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chemistry, multidisciplinary (12) 12
catalysis (11) 11
photoredox catalysis (7) 7
alkenes (6) 6
carboxylic-acids (5) 5
complexes (5) 5
organic-synthesis (5) 5
oxidative addition (5) 5
reactivity (5) 5
chemistry, inorganic & nuclear (4) 4
decarboxylation (4) 4
hydrogen (4) 4
radicals (4) 4
visible-light photoredox (4) 4
alcohols (3) 3
alkyl-halides (3) 3
alkynes (3) 3
chemistry (3) 3
diazo compounds (3) 3
diazonium salts (3) 3
efficient synthesis (3) 3
gold (3) 3
homogeneous gold catalysis (3) 3
hydrogen-atom transfer (3) 3
oxidation (3) 3
styrene (3) 3
styrol (3) 3
supramolecular chemistry (3) 3
alkohole (2) 2
alkylation (2) 2
alpha-amino-acids (2) 2
analysis (2) 2
anion binding (2) 2
aromatic compounds (2) 2
arylation (2) 2
bond activation (2) 2
bonding (2) 2
c-h (2) 2
c-h functionalization (2) 2
carbon-tetrachloride (2) 2
carbonyl radicals (2) 2
catalyzed multicomponent synthesis (2) 2
chemical reactions (2) 2
chemistry, organic (2) 2
chemistry, physical (2) 2
chlorides (2) 2
combining photoredox (2) 2
coupling (2) 2
cross-coupling reactions (2) 2
c‐c bond formation (2) 2
decarboxylative alkynylation (2) 2
decarboxylierung (2) 2
dimethyl-sulfoxide (2) 2
dithiocarbamate (2) 2
electron-transfer mechanism (2) 2
electrons (2) 2
elektron (2) 2
functionalisation (2) 2
funktionalisierung (2) 2
h bond activation (2) 2
heterocyclic carbenes (2) 2
hydrogen bonds (2) 2
hydrogen ion concentration (2) 2
hypervalent compounds (2) 2
ligand-exchange (2) 2
light effects (2) 2
light photoredox catalysis (2) 2
light-radiation (2) 2
mechanism (2) 2
molecular-structure (2) 2
one-pot synthesis (2) 2
organotin complexes (2) 2
photocatalysis (2) 2
photocatalytic reactions (2) 2
photochemistry, radiation chemistry, chemoluminescence (2) 2
photokatalyse (2) 2
protein-kinase (2) 2
receptor antagonists (2) 2
sichtbares licht (2) 2
sonogashira reactions (2) 2
substrates (2) 2
temperature ionic liquids (2) 2
tin compounds (2) 2
tolerances (2) 2
transformations (2) 2
1,2-amino alcohols (1) 1
1,4-dicarbonyl compounds (1) 1
activation (1) 1
acyl radicals (1) 1
aerobic conditions (1) 1
aldehyd (1) 1
aldehydes (1) 1
aliphatic compounds (1) 1
alkadienes - chemistry (1) 1
alkine (1) 1
alkyl radicals (1) 1
alkylradikale (1) 1
alkynylation (1) 1
allylation (1) 1
allylierung (1) 1
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1. Full Text Multicomponent Oxyalkylation of Styrenes Enabled by Hydrogen‐Bond‐Assisted Photoinduced Electron Transfer
by Tlahuext‐Aca, Adrian and Garza‐Sanchez, R. Aleyda and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 13, pp. 3708 - 3711
Herein, we disclose a strategy for the activation of N‐(acyloxy)phthalimides towards photoinduced electron transfer through hydrogen bonding. This activation... 
hydrogen bonding | alkyl radicals | oxyalkylation | photoredox catalysis | decarboxylation | ALPHA-AMINO-ACIDS | QUATERNARY CARBONS | CHEMISTRY, MULTIDISCIPLINARY | DECARBOXYLATIVE ALKYNYLATION | TRANSFER MECHANISM | ALKENES | ARYL DIAZONIUM SALTS | LIGHT PHOTOREDOX CATALYSIS | RADICALS | METAL-FREE | CARBOXYLIC-ACIDS | Electron transport | Hydrogen | Hydrogen bonding | Hydrogen bonds | Decarboxylation | Styrene | Electron transfer | Bonding | Hydrogen ion concentration | Substrates | Radicals | Alcohols
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2. Full Text Alkyne Difunctionalization by Dual Gold/Photoredox Catalysis
by Tlahuext‐Aca, Adrian and Hopkinson, Matthew N and Garza‐Sanchez, R. Aleyda and Glorius, Frank
Chemistry – A European Journal, ISSN 0947-6539, 04/2016, Volume 22, Issue 17, pp. 5909 - 5913
Highly selective tandem nucleophilic addition/cross‐coupling reactions of alkynes have been developed using visible‐light‐promoted dual gold/photoredox... 
gold | diazonium salts | synthetic methods | alkynes | arylation | ORGANIC-SYNTHESIS | MECHANISM | VISIBLE-LIGHT PHOTOREDOX | N-HALOSUCCINIMIDES | COMPLEXES | HOMOGENEOUS GOLD CATALYSIS | EFFICIENT SYNTHESIS | FUNCTIONALIZED HYDRATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | Diazo compounds | Catalysis | Gold | Cross coupling | Catalysts | Hydration | Chemical reactions | Activation | Selectivity | Light effects | Substrates | Radicals | Aromatic compounds | Oxidation | Coupling | Cascade chemical reactions | Alkynes | Level (quantity)
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3. Full Text Oxidative Addition to Gold(I) by Photoredox Catalysis: Straightforward Access to Diverse (C,N)‐Cyclometalated Gold(III) Complexes
by Tlahuext‐Aca, Adrian and Hopkinson, Matthew N and Daniliuc, Constantin G and Glorius, Frank
Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 33, pp. 11587 - 11592
Herein, we report the oxidative addition of aryldiazonium salts to ligand‐supported gold(I) complexes under visible light photoredox conditions. This method... 
gold(III) complexes | diazonium salts | photoredox catalysis | oxidative addition | MECHANISM | VISIBLE-LIGHT PHOTOREDOX | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | COUPLING REACTIVITY | ALKYL-HALIDES | ALKENES | LIGANDS | ORGANOMETALLIC CHEMISTRY | BOND | Ligands | Gold | Salts | Chlorides | Chemical reactions | Catalysis | Coordination compounds | Light effects | Metalorganic compounds
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4. Full Text Palladium‐Catalyzed Decarboxylative Heck‐Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light
by Koy, Maximilian and Sandfort, Frederik and Tlahuext‐Aca, Adrian and Quach, Linda and Daniliuc, Constantin G and Glorius, Frank
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 18, pp. 4552 - 4555
The palladium‐catalyzed coupling reaction of N‐hydroxyphthalimide esters and styrenes to deliver exclusively (E)‐substituted olefins under irradiation with... 
palladium | decarboxylation | redox-active esters | Heck-type coupling | carboxylic acids | PALLADATION | ROOM-TEMPERATURE | N-HYDROXYPHTHALIMIDE ESTERS | BOND FORMATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | IODIDES | OLEFINATION | AMINES | ROBUSTNESS SCREEN | Palladium | Organic compounds | Alkenes | Styrenes | Decarboxylation | Radiation | Irradiation | Esters | Carboxylic acids | Coupling | Aliphatic compounds
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5. Full Text Merging Visible Light Photoredox and Gold Catalysis
by Hopkinson, Matthew N and Tlahuext-Aca, Adrian and Glorius, Frank
Accounts of Chemical Research, ISSN 0001-4842, 10/2016, Volume 49, Issue 10, pp. 2261 - 2272
Since the beginning of this century, π-Lewis acidic gold complexes have become the catalysts of choice for a wide range of organic reactions, especially those... 
TRANSITION-METAL CATALYSIS | ALKENES | ARYLDIAZONIUM SALTS | C-H ARYLATION | DIAZONIUM SALTS | COUPLING REACTIONS | COMPLEXES | CHEMISTRY | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | OXYARYLATION
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6. Full Text DMSO as a Switchable Alkylating Agent in Heteroarene C−H Functionalization
by Garza‐Sanchez, R. Aleyda and Patra, Tuhin and Tlahuext‐Aca, Adrian and Strieth‐Kalthoff, Felix and Glorius, Frank
Chemistry – A European Journal, ISSN 0947-6539, 07/2018, Volume 24, Issue 40, pp. 10064 - 10068
Herein, we report a novel strategy for the activation of DMSO to act as a versatile alkylating agent in heteroarene C−H functionalization. This direct, simple,... 
C−H functionalization | heteroarenes | photoredox catalysis | methylthiomethylation | methylation | OXIDATION | C-H functionalization | COMBINING PHOTOREDOX | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | NUCLEOPHILIC CHARACTER | LIGHT PHOTOREDOX CATALYSIS | CHEMISTRY | RADICALS | DIMETHYL-SULFOXIDE | HETEROAROMATIC BASES | Methylation | Catalysis | Alkylation | Reagents | Computer applications
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7. Full Text Visible-Light-Promoted Activation of Unactivated C(sp3)–H Bonds and Their Selective Trifluoromethylthiolation
by Mukherjee, Satobhisha and Maji, Biplab and Tlahuext-Aca, Adrian and Glorius, Frank
Journal of the American Chemical Society, ISSN 0002-7863, 12/2016, Volume 138, Issue 50, pp. 16200 - 16203
Selective functionalization of ubiquitous C­(sp3)–H bonds using visible light is a highly challenging yet desirable goal in organic synthesis. The development... 
OXIDATION | AMINATION | ETHERS | DIRECT ARYLATION | AMINO-ACIDS | COMPLEXES | RADICALS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | LATE-STAGE FUNCTIONALIZATION | PHOTOREDOX CATALYSIS
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8. Full Text Alkynylation of Csp2 (O)–H Bonds Enabled by Photoredox‐Mediated Hydrogen‐Atom Transfer
by Mukherjee, Satobhisha and Garza‐Sanchez, R. Aleyda and Tlahuext‐Aca, Adrian and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 46, pp. 14723 - 14726
The development of new hydrogen‐atom transfer (HAT) strategies within the framework of photoredox catalysis is highly appealing for its power to activate a... 
C−H activation | photocatalysis | hypervalent compounds | hydrogen-atom transfer | carbonyl radicals | Hydrogen | Bonds | Catalysis
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9. Full Text Visible Light-Mediated Direct Decarboxylative C–H Functionalization of Heteroarenes
by Garza-Sanchez, R. Aleyda and Tlahuext-Aca, Adrian and Tavakoli, Ghazal and Glorius, Frank
ACS Catalysis, ISSN 2155-5435, 06/2017, Volume 7, Issue 6, pp. 4057 - 4061
The direct visible light-mediated C–H alkylation of heteroarenes using aliphatic carboxylic acids is reported. This mild method proceeds at low catalyst... 
Minisci reaction | alkylation | photoredox catalysis | decarboxylation | C-H functionalization | heterocycles | MERGING PHOTOREDOX | CONVERSION | ARYLATION | CHEMISTRY, PHYSICAL | ALPHA-AMINO-ACIDS | ALKYNYLATION | N-HETEROARENES | SO4 | CARBOXYLIC-ACIDS
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10. Full Text Dual gold/photoredox-catalyzed C(sp)-H arylation of terminal alkynes with diazonium salts
by Tlahuext-Aca, Adrian and Hopkinson, Matthew N and Sahoo, Basudev and Glorius, Frank
Chemical science, ISSN 2041-6520, 01/2016, Volume 7, Issue 1, pp. 89 - 93
The arylation of alkyl and aromatic terminal alkynes by a dual gold/photoredox catalytic system is described. Using aryldiazonium salts as readily available... 
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11. Full Text Dual gold/photoredox-catalyzed C(sp)-H arylation of terminal alkynes with diazonium salts
by Tlahuext-Aca, Adrian and Hopkinson, Matthew N and Sahoo, Basudev and Glorius, Frank
Chemical Science, ISSN 2041-6520, 2016, Volume 7, Issue 1, pp. 89 - 93
The arylation of alkyl and aromatic terminal alkynes by a dual gold/photoredox catalytic system is described. Using aryldiazonium salts as readily available... 
ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | VISIBLE-LIGHT PHOTOREDOX | COMPLEXES | HOMOGENEOUS GOLD CATALYSIS | REACTIVITY | PHOTOCATALYTIC REACTIONS | BOND ACTIVATION | SONOGASHIRA REACTIONS | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | Gold | Aromatic compounds | Households | Transformations | Tolerances | Terminals | Catalysis | Alkynes
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12. Full Text Decarboxylative Olefination of Activated Aliphatic Acids Enabled by Dual Organophotoredox/Copper Catalysis
by Tlahuext-Aca, Adrian and Candish, Lisa and Garza-Sanchez, R. Aleyda and Glorius, Frank
ACS Catalysis, ISSN 2155-5435, 03/2018, Volume 8, Issue 3, pp. 1715 - 1719
Herein, we demonstrate a dual organophotoredox/copper catalytic strategy toward challenging decarboxylative olefination processes proceeding in high yields and... 
copper catalysis | photoredox catalysis | decarboxylation | dual catalysis | olefin synthesis | VISIBLE-LIGHT PHOTOCATALYSIS | CHEMISTRY, PHYSICAL | FATTY-ACIDS | TRANSFER RADICAL POLYMERIZATION | LINEAR ALPHA-OLEFINS | DECARBONYLATIVE DEHYDRATION | COOPERATIVE PHOTOREDOX | ELECTRON-TRANSFER MECHANISM | METAL-COMPLEXES | CARBOXYLIC-ACIDS
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13. Full Text Diastereoselective Allylation of Aldehydes by Dual Photoredox and Chromium Catalysis
by Schwarz, J. Luca and Schäfers, Felix and Tlahuext-Aca, Adrian and Lückemeier, Lukas and Glorius, Frank
Journal of the American Chemical Society, ISSN 0002-7863, 10/2018, Volume 140, Issue 40, pp. 12705 - 12709
Herein, we report the redox-neutral allylation of aldehydes with readily available electron-rich allyl (hetero-) arenes, β-alkyl styrenes and... 
ANTI-AMINOALLYLATION | ORGANIC-SYNTHESIS | HYDROGEN-ATOM TRANSFER | HOMOALLYL ALCOHOLS | 1,2-AMINO ALCOHOLS | TITANIUM TRICHLORIDE | CARBONYL-COMPOUNDS | RADICAL-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | ASYMMETRIC ALLYLATION
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14. Full Text Visible-Light-Mediated Synthesis of Ketones by the Oxidative Alkylation of Styrenes
by Tlahuext-Aca, Adrian and Garza-Sanchez, R. Aleyda and Schäfer, Michael and Glorius, Frank
Organic Letters, ISSN 1523-7060, 03/2018, Volume 20, Issue 6, pp. 1546 - 1549
The oxidative coupling of photogenerated alkyl radicals with readily available styrenes is disclosed. This visible-light-mediated method allows rapid access to... 
ORGANIC-SYNTHESIS | AEROBIC CONDITIONS | DIRECT OXYSULFONYLATION | BETA-KETOSULFONES | 1,4-DICARBONYL COMPOUNDS | CHEMISTRY, ORGANIC | DIMETHYL-SULFOXIDE | ELECTRON-TRANSFER MECHANISM | DECARBOXYLATIVE ALKYLATION | COMBINING PHOTOREDOX | PHOTOREDOX CATALYSIS
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15. Full Text On the Catalytic Hydrodefluorination of Fluoroaromatics Using Nickel Complexes: The True Role of the Phosphine
by Arévalo, Alma and Tlahuext-Aca, Adrian and Flores-Alamo, Marcos and García, Juventino J
Journal of the American Chemical Society, ISSN 0002-7863, 03/2014, Volume 136, Issue 12, pp. 4634 - 4639
Homogeneous catalytic hydrodefluorination (HDF) of fluoroaromatics under thermal conditions was achieved using nickel(0) compounds of the type... 
TRIFLUOROTOLUENES | MOLECULAR-STRUCTURE | P-C | REACTIVITY | CARBON-CARBON BONDS | FLUOROPYRIDINES | OXIDATIVE ADDITION | CLEAVAGE | C-F | CHEMISTRY, MULTIDISCIPLINARY | F BOND ACTIVATION | Nickel compounds | Fluorocarbons | Research | Analysis
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16. Full Text Mehrkomponenten‐Oxyalkylierung von Styrolen durch Wasserstoffbrücken‐unterstützten photoinduzierten Elektronentransfer
by Tlahuext‐Aca, Adrian and Garza‐Sanchez, R. Aleyda and Glorius, Frank
Angewandte Chemie, ISSN 0044-8249, 03/2017, Volume 129, Issue 13, pp. 3762 - 3765
Eine Strategie zur Aktivierung von N‐(Acyloxy)phthalimiden für den photoinduzierten Elektronentransfer durch die Bildung von Wasserstoffbrücken wird... 
Wasserstoffbrücken | Alkylradikale | Decarboxylierungen | Oxyalkylierungen | Photoredoxkatalyse
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17. Full Text Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines
by Tlahuext-Aca, Adrian and Hernández-Fajardo, Oscar and Arévalo, Alma and García, Juventino J
Dalton Transactions, ISSN 1477-9226, 11/2014, Volume 43, Issue 42, pp. 15997 - 16005
Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved... 
H BOND ACTIVATION | TEMPERATURE IONIC LIQUIDS | RECEPTOR ANTAGONISTS | ONE-POT SYNTHESIS | PROTEIN-KINASE | EFFICIENT SYNTHESIS | CATALYZED MULTICOMPONENT SYNTHESIS | HETEROCYCLIC CARBENES | CARBON-TETRACHLORIDE | C-H | CHEMISTRY, INORGANIC & NUCLEAR | Organophosphorus Compounds - chemistry | Catalysis | Nickel - chemistry | Alkadienes - chemistry | Imidazoles - chemistry | Imines - chemistry
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