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Nature Communications, ISSN 2041-1723, 06/2017, Volume 8, Issue 1, p. 15547
The enantioselective silylation of racemic alcohols, where one enantiomer reacts faster than the other, is an alternative approach to established enzymatic and... 
SILICON-STEREOGENIC SILANES | SECONDARY ALCOHOLS | ENANTIOSELECTIVE SILYLATION | ASYMMETRIC SILYLATION | 1,2-DIOLS | PROTECTION | MULTIDISCIPLINARY SCIENCES | STEREOSELECTIVE SILYLATION | DESYMMETRIZATION
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2010, Volume 8, Issue 7, pp. 1497 - 1504
Stereoselective Si-O couplings are auspicious processes for the synthesis of both chiral alcohols and chiral silanes. Attractive facets of this theme are... 
SILICON-STEREOGENIC SILANES | SECONDARY ALCOHOLS | CHIRALITY TRANSFER | MECHANISM | HYDROSILYLATION | CHEMISTRY, ORGANIC | NONENZYMATIC KINETIC RESOLUTION | DONOR-FUNCTIONALIZED ALCOHOLS | STEREOSELECTIVE SILYLATION | RHODIUM COMPLEXES | ORGANOSILICON COMPOUNDS
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 03/2009, Volume 4, Issue 3, pp. 406 - 410
As simple as it gets! Potassium tert‐butoxide alone catalyzes the direct dehydrogenative SiO coupling of several synthetically important silanes with 1°, 2°,... 
reaction mechanisms | alcohols | silylation | nucleophilic substitution | protective groups | Protective groups | Nucleophilic substitution | Reaction mechanisms | Silylation | Alcohols | SILICON-STEREOGENIC SILANES | STEREOCHEMISTRY CROSSOVER | SUBSTITUTION | KINETIC RESOLUTION | HYDROSILYLATION | HYDROLYSIS | ASYMMETRIC SILICON | EXCHANGE | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | TRIORGANOSILANES
Journal Article
Organic Letters, ISSN 1523-7060, 02/2013, Volume 15, Issue 4, pp. 792 - 795
A mild method for the regioselective C2-bromination of fused azine N-oxides is presented, employing tosic anhydride as the activator and tetra-n-butylammonium... 
BIOLOGICAL EVALUATION | 1ST SYNTHESES | CHEMISTRY, ORGANIC | POTENT | PYRIDINE | Cyclic N-Oxides - chemistry | Stereoisomerism | Halogenation | Hydrocarbons, Brominated - chemical synthesis | Hydrocarbons, Brominated - chemistry | Molecular Structure | Catalysis
Journal Article
ChemCatChem, ISSN 1867-3880, 10/2011, Volume 3, Issue 10, pp. 1527 - 1529
Reduced to the basics: Activation of Lewis acidic Cl3SiH with chiral amide‐based Lewis bases allows for the stereocontrolled reduction of several types of... 
organocatalysis | silicon | Lewis base | reduction | β‐amino acids | IMINES | HYDROSILYLATION | ENANTIOSELECTIVE REDUCTION | CHEMISTRY, PHYSICAL | AMINO ACID-DERIVATIVES | TRICHLOROSILANE | beta-amino acids | Reduction | Silicon | β-amino acids | Organocatalysis
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2012, Volume 68, Issue 17, pp. 3468 - 3479
Asymmetric silylation of alcohols is an unusual but effective approach to their kinetic resolution, and the Cu–H-catalyzed dehydrogenative Si–O coupling is... 
Enantioselective silylation | Silicon | Copper | Kinetic resolution | Oxime ethers | PROTECTION | MECHANISM | SCOPE | REACTIVITY | CHEMISTRY, ORGANIC | NONENZYMATIC KINETIC RESOLUTION | STEREOSELECTIVE SILYLATION | SILICON-STEREOGENIC SILANES | SECONDARY ALCOHOLS | EPOXIDES | LIGANDS | Enantiomers | Silane | Oximes | Silanes | Catalysts | Dehydrogenation | Reaction kinetics | Byproducts | Joining | Alcohols
Journal Article
Chemistry - An Asian Journal, ISSN 1861-4728, 03/2009, Volume 4, Issue 3, pp. 406 - 410
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2010, Volume 49, Issue 12, pp. 2223 - 2226
Journal Article
Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, ISSN 1539-3755, 03/2011, Volume 83, Issue 3, p. 036305
The work describes the experimental and theoretical investigation of water drop impact onto electrospun polymer nanofiber mats deposited on heated... 
HEAT-TRANSFER | PHYSICS, FLUIDS & PLASMAS | IMPINGEMENT | JETS | SPRAY | PHYSICS, MATHEMATICAL | SURFACES
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 2010, Volume 21, Issue 9, pp. 1232 - 1237
A simple and reliable protocol for the synthesis of TADDOL-derived monodentate ligands is reported. The reaction of the requisite TADDOL with PCl is... 
AUXILIARIES | KETONES | REAGENTS | ASYMMETRIC CONJUGATE ADDITION | DIELS-ALDER REACTIONS | ANALOGS | COMPLEXES | ENONES | CHEMISTRY, PHYSICAL | RHODIUM-CATALYZED HYDROGENATION | DERIVATIVES
Journal Article
2013, 1. Aufl., ISBN 9783527329212, 432
Continuing the proven and successful concept of the well-received textbook 'Asymmetric Synthesis - The Essentials', this is a brief and timely update on the... 
Asymmetric synthesis
eBook
Angewandte Chemie, ISSN 0044-8249, 03/2010, Volume 122, Issue 12, p. 2269
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2010, Volume 122, Issue 12, pp. 2269 - 2272
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2010, Volume 122, Issue 12, pp. 2269 - 2272
Racematspaltung auf Siliciumbasis: Si‐H und H‐OR werden mithilfe eines chiralen Cu‐H‐Komplexes enantioselektiv gekuppelt. So gelang die kinetische... 
Silicium | Asymmetrische Katalyse | Dehydrierende Kupplungen | Kinetische Racematspaltung | Einzähnige Liganden
Journal Article
07/2019
The present invention relates to a process for hydrogenating a mixture (G1) in the presence of a catalyst, where the mixture (G1) comprises at least one... 
METALLURGY | ORGANIC CHEMISTRY | CHEMISTRY | ACYCLIC OR CARBOCYCLIC COMPOUNDS
Patent
07/2019
The present invention relates to a process for hydrogenating a mixture (G1) in the presence of a catalyst, where the mixture (G1) comprises at least one... 
METALLURGY | ORGANIC CHEMISTRY | CHEMISTRY | ACYCLIC OR CARBOCYCLIC COMPOUNDS
Patent
05/2019
본 발명은 촉매의 존재 하에 혼합물 (G1)을 수소화하는 방법으로서, 혼합물 (G1)은 적어도 하나의 무색 아민 및 적어도 하나의 색 부여 성분을 포함하는 것인 방법에 관한 것이다. 수소화 단계의 결과로서, 적어도 하나의 색 부여 성분은 우선 부분적으로, 바람직하게는 완전히... 
METALLURGY | ORGANIC CHEMISTRY | CHEMISTRY | ACYCLIC OR CARBOCYCLIC COMPOUNDS
Patent
ChemInform, ISSN 0931-7597, 04/2010, Volume 41, Issue 15, pp. no - no
ChemInform is a weekly ing Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform of an... 
organic chemistry, review | hydrosilylation, silylation, phosphorylation | catalysis, phase‐transfer catalysis
Journal Article
ChemInform, ISSN 0931-7597, 10/2012, Volume 43, Issue 44, pp. no - no
A series of oxime ether‐functionalized alcohols such as (I) and (II) are prepared on two routes. 
organo‐silicon compounds | diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) | hydrosilylation, silylation, phosphorylation | Enantiomers
Journal Article
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