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Chemical & Pharmaceutical Bulletin, ISSN 0009-2363, 05/2017, Volume 65, Issue 5, p. 409
C-H functionalization reactions involve the activation of otherwise unreactive C-H bonds, and represent atom economical methods for the direct transformation... 
Alkaloids | Fluorene | Construction | Transformation | Natural products | Protecting groups | Selectivity | Palladium | Substrates
Journal Article
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, ISSN 0037-9980, 2018, Volume 76, Issue 5, pp. 486 - 489
Journal Article
Nature Communications, ISSN 2041-1723, 12/2017, Volume 8, Issue 1, pp. 674 - 9
Avenaol, isolated from the allelopathic plant black oat, was the first C-20 germination stimulant related to strigolactones. Structurally, it consisted of a... 
OXIDATION | STEREOISOMERS | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | ALKYLIDENECYCLOPROPANES | MULTIDISCIPLINARY SCIENCES | ISOMERIZATION | CYCLOPROPANATION | TRICYCLIC SESQUITERPENES | GERMINATION STIMULANT | STRIGOLACTONE | Cyclopropane | Allene | Germination | Isomerization | Strategy | Oxidation | Chemical synthesis | Ring opening | Organic compounds
Journal Article
Organic Letters, ISSN 1523-7060, 08/2012, Volume 14, Issue 16, pp. 4270 - 4273
Synthesis of the indole skeleton was achieved using a Pd-catalyzed cascade process consisting of isocyanide insertion and benzylic C(sp3)–H activation. It was... 
FUNCTIONALIZATION | ROUTE | MECHANISM | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | INTRAMOLECULAR ALKANE ARYLATION | 2,3-DISUBSTITUTED INDOLES | C-H BONDS | ARYL CHLORIDES | CARBOXYLIC-ACIDS | Nitriles - chemistry | Indoles - chemical synthesis | Alkynes - chemistry | Molecular Structure | Catalysis | Indoles - chemistry | Palladium - chemistry
Journal Article
Journal of Antibiotics, ISSN 0021-8820, 2019, Volume 72, Issue 6, pp. 407 - 419
Communesins, isolated from the mycelium of a strain of Penicillium sp., are cytotoxic heptacyclic indole alkaloids bearing a bis-aminal structure and two... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2019, Volume 25, Issue 37, pp. 8701 - 8704
A concise route for construction of the ACDE ring skeleton in calyciphylline A type alkaloids was developed using an intramolecular [5+2] cycloaddition... 
[5+2] cycloaddition | daphniphyllum alkaloids | synthetic strategy | daphniyunnine | calyciphylline A | ALCOHOLS | TRICYCLIC CORE | DAPHNIPHYLLUM | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | calyciphylline A | CYCLIZATION | Alkaloids | Analysis | Construction | Cycloaddition | Oxidation | Quaternary | Cyclic compounds
Journal Article
Chemical and Pharmaceutical Bulletin, ISSN 0009-2363, 2017, Volume 65, Issue 12, pp. 1167 - 1174
Journal Article
Scientific Reports, ISSN 2045-2322, 12/2019, Volume 9, Issue 1, pp. 4538 - 10
Fluctuations in food availability and shifts in temperature are typical environmental changes experienced by animals. These environmental shifts sometimes... 
Biodegradation | Ubiquitin | Starvation | Cell survival | Cold | Dietary supplements | Environmental changes | Desaturase | Arachidonic acid | Linoleic acid | Food availability | Feedback | Oxidation | Supplementation | Adaptation
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2016, Volume 2016, Issue 1, pp. 108 - 115
Communesins are a class of heptacyclic indole alkaloids that contain two aminal moieties and two contiguous quaternary carbon centers. We have investigated the... 
Alkaloids | Heterocycles | Cyclization | Diastereoselectivity | Rearrangement | ASYMMETRIC-SYNTHESIS | OXINDOLES | CHEMISTRY, ORGANIC | CATALYZED ALPHA-ARYLATION | BIOMIMETIC APPROACH | PEROPHORAMIDINE | EVOLUTION | BIOSYNTHESIS | ENANTIOSELECTIVE TOTAL SYNTHESES | INDOLE ALKALOIDS | TRANSFORMATIONS
Journal Article
Chemistry Letters, ISSN 0366-7022, 7/2013, Volume 42, Issue 7, pp. 753 - 755
The synthesis of spirooxindoles fused with cyclopropanes from carbamoyl chlorides, via methine C(sp3)–H activation, is reported. The regioselectivity of C–H... 
Catalytic C-H Activation | HETEROCYCLIC SCAFFOLDS | ROUTE | ALKYLATION | CONSTRUCTION | AMIDATION | OXINDOLES | INTRAMOLECULAR ALKANE ARYLATION | BOND | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | ACCESS
Journal Article
ISSN 1477-0520, 2/2019, Volume 17, Issue 7, pp. 1731 - 1735
A palladium-catalyzed intramolecular carboborylation of 1,3-diene has been developed for the synthesis of iminoindolines with a quaternary carbon centre. This... 
Journal Article
Chemical and Pharmaceutical Bulletin, ISSN 0009-2363, 2016, Volume 64, Issue 9, pp. 1384 - 1392
The synthesis of benzocyclobutenes from simple arenes bearing a directing group was investigated via the palladium-catalyzed cyclization of norbornene... 
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2019, Volume 17, Issue 7, pp. 1731 - 1735
A palladium-catalyzed intramolecular carboborylation of 1,3-diene has been developed for the synthesis of iminoindolines with a quaternary carbon centre. This... 
Nuclear magnetic resonance--NMR | Quaternary | Palladium | Chemical synthesis | Functional groups | Substrates
Journal Article
Genes to Cells, ISSN 1356-9597, 11/2019, Volume 24, Issue 11, pp. 688 - 704
In Chinese medicine, herbal medicine is commonly used to treat individuals suffering from many types of diseases. We thus expected that some herbal medicines... 
PTEN | melanoma | ellagic acid | cisplatin | G1 arrest | Phosphorylation | Phosphatidylinositol 3,4,5-triphosphate | p53 Protein | Melanoma | AKT protein | Phosphatase | Kinases | Cisplatin | Herbal medicine | Proteins | Chemotherapy | Allosteric properties | Cell death | Ellagic acid | Protein phosphatase | Focal adhesion kinase | PTEN protein
Journal Article