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ChemCatChem, ISSN 1867-3880, 02/2012, Volume 4, Issue 2, pp. 177 - 185
Journal Article
Chemical Communications, ISSN 1359-7345, 2009, Issue 16, pp. 2086 - 2099
Over the past two decades there has been a dramatic increse in the use of hypervalent iodine compounds in synthetic organic chemistry due to their mild and... 
O-IODOXYBENZOIC ACID | M-CHLOROPERBENZOIC ACID | DESS-MARTIN PERIODINANE | P-TOLUENESULFONIC ACID | 2-IODOXYBENZENESULFONIC ACID | OXIDIZING REAGENTS | CARBONYL-COMPOUNDS | IN-SITU GENERATION | CHEMISTRY, MULTIDISCIPLINARY | POLYMER-SUPPORTED IBX | RAY CRYSTAL-STRUCTURE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 3956 - 3960
A site‐selective hydroxylative dearomatization of 2‐substituted phenols to either 1,2‐benzoquinols or their cyclodimers, catalyzed by... 
oxidation | phenol | iodine | silicon | hypervalent compounds | REGIOSELECTIVE OXIDATION | ORGANIC-SYNTHESIS | IODOARENES | SIBX | CHEMISTRY, MULTIDISCIPLINARY | SESQUITERPENOIDS | SKELETON | ALCOHOLS | METHYL-ETHER | OXONE(R) | DEAROMATIZATION | Methyl ether | Phenols | Oxidation-reduction reaction | Selectivity | Oxidation | Cascade chemical reactions | Acids | Natural products
Journal Article
ChemCatChem, ISSN 1867-3880, 02/2012, Volume 4, Issue 2, pp. 177 - 185
This Concept highlights the discovery and development of oxidative coupling reactions catalyzed by the hypoiodite (IO−) or iodite (OIO−) ion, which are... 
chemoselectivity | oxidative coupling | TBHP | iodine | homogeneous catalysis | hydrogen peroxide | ORGANIC-SYNTHESIS | CHEMISTRY, PHYSICAL | CARBONYL-COMPOUNDS | M-CHLOROPERBENZOIC ACID | HYPERVALENT | ALPHA-ACETOXY KETONES | POLYVALENT IODINE COMPOUNDS | AMINO-ACIDS | PHENOL DEAROMATIZATION | CYCLIZATION | CARBOXYLIC-ACIDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2011, Volume 50, Issue 23, pp. 5331 - 5334
It′s the iodine: The intra‐ and intermolecular title reaction is catalyzed by an in situ generated ammonium (hypo)iodite species. Either H2O2 or tert‐butyl... 
oxidation | iodine | heterocycles | cyclization | hypervalent compounds | M-CHLOROPERBENZOIC ACID | ACETOXY KETONES | CHEMISTRY | ACETATE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2019, Volume 2019, Issue 1, pp. 1 - 1
The Front Cover shows a chef (chemist) who is synthesizing a 2‐chlorinated compound from 1‐alkyl‐2‐naphthol, sodium chloride, and Oxone in a solvent,... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2010, Volume 49, Issue 12, pp. 2175 - 2177
The iodines(III) have it: The rational design of a conformationally flexible C2‐symmetric iodosylarene catalyst has been used for the enantioselective Kita... 
organocatalysis | spirolactones | asymmetric oxidation | iodine | hypervalent compounds | Asymmetric oxidation | Organocatalysis | Hypervalent compounds | Iodine | Spirolactones | REAGENTS | IODOARENES | SULFIDES | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | SULFOXIDES | KETONES | PHENOLS | ENONES | DEAROMATIZATION
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2019, Volume 2019, Issue 1, pp. 27 - 31
We developed a practical and environmentally benign method for the chlorinative dearomatization of arenols using transient electrophilic chlorinating species... 
Dearomatization | Phenols | Oxidation | Chlorination | Regioselectivity | Chemoselectivity | CARBON | PHENOL | CATALYTIC ASYMMETRIC DEAROMATIZATION | CHEMISTRY, ORGANIC | CONVENIENT | IPSO-CHLORINATION | HALOGENATION | SODIUM-HYPOCHLORITE | METHYL-ETHER | POTASSIUM | CHLORIDE
Journal Article
Chemistry Letters, ISSN 0366-7022, 01/2019, Volume 48, Issue 4, p. 353
The first transition metal-free catalytic oxidative dearomatizative azidation of arenols has been developed using hypoiodite catalysis with aqueous hydrogen... 
Transition metals | Hydrogen peroxide | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2009, Volume 131, Issue 1, pp. 251 - 262
Electron-donating group-substituted 2-iodoxybenzoic acids (IBXs) such as 5-Me-IBX (1g), 5-MeO-IBX (1h), and 4,5-Me2-IBX (1i) were superior to IBX 1a as... 
O-IODOXYBENZOIC ACID | ORGANIC-SYNTHESIS | DEHYDROGENATION | REDUCTION | SULFIDES | GENERALITY | IODINE(V) REAGENTS | SAFE OXIDATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | IBX
Journal Article
ACS Catalysis, ISSN 2155-5435, 04/2013, Volume 3, Issue 4, pp. 513 - 520
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2017, Volume 7, Issue 1, pp. 872 - 876
A highly enantioselective oxidative dearomatization of ortho- and para-hydroquinone derivatives to the corresponding masked ortho- and para-benzoquinones has... 
hypervalent iodine | hydrogen bonds | masked benzoquinones | enantioselective catalysis | dearomatization | ORGANIC-SYNTHESIS | HYDROXYLATIVE PHENOL DEAROMATIZATION | ASYMMETRIC-SYNTHESIS | IODOARENES | QUINOLS | OXIDATIVE DEAROMATIZATION | CHEMISTRY, PHYSICAL | SPIROLACTONIZATION | ALKENES | IODINE REAGENTS | DIFLUORINATION
Journal Article
Tetrahedron, ISSN 0040-4020, 2010, Volume 66, Issue 31, pp. 5841 - 5851
We demonstrate here the rational design of a conformationally flexible -symmetric iodosylarene based on secondary –σ or hydrogen-bonding interactions as a... 
Dearomatization | Hypervalent iodine | Asymmetric oxidation | Spirolactone | REAGENTS | IODOARENES | REACTIVITY | CHEMISTRY, ORGANIC | IN-SITU GENERATION | M-CHLOROPERBENZOIC ACID | SULFOXIDES | KETONES | PHENOL DEAROMATIZATION | COMPLEXATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2012, Volume 51, Issue 36, pp. 9093 - 9096
Efficient and selective: Two lipophilic catalysts were used for Baeyer–Villiger (BV) oxidations to give lactones in high yields (see scheme). Cascade reactions... 
oxidation | lactones | alkaline earth metals | borates | alkali metals | METHYLTRIOXORHENIUM | BENZYLATION | ACETALS | CHEMISTRY, MULTIDISCIPLINARY | KETONES | H2O2/NITRILE | CHIRAL BRONSTED ACID | SODIUM TETRAKIS(3,5-TRIFLUOROMETHYLPHENYL)BORATE | CYCLOBUTANONES | CYCLIZATION
Journal Article