHES | SELECTIVE AEROBIC OXIDATION | TRANSITION-METAL-FREE | Polymer chemistry
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6. Full Text Transition‐Metal‐Free Trifluoromethylaminoxylation of Alkenes
by Li, Yi and Studer, Armido
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2012, Volume 51, Issue 33, pp. 8221 - 8224
No transition metal! Fluorinated hypervalent‐iodine reagents react with TEMPONa in the presence of an alkene under mild conditions to give the corresponding... 
trifluoromethylation | single‐electron transfer | TEMPO | radicals | synthetic methods | MEDIATED TRIFLUOROMETHYLATION | single-electron transfer | POLAR CROSSOVER REACTIONS | RUTHENIUM(II) COMPLEX | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | COPPER-CATALYZED TRIFLUOROMETHYLATION | SILYL ENOL ETHERS | CHEMISTRY | RADICAL TRIFLUOROMETHYLATION | PERFLUOROALKYL IODIDES | Alkenes - chemistry | Hydrocarbons, Fluorinated - chemical synthesis | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Olefins | Stereoselectivity | Transition metals | Trapping | Alkenes | Fluorination | Radicals | Alcohols
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