Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 11/2014, Volume 52, Issue 22, pp. 3147 - 3165
ABSTRACT This review highlights the concept of multiple click reaction strategy which is utilized for design and synthesis of well‐defined complex...
post‐functionalization of polymer | copper catalyzed azide‐alkyne cycloaddition (CuAAC) | nitroxide radical coupling (NRC) | Michael thiol‐ene | nucleophilic substitution | thiol‐ene | living polymerization | polymer‐polymer conjugation | thiol‐yne | strain promoted azide‐alkyne cycloaddition (SPAAC) | Diels‐Alder | orthogonal multifunctionalization | Copper Catalyzed azide-alkyne cycloaddition (CuAAC) | Living polymerization | Orthogonal multifunctionalization | Strain promoted azide-alkyne cycloaddition (SPAAC) | Post-functionalization of polymer | Michael thiol-ene | Nitroxide Radical Coupling (NRC) | Diels-Alder | Thiol-yne | Nucleophilic substitution | Polymer-polymer conjugation | Thiol-ene | post-functionalization of polymer | copper catalyzed azide-alkyne cycloaddition (CuAAC) | polymer-polymer conjugation | strain promoted azide-alkyne cycloaddition (SPAAC) | thiol-yne | thiol-ene | POST-FUNCTIONALIZATION | AZIDE-ALKYNE CYCLOADDITION | POLYMER SCIENCE | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | TRIBLOCK COPOLYMERS | 3-MIKTOARM STAR TERPOLYMERS | THIOL-ENE CLICK | SEQUENTIAL MICHAEL ADDITION | DIELS-ALDER REACTION | HETEROGRAFT COPOLYMERS | Polymerization | Thiols | Polymer industry | Polymers | Polymer chemistry | Strategy | Synthesis | Dealing
post‐functionalization of polymer | copper catalyzed azide‐alkyne cycloaddition (CuAAC) | nitroxide radical coupling (NRC) | Michael thiol‐ene | nucleophilic substitution | thiol‐ene | living polymerization | polymer‐polymer conjugation | thiol‐yne | strain promoted azide‐alkyne cycloaddition (SPAAC) | Diels‐Alder | orthogonal multifunctionalization | Copper Catalyzed azide-alkyne cycloaddition (CuAAC) | Living polymerization | Orthogonal multifunctionalization | Strain promoted azide-alkyne cycloaddition (SPAAC) | Post-functionalization of polymer | Michael thiol-ene | Nitroxide Radical Coupling (NRC) | Diels-Alder | Thiol-yne | Nucleophilic substitution | Polymer-polymer conjugation | Thiol-ene | post-functionalization of polymer | copper catalyzed azide-alkyne cycloaddition (CuAAC) | polymer-polymer conjugation | strain promoted azide-alkyne cycloaddition (SPAAC) | thiol-yne | thiol-ene | POST-FUNCTIONALIZATION | AZIDE-ALKYNE CYCLOADDITION | POLYMER SCIENCE | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | TRIBLOCK COPOLYMERS | 3-MIKTOARM STAR TERPOLYMERS | THIOL-ENE CLICK | SEQUENTIAL MICHAEL ADDITION | DIELS-ALDER REACTION | HETEROGRAFT COPOLYMERS | Polymerization | Thiols | Polymer industry | Polymers | Polymer chemistry | Strategy | Synthesis | Dealing
Journal Article
Macromolecular Rapid Communications, ISSN 1022-1336, 01/2013, Volume 34, Issue 1, pp. 38 - 46
This Feature Article focuses on the rapidly emerging concept of the “triple click reactions” towards the design and synthesis of macromolecules with...
nitroxide radical coupling (NRC) | Diels–Alder cycloaddition | copper catalyzed azide–alkyne cycloaddition (CuAAC) | thiol‐ene | living polymerization | copper catalyzed azide-alkyne cycloaddition (CuAAC) | Diels-Alder cycloaddition | thiol-ene | AZIDE-ALKYNE CYCLOADDITION | RADICAL COUPLING REACTIONS | POLYMER SCIENCE | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | TRIBLOCK COPOLYMERS | 3-MIKTOARM STAR TERPOLYMERS | AMBIENT-TEMPERATURE | TERMINAL ALKYNES | POLYMER CONJUGATION | Copper - chemistry | Ultraviolet Rays | Polymers - chemical synthesis | Click Chemistry | Nitrogen Oxides - chemistry | Polymers - chemistry | Sulfhydryl Compounds - chemistry | Alkynes - chemistry | Azides - chemistry | Cycloaddition Reaction | Polymerization | Copper | Polymers | Molecular weight | Synthesis | Utilization | Molecular weight distribution | Strategy | Resultants | Conjugation
nitroxide radical coupling (NRC) | Diels–Alder cycloaddition | copper catalyzed azide–alkyne cycloaddition (CuAAC) | thiol‐ene | living polymerization | copper catalyzed azide-alkyne cycloaddition (CuAAC) | Diels-Alder cycloaddition | thiol-ene | AZIDE-ALKYNE CYCLOADDITION | RADICAL COUPLING REACTIONS | POLYMER SCIENCE | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | TRIBLOCK COPOLYMERS | 3-MIKTOARM STAR TERPOLYMERS | AMBIENT-TEMPERATURE | TERMINAL ALKYNES | POLYMER CONJUGATION | Copper - chemistry | Ultraviolet Rays | Polymers - chemical synthesis | Click Chemistry | Nitrogen Oxides - chemistry | Polymers - chemistry | Sulfhydryl Compounds - chemistry | Alkynes - chemistry | Azides - chemistry | Cycloaddition Reaction | Polymerization | Copper | Polymers | Molecular weight | Synthesis | Utilization | Molecular weight distribution | Strategy | Resultants | Conjugation
Journal Article
Macromolecular Chemistry and Physics, ISSN 1022-1352, 09/2017, Volume 218, Issue 18
Journal Article
Macromolecular Chemistry and Physics, ISSN 1022-1352, 08/2018, Volume 219, Issue 16, pp. 1800163 - n/a
This article investigates the current combinations of click and multicomponent reactions (MCRs) to produce complex macromolecular structures through...
multicomponent reactions | Diels–Alder reactions | click reactions | copper‐catalyzed azide–alkyne cycloaddition reactions | Ugi reactions | Biginelli reactions | thiol‐ene reactions | Passerini reactions | copper-catalyzed azide–alkyne cycloaddition reactions | thiol-ene reactions | copper-catalyzed azide-alkyne cycloaddition reactions | POLYMER SCIENCE | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | SIDE-CHAIN | UGI 4-COMPONENT REACTION | PASSERINI 3-COMPONENT REACTION | Diels-Alder reactions | FUNCTIONAL POLYMERS | CYCLOADDITION | SEQUENCE | MODULAR SYNTHESIS | POLYAMIDES | Polymers | Polymer industry | Substitution reactions | Organic chemistry | Polymer chemistry | Conjugation | Molecular structure
multicomponent reactions | Diels–Alder reactions | click reactions | copper‐catalyzed azide–alkyne cycloaddition reactions | Ugi reactions | Biginelli reactions | thiol‐ene reactions | Passerini reactions | copper-catalyzed azide–alkyne cycloaddition reactions | thiol-ene reactions | copper-catalyzed azide-alkyne cycloaddition reactions | POLYMER SCIENCE | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | SIDE-CHAIN | UGI 4-COMPONENT REACTION | PASSERINI 3-COMPONENT REACTION | Diels-Alder reactions | FUNCTIONAL POLYMERS | CYCLOADDITION | SEQUENCE | MODULAR SYNTHESIS | POLYAMIDES | Polymers | Polymer industry | Substitution reactions | Organic chemistry | Polymer chemistry | Conjugation | Molecular structure
Journal Article
Macromolecular Chemistry and Physics, ISSN 1022-1352, 09/2017, Volume 218, Issue 18, pp. 1700352 - n/a
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 10/2011, Volume 6, Issue 10, pp. 2584 - 2591
Well‐defined polymeric structures were easily generated through living polymerization systems, in particular, living radical polymerizations. The polymeric...
catalysis | copper | cycloaddition | radicals | terpolymers | AZIDE-ALKYNE CYCLOADDITION | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | MIKTOARM STAR TERPOLYMERS | CHEMISTRY, MULTIDISCIPLINARY | THERMO-RESPONSIBILITY | DIELS-ALDER REACTION | TRIBLOCK TERPOLYMERS | RING-OPENING POLYMERIZATION | RADICAL POLYMERIZATION | H-SHAPED TERPOLYMERS | Copper - chemistry | Cyclization | Polymers - chemical synthesis | Click Chemistry | Polymers - chemistry | Alkynes - chemistry | Molecular Structure | Catalysis | Azides - chemistry
catalysis | copper | cycloaddition | radicals | terpolymers | AZIDE-ALKYNE CYCLOADDITION | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | MIKTOARM STAR TERPOLYMERS | CHEMISTRY, MULTIDISCIPLINARY | THERMO-RESPONSIBILITY | DIELS-ALDER REACTION | TRIBLOCK TERPOLYMERS | RING-OPENING POLYMERIZATION | RADICAL POLYMERIZATION | H-SHAPED TERPOLYMERS | Copper - chemistry | Cyclization | Polymers - chemical synthesis | Click Chemistry | Polymers - chemistry | Alkynes - chemistry | Molecular Structure | Catalysis | Azides - chemistry
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 06/2018, Volume 56, Issue 12, pp. 1181 - 1198
ABSTRACT Post‐polymerization modification (PPM) of polymers is extremely beneficial in terms of designing brand new synthetic pathways toward functional...
fluorinated polymers | post‐polymerization modifications | click reactions | pentafluorophenyl | thiol‐para‐fluoro nucleophilic aromatic substitution reactions | thiol-para-fluoro nucleophilic aromatic substitution reactions | post-polymerization modifications | POLYMER SCIENCE | GRAFT-COPOLYMERS | BLOCK-COPOLYMERS | EFFICIENT SYNTHESIS | TRANSFER RADICAL POLYMERIZATION | ENE CLICK | MICHAEL ADDITION | HYPERBRANCHED FLUOROPOLYMERS | CONTAINING POLYMERS | DIELS-ALDER REACTION | CHEMISTRY | Substitution reactions | Polymerization | Thiols | Methods | Organic chemistry | Fluorine | Chemical reactions | Polymers | Fluorination
fluorinated polymers | post‐polymerization modifications | click reactions | pentafluorophenyl | thiol‐para‐fluoro nucleophilic aromatic substitution reactions | thiol-para-fluoro nucleophilic aromatic substitution reactions | post-polymerization modifications | POLYMER SCIENCE | GRAFT-COPOLYMERS | BLOCK-COPOLYMERS | EFFICIENT SYNTHESIS | TRANSFER RADICAL POLYMERIZATION | ENE CLICK | MICHAEL ADDITION | HYPERBRANCHED FLUOROPOLYMERS | CONTAINING POLYMERS | DIELS-ALDER REACTION | CHEMISTRY | Substitution reactions | Polymerization | Thiols | Methods | Organic chemistry | Fluorine | Chemical reactions | Polymers | Fluorination
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 05/2011, Volume 49, Issue 9, pp. 1962 - 1968
Azide‐alkyne and Diels–Alder click reactions together with a click‐like nitroxide radical coupling reaction were used in a one‐pot fashion to generate...
Diels–Alder cycloaddition reaction | nitroxide radical coupling reaction | poly(tert‐butyl acrylate) | click reactions | quaterpolymer | polystyrene | atom transfer radical polymerization (ATRP) | poly(ε‐caprolactone) | block copolymer | azide‐alkyne cycloaddition reaction | NMR | poly(n‐butyl acrylate) | poly(ethylene glycol) | GPC | ring opening polymerization (ROP) | azide-alkyne cycloaddition reaction | poly(tert-butyl acrylate) | Diels-Alder cycloaddition reaction | poly(Îμ-caprolactone) | poly(n-butyl acrylate) | TRIBLOCK COPOLYMERS | POLYMERIZATION | FUNCTIONALIZED POLYMERS | CHEMISTRY | poly(epsilon-caprolactone) | POLYMER SCIENCE | GRAFT-COPOLYMERS | SET-LRP | MATERIALS SCIENCE | DEFINED BLOCK-COPOLYMERS | MODULAR SYNTHESIS | STAR POLYMERS | Chemical industry | Polystyrene resins | Anthracene | Nuclear magnetic resonance--NMR | Dimethyl formamide | Polyethylene glycol | Liquid chromatography | Coupling | Alkynes | Acrylics | Acrylates | Reproduction | Precursors | Joining | Radicals | Gel permeation chromatography
Diels–Alder cycloaddition reaction | nitroxide radical coupling reaction | poly(tert‐butyl acrylate) | click reactions | quaterpolymer | polystyrene | atom transfer radical polymerization (ATRP) | poly(ε‐caprolactone) | block copolymer | azide‐alkyne cycloaddition reaction | NMR | poly(n‐butyl acrylate) | poly(ethylene glycol) | GPC | ring opening polymerization (ROP) | azide-alkyne cycloaddition reaction | poly(tert-butyl acrylate) | Diels-Alder cycloaddition reaction | poly(Îμ-caprolactone) | poly(n-butyl acrylate) | TRIBLOCK COPOLYMERS | POLYMERIZATION | FUNCTIONALIZED POLYMERS | CHEMISTRY | poly(epsilon-caprolactone) | POLYMER SCIENCE | GRAFT-COPOLYMERS | SET-LRP | MATERIALS SCIENCE | DEFINED BLOCK-COPOLYMERS | MODULAR SYNTHESIS | STAR POLYMERS | Chemical industry | Polystyrene resins | Anthracene | Nuclear magnetic resonance--NMR | Dimethyl formamide | Polyethylene glycol | Liquid chromatography | Coupling | Alkynes | Acrylics | Acrylates | Reproduction | Precursors | Joining | Radicals | Gel permeation chromatography
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 08/2018, Volume 56, Issue 16, pp. 1853 - 1859
ABSTRACT The para‐fluoro‐thiol “click” reaction (PFTCR) was utilized to prepare linear and hyperbranched fluorinated poly (aryl ether‐thioether). For this...
linear polymers | fluorinated poly(aryl ether‐thioether) | para‐fluoro‐thiol “click” reaction | hyperbranched polymers | fluorinated poly(aryl ether-thioether) | para-fluoro-thiol “click” reaction | POST-FUNCTIONALIZATION | POLYMERS | POLYMER SCIENCE | CHEMISTRY | LIGATION | COPOLYMERS | POWERFUL | para-fluoro-thiol "click" reaction | hyper-branched polymers | TOOL | Polymers | Analysis | Thiols | Infrared spectroscopy | Fourier transforms | Addition polymerization | Nuclear magnetic resonance--NMR | Fluorine | Aromatic compounds | Chemical reactions | Liquid chromatography | Fluorination | Ethane
linear polymers | fluorinated poly(aryl ether‐thioether) | para‐fluoro‐thiol “click” reaction | hyperbranched polymers | fluorinated poly(aryl ether-thioether) | para-fluoro-thiol “click” reaction | POST-FUNCTIONALIZATION | POLYMERS | POLYMER SCIENCE | CHEMISTRY | LIGATION | COPOLYMERS | POWERFUL | para-fluoro-thiol "click" reaction | hyper-branched polymers | TOOL | Polymers | Analysis | Thiols | Infrared spectroscopy | Fourier transforms | Addition polymerization | Nuclear magnetic resonance--NMR | Fluorine | Aromatic compounds | Chemical reactions | Liquid chromatography | Fluorination | Ethane
Journal Article
Polym. Chem, ISSN 1759-9954, 2012, Volume 3, Issue 4, pp. 825 - 835
Journal Article
Polymer Chemistry, ISSN 1759-9954, 3/2012, Volume 3, Issue 4, pp. 825 - 835
Double click reaction strategies, which are a combination of different type of click reactions, allow the preparation of polymers with various topologies and...
POLYMER SCIENCE | FACILE SYNTHESIS | LIVING RADICAL POLYMERIZATION | ONE-POT SYNTHESIS | FRAGMENTATION CHAIN TRANSFER | TRIBLOCK COPOLYMERS | DIELS-ALDER REACTION | HETEROGRAFT COPOLYMERS | MACROMOLECULAR ARCHITECTURES | STAR-BLOCK-COPOLYMERS | THIOL-ENE CLICK
POLYMER SCIENCE | FACILE SYNTHESIS | LIVING RADICAL POLYMERIZATION | ONE-POT SYNTHESIS | FRAGMENTATION CHAIN TRANSFER | TRIBLOCK COPOLYMERS | DIELS-ALDER REACTION | HETEROGRAFT COPOLYMERS | MACROMOLECULAR ARCHITECTURES | STAR-BLOCK-COPOLYMERS | THIOL-ENE CLICK
Journal Article
Macromolecular Chemistry and Physics, ISSN 1022-1352, 09/2017, Volume 218, Issue 18, pp. 1600572 - n/a
A combination of light‐induced [4+4] cycloaddition polymerization and activated ester substitution reaction is demonstrated as a new method to obtain novel...
perfluorophenyl ester | light‐induced [4+4] cycloaddition polymerization | anthracene dimerization | activated ester substitution | postpolymerization functionalization | light-induced [4+4] cycloaddition polymerization | POST-FUNCTIONALIZATION | POLYMERS | POLYMER SCIENCE | LIGATION | ANTHRACENE | COPOLYMERS | METHACRYLATE | PHOTODIMERIZATION | PENTAFLUOROPHENYL ESTER | CLICK REACTION STRATEGY | CHEMISTRY | Polymerization | Polyols | Infrared spectroscopy | Fourier transforms | Cycloaddition | Anthracene | Nuclear magnetic resonance--NMR | Liquid chromatography | Heat measurement | Polyester resins | Chemical synthesis | Esterification
perfluorophenyl ester | light‐induced [4+4] cycloaddition polymerization | anthracene dimerization | activated ester substitution | postpolymerization functionalization | light-induced [4+4] cycloaddition polymerization | POST-FUNCTIONALIZATION | POLYMERS | POLYMER SCIENCE | LIGATION | ANTHRACENE | COPOLYMERS | METHACRYLATE | PHOTODIMERIZATION | PENTAFLUOROPHENYL ESTER | CLICK REACTION STRATEGY | CHEMISTRY | Polymerization | Polyols | Infrared spectroscopy | Fourier transforms | Cycloaddition | Anthracene | Nuclear magnetic resonance--NMR | Liquid chromatography | Heat measurement | Polyester resins | Chemical synthesis | Esterification
Journal Article
Journal of Polymer Science, Part A: Polymer Chemistry, ISSN 0887-624X, 10/2011, Volume 49, Issue 19, pp. 4103 - 4120
Functional polymeric materials with desired properties can be designed by precise control of macromolecular architectures. Over the recent years, click...
star polymers | click chemistry | Diels-Alder polymers | dendrimers | diblock copolymers | DESIGN | POLYMER SCIENCE | MULTIARM STAR POLYMERS | BLOCK-COPOLYMERS | CYCLOADDITION | CONJUGATION | CHEMISTRY | RADICAL POLYMERIZATION | POLYPHENYLENE DENDRIMERS | MENDABLE POLYMERS | EFFICIENT
star polymers | click chemistry | Diels-Alder polymers | dendrimers | diblock copolymers | DESIGN | POLYMER SCIENCE | MULTIARM STAR POLYMERS | BLOCK-COPOLYMERS | CYCLOADDITION | CONJUGATION | CHEMISTRY | RADICAL POLYMERIZATION | POLYPHENYLENE DENDRIMERS | MENDABLE POLYMERS | EFFICIENT
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 02/2016, Volume 54, Issue 4, pp. 480 - 486
ABSTRACT The aliphatic polyurethane with pendant alkyne, perfluorophenyl, and anthracene moieties (PU‐anthracene) was prepared from polycondensation of...
aliphatic polyurethane (PU) | perfluorophenyl ester | differential scanning calorimetry (DSC) | active ester substitution | anthracene | polycondensation | NMR | maleimide | alkyl amine | CuAAC | alkyne | Diels–Alder reaction | azide | Diels-Alder reaction | POLYMERS | POLYMER SCIENCE | OILS | ONE-POT | POLYMERIZATION | FUNCTIONALIZATION | CONJUGATION | CHEMISTRY | Polyurethanes | Furans | Diels-Alder reactions | Polyurethane resins | Cycloaddition | Anthracene | Esters | Aliphatic compounds | Standards | Alkynes
aliphatic polyurethane (PU) | perfluorophenyl ester | differential scanning calorimetry (DSC) | active ester substitution | anthracene | polycondensation | NMR | maleimide | alkyl amine | CuAAC | alkyne | Diels–Alder reaction | azide | Diels-Alder reaction | POLYMERS | POLYMER SCIENCE | OILS | ONE-POT | POLYMERIZATION | FUNCTIONALIZATION | CONJUGATION | CHEMISTRY | Polyurethanes | Furans | Diels-Alder reactions | Polyurethane resins | Cycloaddition | Anthracene | Esters | Aliphatic compounds | Standards | Alkynes
Journal Article