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Nature Communications, ISSN 2041-1723, 07/2016, Volume 7, Issue 1, p. 12181
Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied, because the iron atom plays an important role in the industrial and... 
NITROGEN-FIXATION | SQUARE-PLANAR | N-2 | REDUCTION | MOLYBDENUM | (FEFEI)-FE-II | MULTIDISCIPLINARY SCIENCES | FE-N-2 COMPLEX | UNIQUE BEHAVIOR | MOLECULAR DINITROGEN | N BOND-CLEAVAGE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 46, pp. 14291 - 14295
The direct formation of ammonia from molecular dinitrogen under mild reaction conditions was achieved by using new cobalt dinitrogen complexes bearing an... 
ammonia | catalysis | dinitrogen | cobalt | pincer ligands | AMBIENT REACTION CONDITIONS | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | SINGLE MOLYBDENUM CENTER | PENDANT AMINES | ALKALI-METAL | REDUCTION | NITROGEN | BOND ORDER | N-2 ACTIVATION | UNIQUE BEHAVIOR | Ammonia | Catalysis | Surface active agents | Nitrogen | Cobalt
Journal Article
Nature Communications, ISSN 2041-1723, 04/2017, Volume 8, Issue 1, p. 14874
Intensive efforts for the transformation of dinitrogen using transition metal-dinitrogen complexes as catalysts under mild reaction conditions have been made.... 
SINGLE MOLYBDENUM CENTER | N-2 REDUCTION | AMBIENT REACTION CONDITIONS | FEMO-COFACTOR | DONOR PROPERTIES | C-ATOM | MULTIDISCIPLINARY SCIENCES | FE-N-2 COMPLEX | N-HETEROCYCLIC CARBENES | UNIQUE BEHAVIOR | MOLECULAR DINITROGEN
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 10/2017, Volume 90, Issue 10, pp. 1111 - 1118
We have now found that molybdenum–iodide complexes bearing a PNP-pincer ligand have a higher catalytic activity than the so far reported molybdenum–dinitrogen... 
N-2 REDUCTION | FUNCTIONALIZATION | TRANSFORMATION | BEARING PINCER LIGAND | MOLYBDENUM | CONVERSION | COMPLEXES BEARING | NITRIDE | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | AMMONIA FORMATION | Ammonia | Nitrogen compounds | Chemical bonds | Ligands | Cleavage | Catalytic activity | Catalysis | Coordination compounds | Nitrogen | Molybdenum | Bearing
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 29, pp. 9064 - 9068
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2014, Volume 53, Issue 43, pp. 11488 - 11492
The NN bond of molecular dinitrogen bridging two molybdenum atoms in the pentamethylcyclopentadienyl molybdenum complexes that bear ferrocenyldiphosphine as... 
iron | dinitrogen complexes | Haber–Bosch process | nitrogen fixation | molybdenum | Nitrogen fixation | Dinitrogen complexes | Iron | Haber-Bosch process | Molybdenum | ACTIVATION | PINCER LIGAND | HYDROGENATION | AMMONIA | CONVERSION | CHEMISTRY, MULTIDISCIPLINARY | CATALYTIC FORMATION | NITRIDO COMPLEXES | REDUCTION | INTERMEDIATE | Nitrogen | Hydrogen | Nitrides | Bridging | Neural networks | Cleavage | Formations | Bonding | Stimuli | Bearing
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2015, Volume 21, Issue 24, pp. 8905 - 8909
The first successful example of cobalt‐catalyzed reduction of N2 with Me3SiCl and Na as a reductant, under ambient reaction conditions, gives N(SiMe3)3, which... 
density functional calculations | cobalt | silylation | nitrogen fixation | reduction | Nitrogen fixation | Reduction | Density functional calculations | Cobalt | Silylation | ACTIVATION | PINCER LIGAND | AMMONIA | COMPLEXES | IRON | CHEMISTRY, MULTIDISCIPLINARY | SINGLE MOLYBDENUM CENTER | NITROGEN-FIXATION | N-2 | METAL | Pathways | Mathematical analysis | Ligands | Transformations | Catalytic activity | Proposals | Bearing
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 46, pp. 14180 - 14180
Cobalt complexes bearing an anionic PNP‐type pincer ligand are effective catalysts for the reduction of molecular dinitrogen into ammonia under mild reaction... 
ammonia | catalysis | dinitrogen | cobalt | pincer ligands
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 06/2019, Volume 14, Issue 12, pp. 2091 - 2096
Molybdenum–iodide complexes bearing a PCP[1] ligand have been found to work as excellent catalysts toward ammonia formation under ambient reaction conditions... 
pincer ligands | nitrogen fixation | halides | molybdenum | N-heterocyclic carbenes | CARBON | AMMONIA | FE-N-2 COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | N-2 | HYDRAZINE | REDUCTION | C-ATOM | DINITROGEN | NITROGEN | CHEMISTRY | Ammonia | Fixation | Nitrogen | Molybdenum
Journal Article
Dalton Transactions, ISSN 1477-9226, 01/2018, Volume 47, Issue 33, pp. 11322 - 11326
Dinitrogen-bridged dititanium and dizirconium complexes bearing anionic pyrrole-based PNP-type pincer ligands are prepared and characterized by X-ray analysis.... 
Ammonia | Hydrazines | Zirconium | Nitrogen compounds | Titanium | Ligands | Catalytic activity | Catalysis | X ray analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 27, pp. 9719 - 9731
A series of dinitrogen-bridged dimolybdenum–dinitrogen complexes bearing 4-substituted PNP-pincer ligands are synthesized by the reduction of the corresponding... 
SINGLE MOLYBDENUM CENTER | DENSITY | N-2 | SYNTHETIC NITROGEN-FIXATION | REDUCTION | C-ATOM | BOND FORMATION | IRON | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | Ammonia | Catalysis | Research | Chemical properties | Molybdenum compounds | Chemical synthesis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 17, pp. 5666 - 5669
Newly designed and prepared molybdenum–nitride complexes bearing a mer-tridentate triphosphine as a ligand have been found to work as the most effective... 
N-2 | ACTIVATION | MOLECULAR NITROGEN | CONVERSION | COORDINATED DINITROGEN | C-ATOM | MONO(DINITROGEN) COMPLEXES | TRIPOD LIGAND | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | PRODUCE AMMONIA | Ammonia | Oxidation-reduction reaction | Research | Chemical properties | Molybdenum compounds | Catalysts
Journal Article
ISSN 1359-7345, 12/2019, Volume 55, Issue 99, pp. 14886 - 14889
Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of... 
Journal Article
Nature, ISSN 0028-0836, 02/2018, Volume 554, Issue 7691, pp. 249 - 254
To facilitate clinical trials of disease-modifying therapies for Alzheimer's disease, which are expected to be most efficacious at the earliest and mildest... 
NATIONAL INSTITUTE | LIFE-STYLE AIBL | ANALYTICAL PLATFORMS | QUANTIFICATION | MULTIDISCIPLINARY SCIENCES | BLOOD-BASED BIOMARKERS | DIAGNOSTIC GUIDELINES | MILD COGNITIVE IMPAIRMENT | CEREBROSPINAL-FLUID | MASS-SPECTROMETRY | ASSOCIATION WORKGROUPS | Immunoprecipitation | Humans | Male | Positron-Emission Tomography | Amyloid beta-Peptides - blood | Case-Control Studies | Alzheimer Disease - diagnosis | Brain - metabolism | Mass Spectrometry | Amyloid beta-Peptides - metabolism | Amyloid beta-Protein Precursor - metabolism | Peptide Fragments - blood | Amyloid beta-Peptides - cerebrospinal fluid | Amyloid beta-Protein Precursor - blood | Female | Biomarkers - metabolism | Peptide Fragments - metabolism | Reproducibility of Results | Peptide Fragments - cerebrospinal fluid | Cognitive Dysfunction - metabolism | Japan | Cognitive Dysfunction - blood | Biomarkers - blood | Alzheimer Disease - cerebrospinal fluid | Cost-Benefit Analysis | Alzheimer Disease - metabolism | Aged | Biomarkers - cerebrospinal fluid | Australia | Alzheimer Disease - blood | Neuroimaging | Plasma | Brain | Peptides | Cognitive ability | Clinical trials | Cerebrospinal fluid | Blood | Aging | Alzheimer's disease | Medical research | Medical imaging | Neurodegenerative diseases | Positron emission | Mass spectroscopy | Amyloid precursor protein | Studies | Biomarkers | Ligands | Scientific imaging | Alzheimers disease | Mass spectrometry | Positron emission tomography | Dementia
Journal Article
Chemical Science, ISSN 2041-6520, 07/2015, Volume 6, Issue 7, pp. 3940 - 3951
A series of dinitrogen-bridged dimolybdenum-dinitrogen complexes bearing metallocene-substituted PNP-pincer ligands is synthesized by the reduction of the... 
REDUCTION | LIGANDS |