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Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 1/2009, Volume 82, Issue 1, pp. 29 - 49
New reactivities of silylboranes are described with their applications to organic synthesis. The silylboranes add to unsaturated organic compounds such as... 
ORGANOBORON COMPOUNDS | C BOND-CLEAVAGE | TRANSITION-METAL-COMPLEXES | ASYMMETRIC SILABORATION | HETEROATOM BONDS | GEM-SILYLBORYLATION | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED REGIOSELECTIVE SILABORATION | PLATINUM COMPLEXES | INTRAMOLECULAR BIS-SILYLATION
Journal Article
The Chemical Record, ISSN 1527-8999, 10/2010, Volume 10, Issue 5, pp. 348 - 358
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2011, Volume 50, Issue 38, pp. 8844 - 8847
Taking a new turn: An asymmetric Suzuki–Miyaura coupling of 1‐bromo‐2‐naphthalenephosphonic esters with o‐methyl‐substituted phenylboronic acids proceeds with... 
ligand design | asymmetric synthesis | biaryls | cross‐coupling | helical structures | cross-coupling | SCREW-SENSE | CATALYSIS | POLYMERS | COMPLEXES | LIVING POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | POLY(QUINOXALINE-2,3-DIYL)S | ABSOLUTE-CONFIGURATION | LIGANDS | 1,2-DIISOCYANOBENZENES | WATER
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2010, Volume 132, Issue 8, pp. 2548 - 2549
A differentially protected diboron bearing the naphthalene-1,8-diaminato group on one of the two boron atoms undergoes highly regioselective diboration with... 
PALLADIUM | ROUTE | CATALYZED ENANTIOSELECTIVE DIBORATION | PLATINUM-CATALYZED DIBORATION | ALPHA,BETA-UNSATURATED ESTERS | ALLENES | EFFICIENT | TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | BETA-BORATION | BORYLATION | Naphthalene | Platinum | Analysis | Olefins | Substitution reactions | Iridium | Chemical properties
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 50, pp. 6867 - 6870
Poly(quinoxaline-2,3-diyl)s bearing (S)-3-octyloxymethyl and n-propoxymethyl side chains show an abnormal sergeants-and-soldiers effect in n-alkane solvents,... 
Solvents | Alkanes | Homology | Soldiers | Discrimination | Heptanes
Journal Article
Chemistry Letters, ISSN 0366-7022, 8/2017, Volume 46, Issue 8, pp. 1169 - 1172
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2015, Volume 137, Issue 8, pp. 2852 - 2855
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2009, Volume 131, Issue 22, pp. 7502 - 7503
o-C−H silylation of arylboronic acids has been achieved using 2-pyrazol-5-ylaniline as an ortho-directing agent, which was temporarily attached to the boronyl... 
ORGANOBORON COMPOUNDS | CARBON BOND | HYDROSILANES | VINYLSILANES BEARING | BOND FORMATION | HYDROXY GROUP | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | POLYSUBSTITUTED AROMATICS | OLIGOARENES | Hydroxides | Ruthenium | Pyridazine | Chemical properties | Structure | Organoboron compounds | Iodine
Journal Article
Chemistry Letters, ISSN 0366-7022, 12/2017, Volume 46, Issue 12, pp. 1793 - 1796
Acetylenedicarboxylates undergo trans-addition of tetraalkoxydiboron in THF at 60 °C in the presence of 4,4′-bipyridine (5 mol %) as a catalyst to give... 
Diboration | Organocatalyst | Organoboron compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 25, pp. 7126 - 7130
Journal Article
ISSN 1359-7345, 6/2018, Volume 54, Issue 5, pp. 6867 - 687
Poly(quinoxaline-2,3-diyl)s bearing ( S )-3-octyloxymethyl and n -propoxymethyl side chains show an abnormal sergeants-and-soldiers effect in n -alkane... 
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 09/2018, Volume 13, Issue 17, pp. 2414 - 2417
Suzuki–Miyaura coupling of nonbenzylic α‐(acylamino)alkylboron compounds with aryl halides is established. A Pd/PCy2Ph catalyst promotes the reaction... 
palladium | asymmetric synthesis | stereospecific reaction | organoboron compounds | synthetic methods
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 32, pp. 9333 - 9337
A highly efficient majority‐rules effect of poly(quinoxaline‐2,3‐diyl)s (PQXs) bearing 2‐butoxymethyl chiral side chains at the 6‐ and 7‐positions was... 
ligand design | asymmetric synthesis | helical structures | asymmetric amplification | polymer catalysts | MACROMOLECULAR STEREOCHEMISTRY | POLYMERS | POLYISOCYANATES | ENANTIOSELECTIVE SYNTHESIS | HOMOCHIRALITY | HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | ORIGINS | SERGEANTS | PALLADIUM CATALYST | LIGAND | Solvent effect | Copolymers | Asymmetry | Helical | Ligands | Bowing | Monomers | Bearing
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 38, pp. 13191 - 13193
The first invertive B-alkyl Suzuki−Miyaura coupling has been achieved. The coupling of enantioenriched α-(acylamino)benzylboronic esters with aryl bromides and... 
HALIDES | PALLADIUM | ACID | C-N | RETENTION | TRANSMETALATION | STEREOCHEMISTRY | ALKYLBORANES | ARYL | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2010, Volume 132, Issue 23, pp. 7899 - 7901
A polyquinoxaline-based helical polymer ligand bearing both helical-sense-determining chiral side chains and coordinating diarylphosphino side chains exhibits... 
SCREW-SENSE | POLYMERS |