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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 10, pp. 2727 - 2729
A cyclometalated N‐heterocyclic carbene ligand in a half‐sandwich iron complex was found to couple with alkynes, leading to a unique type of ring opening of... 
sandwich complexes | iron | N‐heterocyclic carbene | bond cleavage | diimines | N-heterocyclic carbene
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2005, Volume 127, Issue 25, pp. 8950 - 8951
[NiFe] hydrogenase, the enzyme of which catalyzes the reversible oxidation of molecular hydrogen to protons and electrons, contains a unique heterodinuclear... 
Hydrogenase - chemical synthesis | Models, Chemical | Nickel - chemistry | Organometallic Compounds - chemical synthesis | Iron - chemistry | Molecular Conformation | Models, Molecular | Crystallography, X-Ray | Organometallic Compounds - chemistry | Hydrogenase - chemistry | Binding Sites
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2008, Volume 130, Issue 35, pp. 11610 - 11611
Facile H2 heterolysis was found to be mediated by coordinatively unsaturated Cp*Ir and Cp*Rh thiolate complexes. The reaction of iridium complex is reversible,... 
Hydrogenase - metabolism | Deuterium - chemistry | Sulfhydryl Compounds - chemistry | Hydrogenase - chemistry | Binding Sites | Hydrogen - chemistry | Iridium - chemistry | Hydrogen - metabolism | Rhodium - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 36, pp. 11594 - 11597
Journal Article
Pure and Applied Chemistry, ISSN 0033-4545, 01/2015, Volume 87, Issue 1, pp. 1 - 2
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2008, Volume 130, Issue 50, pp. 17174 - 17186
Half-sandwich iron complexes of N-heterocyclic carbenes, Cp*Fe(LR)Cl (2a; LMes = 1,3-dimesityl-imidazol-2-ylidene, 2b; LiPr =... 
ORGANOBORON COMPOUNDS | MECHANISTIC ASPECTS | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | MOLECULAR-STRUCTURE | CATALYZED REACTIONS | METAL BORYL COMPLEXES | X-RAY CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE COMPLEXES | STRUCTURAL CHARACTERIZATION
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 08/2013, Volume 2013, Issue 22‐23, pp. 3966 - 3971
A half‐sandwich, coordinatively unsaturated N‐heterocyclic carbene complex of iron with a metallacycle was found to cleave the Si–H bonds of hydrosilanes to... 
Iron | Hydrosilanes | Hydrogen | Carbenes | Sandwiches | Pyridine | Crystallography
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 07/2013, Volume 639, Issue 8‐9, pp. 1340 - 1349
The nitrogenase metallo‐clusters, namely P‐cluster and FeMo‐cofactor, have been attracting considerable interests because they are indispensable for biological... 
Iron | FeMo‐cofactor | Sulfur | Nitrogenase | P‐cluster | FeMo-cofactor | P-cluster | FE-ONLY NITROGENASE | MOFE-PROTEIN | STRUCTURAL-CHARACTERIZATION | P-N CLUSTER | RHODOBACTER-CAPSULATUS | CHEMISTRY, INORGANIC & NUCLEAR | H BOND ACTIVATION | IRON-MOLYBDENUM COFACTOR | ALTERNATIVE NITROGENASE | AZOTOBACTER-VINELANDII | DOUBLE-CUBANE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2013, Volume 135, Issue 30, pp. 10978 - 10981
The B–H bond of typical boranes is heterolytically split by the polar Ru–S bond of a tethered ruthenium(II) thiolate complex, affording a ruthenium(II) hydride... 
ARENE BORYLATION | LEWIS-ACID | ANILINES | COMPLEXES | BORINIUM | REACTIVITY | CHEMISTRY | RUTHENIUM | CHEMISTRY, MULTIDISCIPLINARY | BASE | CATIONS | Measurement | Thermal properties | Usage | Ruthenium | Analysis | Chemical properties | Activation energy | Hydrogen bonding | Mass spectrometry
Journal Article
Zeitschrift fur anorganische und allgemeine Chemie, ISSN 0044-2313, 07/2013, Volume 639, Issue 8-9, p. 1340
The nitrogenase metallo-clusters, namely P-cluster and FeMo-cofactor, have been attracting considerable interests because they are indispensable for biological... 
Sulfur compounds | Enzymes | Heterocyclic compounds | Analysis | Ferroalloys
Journal Article
Nature Chemistry, ISSN 1755-4330, 05/2018, Volume 10, Issue 5, pp. 568 - 572
The M-cluster is the [(homocitrate) MoFe7S9C] active site of nitrogenase that is derived from an 8Fe core assembled via coupling and rearrangement of two... 
ACTIVATION | PROTEIN | CARBON | DITHIONITE | FEMO-COFACTOR | ACTIVE-SITES | BIOSYNTHESIS | RESOLUTION | DECOMPOSITION | IRON | CHEMISTRY, MULTIDISCIPLINARY | Sulfite | Iron sulfides | Nitrogenase | Methionine | Clusters | Insertion | Functional analysis | Sulfur
Journal Article
Chemistry International -- Newsmagazine for IUPAC, ISSN 0193-6484, 01/2013, Volume 35, Issue 1, pp. 2 - 3
Journal Article
Angewandte Chemie, ISSN 1433-7851, 03/2014, Volume 53, Issue 10, p. 2727
  A cyclometalated N-heterocyclic carbene ligand in a half-sandwich iron complex was found to couple with alkynes, leading to a unique type of ring opening of... 
Ligands
Journal Article
Angewandte Chemie (International Edition), ISSN 1433-7851, 03/2014, Volume 53, Issue 10, pp. 2727 - 2729
A cyclometalated N-heterocyclic carbene ligand in a half-sandwich iron complex was found to couple with alkynes, leading to a unique type of ring opening of... 
Imidazole | Ligands | Joining | Formations | Iron | Carbenes | Ring opening | Alkynes
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 05/2012, Volume 51, Issue 9, pp. 5173 - 5187
Journal Article