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Nature Chemistry, ISSN 1755-4330, 08/2013, Volume 5, Issue 8, pp. 673 - 678
Single-molecule magnets are compounds that exhibit magnetic bistability caused by an energy barrier for the reversal of magnetization (relaxation). Lanthanide... 
SPIN-LATTICE RELAXATION | SYMMETRY | BEHAVIOR | HYSTERESIS | COMPLEXES | ION MAGNETS | EXCHANGE | BLOCKING | DYSPROSIUM TRIANGLES | ANISOTROPY | CHEMISTRY, MULTIDISCIPLINARY | Magnetics | Molecular Structure | Lanthanoid Series Elements - chemistry
Journal Article
Nature Chemistry, ISSN 1755-4330, 06/2013, Volume 5, Issue 6, pp. 482 - 488
The nature and extent of covalency in uranium bonding is still unclear compared with that of transition metals, and there is great interest in studying... 
INFRARED-SPECTRA | ACTIVATION | COMPLEXES | DINITROGEN CLEAVAGE | CHEMISTRY | NITROGEN | URANYL-ION | AZIDE | TERMINAL URANIUM NITRIDE | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE
Journal Article
Nature Communications, ISSN 2041-1723, 07/2015, Volume 6, Issue 1, p. 7492
Single-molecule magnets are a type of coordination compound that can retain magnetic information at low temperatures. Single-molecule magnets based on... 
SYMMETRY | CLUSTERS | PHOSPHINIDENE COMPLEX | MULTIDISCIPLINARY SCIENCES | REACTIVITY | ION MAGNETS | RELAXATION | ASTERISK | BLOCKING | ANISOTROPY | SALTS
Journal Article
Science, ISSN 0036-8075, 8/2012, Volume 337, Issue 6095, pp. 717 - 720
The terminal uranium nitride linkage is a fundamental target in the study of f-orbital participation in metal-ligand multiple bonding but has previously eluded... 
Nitrides | Azides | Uranium | Sodium | REPORTS | Crystals | Atoms | Ligands | Magnetic dipole moment | Chemical bonding | Nitrogen | INFRARED-SPECTRA | ACTIVATION | ANALOGS | MULTIDISCIPLINARY SCIENCES | NUO | AZIDE | MOLECULES | Composition | Chemical properties | Chemical synthesis | Production processes | Methods | Chemical bonds | Molecular structure | Binding | Orbitals | Mathematical analysis | Terminals | Bonding
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2012, Volume 51, Issue 28, pp. 6976 - 6980
The sulfur‐bridged dimers [{Cp′2Ln(μ‐SSiPh3)}2] (Ln=Gd (1), Dy (2); Cp′=η5‐C5H4Me) were synthesized by the transmetalation reactions between [Cp′3Ln] and... 
dysprosium | sulfur | ab initio calculations | single‐molecule magnets | organometallics | single-molecule magnets | COMPLEX | BEHAVIOR | MAGNETIZATION | RELAXATION | AXIALITY | CHEMISTRY, MULTIDISCIPLINARY | ION MAGNET | BISTABILITY | SURFACE | EXCHANGE | DYSPROSIUM TRIANGLES | Dimers | Dysprosium | Magnetization | Anisotropy | Mathematical analysis | Barriers
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 33, pp. 11554 - 11558
We report uranium(IV)‐carbene‐imido‐amide metalla‐allene complexes [U(BIPMTMS)(NCPh3)(NHCPh3)(M)] (BIPMTMS=C(PPh2NSiMe3)2; M=Li or K) that can be described as... 
push–pull effect | amido | imido | metalla-allene | uranium | carbene | Reproduction | Uranium | Allene | Alkali metals | Computer applications | Lithium | Attenuation | Cations | Potassium | Heavy metals
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 12/2015, Volume 21, Issue 50, p. 18038
Uranium-based compounds have been put forward as ideal candidates for the design of single-molecule magnets (SMMs) with improved properties, but to date, only... 
Uranium | Transition metal compounds | Anisotropy | Magnetic properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2011, Volume 50, Issue 29, pp. 6530 - 6533
Single‐molecule magnets: A square‐pyramidal pentametallic dysprosium cluster (see picture) was synthesized and showed slow magnetic relaxation at temperatures... 
dysprosium | cluster compounds | magnetic properties | single‐molecule magnets | lanthanides | single-molecule magnets
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2016, Volume 138, Issue 18, pp. 5801 - 5804
Quantum coherence is detected in the 4f single-ion magnet (SIM) Yb­(trensal), by isotope selective pulsed EPR spectroscopy on an oriented single crystal. At... 
Usage | Spin coupling | Research | Quantum chemistry | Electron paramagnetic resonance spectroscopy | Analysis | Material chemistry | Chemical Sciences
Journal Article
Nature Chemical Biology, ISSN 1552-4450, 04/2016, Volume 12, Issue 4, pp. 298 - 303
Journal Article
Nature Communications, ISSN 2041-1723, 04/2016, Volume 7, Issue 1, p. 11377
The physical implementation of quantum information processing relies on individual modules-qubits-and operations that modify such modules either individually... 
DECOHERENCE | COMPUTERS | RINGS | MULTIDISCIPLINARY SCIENCES | COMPLEXES | TIME | PHYSICS | SIMULATION | ROTAXANES | SPIN QUBITS | COHERENCE
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 33, pp. 11559 - 11563
Uranium(IV)–carbene–imido complexes [U(BIPMTMS)(NCPh3)(κ2‐N,N′‐BIPY)] (2; BIPMTMS=C(PPh2NSiMe3)2; BIPY=2,2‐bipyridine) and [U(BIPMTMS)(NCPh3)(DMAP)2] (3;... 
carbenes | density functional calculations | imido compounds | metalla-allenes | uranium | Ligands | Uranium | Pyridines | Chemistry | Stability | Isomerization | Feasibility | Clear cutting
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 21, pp. 6314 - 6318
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 12/2018, Volume 2018, Issue 48, pp. 5191 - 5202
This investigation reports the syntheses, crystal structures, and magnetic properties of a series of isomorphous hexanuclear MnIII2LnIII4 compounds of... 
Single molecule magnets | Hexanuclear complexes | Lanthanides | Magnetic properties | Manganese | Magnetization | Imines | Anisotropy | Magnetic permeability | Analogue | Chelation | Ligands | Terbium | Magnetism | Crystal structure
Journal Article
Nature Chemistry, ISSN 1755-4330, 06/2017, Volume 9, Issue 6, pp. 578 - 583
Our knowledge of actinide chemical bonds lags far behind our understanding of the bonding regimes of any other series of elements. This is a major issue given... 
RAY-ABSORPTION SPECTROSCOPY | ELEMENT | SERIES | GROUND-STATE | ANALOG | COMPLEXES | CHEMISTRY | LANTHANIDE | LIGAND | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, MULTIDISCIPLINARY | Spectroscopy | Spectroscopic analysis | Nuclei (nuclear physics) | Nuclei | Electron spin | Covalence | Uranium | Actinides | Lanthanides | Spectrum analysis | Chemical bonds | Electron paramagnetic resonance | Thorium
Journal Article