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Helvetica Chimica Acta, ISSN 0018-019X, 10/2017, Volume 100, Issue 10, pp. e1700181 - n/a
Journal Article
Organometallics, ISSN 0276-7333, 03/2016, Volume 35, Issue 5, pp. 758 - 761
Molybdenum imido alkylidene and tungsten oxo alkylidene complexes that contain a tridentate “pincer” [ONO]2– ligand have been prepared and treated with... 
REACTIONS NOBEL LECTURE | OPENING METATHESIS POLYMERIZATION | IMIDO ALKYLIDENE | ALKENE METATHESIS | CHEMISTRY | CHEMISTRY, ORGANIC | MAP COMPLEXES | CATALYSTS | METAL-CARBON BONDS | TRIDENTATE LX2 LIGANDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 10/2016, Volume 35, Issue 20, pp. 3587 - 3593
In the interest of preparing molybdenum and tungsten alkylidene complexes for olefin metathesis that are longer-lived at high temperatures (∼150 °C or above),... 
METALLACYCLOBUTANE COMPLEXES | OXIDATION | CARBON BONDS | ALKANE METATHESIS | PINCER LIGAND | PYRIDINE | CHEMISTRY | CHEMISTRY, ORGANIC | POLYMERIZATION | DEHYDROGENATION-OLEFIN-METATHESIS | TRIDENTATE LX2 LIGANDS | CHEMISTRY, INORGANIC & NUCLEAR | Chemistry
Journal Article
Dalton Transactions, ISSN 1477-9226, 5/2014, Volume 43, Issue 21, pp. 765 - 7667
The asymmetric reduction of ketones and imines by transfer of hydrogen from isopropanol as the solvent catalyzed by metal complexes is a very useful method for... 
TETRADENTATE LIGAND | KETONES | N-N-P | PRECATALYSTS | DIHYDROGEN | MECHANISM | ACETOPHENONE | COMPLEXES | RUTHENIUM | STEREOSELECTIVE HYDROGENATION | CHEMISTRY, INORGANIC & NUCLEAR | Synthesis | Asymmetry | Catalysts | Ligands | Activation | Iron | Catalysis | Hydrogenation
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 4, pp. 1367 - 1380
After their treatment with LiAlH4 and then alcohol, new iron dicarbonyl complexes mer-trans-[Fe­(Br)­(CO)2(P–CHN–P′)]­[BF4] (where P–CHN–P′ =... 
DENSITY FUNCTIONALS | DIHYDROGEN | MECHANISM | ACETOPHENONE | ENANTIOSELECTIVE HYDROGENATION | TRICARBONYL | COOPERATIVE TRANSITION-METAL | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | HETEROLYTIC CLEAVAGE | HYDRIDE | Density functionals | Usage | Iron compounds | Research | Nuclear magnetic resonance | Ketones
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2017, Volume 7, Issue 1, pp. 316 - 326
Our group previously reported the development of iron carbonyl catalysts bearing chiral tridentate P–N–P′ ligands for the asymmetric hydrogenation of prochiral... 
ketone | hydride | iron catalysis | mechanism | asymmetric hydrogenation | ALKENE HYDROGENATION | NEUTRON-DIFFRACTION | CHEMISTRY, PHYSICAL | HOMOGENEOUS HYDROGENATION | SELECTIVE HYDROGENATION | EFFICIENT HYDROGENATION | ENANTIOSELECTIVE HYDROGENATION | TRANSITION-METAL | CHIRAL BRONSTED ACID | NONRIGID 6-COORDINATE MOLECULES | BIFUNCTIONAL ADDITION
Journal Article
Organometallics, ISSN 0276-7333, 08/2011, Volume 30, Issue 16, pp. 4418 - 4431
A series of five (S,S)-trans-[Fe(CO)(Br)(PR2-CH2CHNCH(Ph)CH(Ph)NCHCH2-PR2)][X] compounds (1a–c, X = BPh4; 1d,e, X = BF4) were synthesized and tested for the... 
TETRADENTATE LIGAND | OXIDATION | DESIGN | AROMATIC KETONES | AMINO ALCOHOL | HYDROSILYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | EFFICIENT | DIAMINE LIGANDS | EPOXIDATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2014, Volume 136, Issue 12, pp. 4746 - 4760
The fragmentation of the 1,1,2-tris­(diphenylphosphino)­ethane ligand in [RuCp*­((Ph2P)2CHCH2PPh2)]­[PF6] (1) was explored through treatment with base under... 
P-C BOND | PLATINUM-CATALYZED HYDROPHOSPHINATION | ASYMMETRIC-SYNTHESIS | H BOND | AMIDO COMPLEXES | MOLECULAR-STRUCTURE | DENSITY-FUNCTIONAL THEORY | RING-METHYL ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2015, Volume 44, Issue 27, pp. 12119 - 12127
Our group has developed a series of iron-based asymmetric transfer hydrogenation (ATH) catalysts for the reduction of polar double bonds. The activation of the... 
Pathways | Asymmetry | Catalysts | Ligands | Hydrides | Iron | Decomposition | Catalysis
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2015, Volume 44, Issue 27, pp. 12119 - 12127
Our group has developed a series of iron-based asymmetric transfer hydrogenation (ATH) catalysts for the reduction of polar double bonds. The activation of the... 
ALCOHOLS | MILD | PSEUDOPOTENTIALS | KETONE HYDROGENATION | N-P LIGANDS | EFFICIENT HYDROGENATION | ACETOPHENONE | PINCER COMPLEXES | ESTERS | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 09/2012, Volume 31, Issue 18, pp. 6589 - 6594
Journal Article
Chemical Communications, ISSN 1359-7345, 05/2014, Volume 50, Issue 36, pp. 4707 - 4710
A simple method for synthesizing diphosphine monosulfide species was developed utilizing lithium sulfide and chlorophosphine starting materials. This afforded... 
MONOSULFIDE | DIPHENYLPHOSPHINOUS ACID-DERIVATIVES | MOLECULAR-STRUCTURE | SULFIDES | CRYSTAL-STRUCTURE | PHOSPHINES | PHOSPHORUS-ACIDS | CHEMISTRY | MOLYBDENUM CARBONYL-COMPLEXES | BITE ANGLE | CHEMISTRY, MULTIDISCIPLINARY | Sulfides | Synthesis | Precursors | Lithium | Ligands | Sulfur | Ruthenium compounds
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2012, Volume 51, Issue 17, pp. 9322 - 9332
Journal Article
Organometallics, ISSN 0276-7333, 09/2012, Volume 31, Issue 18, pp. 6589 - 6594
Journal Article
Organometallics, ISSN 0276-7333, 09/2012, Volume 31, Issue 18, pp. 6589 - 6594
A series of four tripodal polyphosphine ligands (PAr2)2CHCH2PAr2 (1a–d) were synthesized and coordinated to ruthenium to produce the complexes... 
Journal Article
Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, 04/2014, Volume 70, Issue 4, pp. m144 - m144
In the title compound, [FeBr(C9H9NO2S)(C30H30N2P2)][B(C6H5)4], the FeIIion is in a distorted octahedral CBrN2P2coordination geometry with a P—Fe—P angle of... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 03/2014, Volume 43, Issue 10, pp. 4137 - 4145
The phosphido complex RuCp*(PPh2CH=CHPPh2)(PPh2) (1) was exposed to a number of small molecules and was found to recognize and activate molecular oxygen in an... 
TRANSITION-ELEMENTS | MECHANISTIC ASPECTS | CYTOCHROME-C-OXIDASE | O-2 ACTIVATION | CATALYZED OXIDATION | OXYGEN-BINDING | N-HYDROXYPHTHALIMIDE | BASIS-SETS | ALKENE EPOXIDATION | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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