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INORGANIC CHEMISTRY, ISSN 0020-1669, 04/2019, Volume 58, Issue 8, pp. 4812 - 4819
We report the first examples of the carbide ligand in (Cy3P)(2)Cl2Ru C (RuC) developing into a mu(3) ligand toward metal centers. Conventionally, sterics... 
GENERATION | CRYSTAL | CARBON COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Oorganisk kemi | Naturvetenskap | Natural Sciences | Inorganic Chemistry | Kemi | Chemical Sciences
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2015, Volume 51, Issue 5, pp. 911 - 913
Cyclometallation of 2-(1-naphthyl)-pyridine is described. While cyclopalladation results in a five-membered metallacycle, cycloauration displays a completely... 
FUNCTIONALIZATION | CATALYZED CYANATION | ACTIVATION | C-H BOND | 2-ARYLPYRIDINES | ARENES | SITE-SELECTIVITY | RUTHENIUM | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | BENZOXYLATION | Gold | Displays | Bromination | Analogue | Metalorganic compounds
Journal Article
Dalton Transactions, ISSN 1477-9226, 10/2016, Volume 45, Issue 40, pp. 15963 - 15969
A novel electron deficient 4,6-bis(trifluoromethyl)-1,3-phenylene diphosphinite ligand 4 was developed and synthesized. Reaction of Ir precursors with ligand 4... 
Catalysts | Dehydrogenation | Alkanes | Ligands | Iridium | Catalysis | NMR spectroscopy | Adducts
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2015, Volume 54, Issue 32, pp. 9372 - 9375
Despite significant progress in recent years, the cleavage of unstrained C(sp(3))C(sp(3)) bonds remains challenging. A CC coupling and cleavage reaction in a... 
CARBENE POLYMERIZATION | ACTIVATION | REACTIVITY | CARBON-CARBON BONDS | CHEMISTRY, MULTIDISCIPLINARY | iridium | FUNCTIONALIZATION | density functional calculations | MIGRATORY INSERTION | COUPLING REACTIONS | kinetics | elimination | pincer complexes | C-H | Naturvetenskap | Kemi | Natural Sciences | Chemical Sciences
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 2, pp. 525 - 531
2-(1-Naphthyl)-pyridine (1) possesses sp(2) C-H bonds in both the gamma- and delta-positions and is therefore a suitable substrate for studying the... 
CATALYZED CYANATION | ROOM-TEMPERATURE | FUNCTIONALIZATIONS | 2-ARYLPYRIDINES | COMPLEXES | ARENES | DIRECT ORTHO ARYLATION | RUTHENIUM | BOND ACTIVATION | BORYLATION | CHEMISTRY, INORGANIC & NUCLEAR | Thermodynamics | Gold | Reagents | Activation | Dimers | Selectivity | Palladium | Substrates
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2018, Volume 83, Issue 18, pp. 10864 - 10870
A simple method has been developed for the cross dehydrogenative coupling between two different primary alcohols using readily available RuCl2(PPh3)3 as a... 
SECONDARY ALCOHOLS | METHYLATION | METHANOL | IRIDIUM | COMPLEXES | CHEMISTRY, ORGANIC | CONDENSATION | ALPHA-ALKYLATED KETONES | ALDEHYDES | 2-ARYLETHANOLS
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 09/2017, Volume 845, pp. 157 - 164
Through a salt metathesis reaction, ( PCN)Pd-ONO ( ) was prepared and used as a precursor for producing ( PCN)Pd-OH ( ) and ( PCN)Pd-aryl acetylide complexes... 
Carboxylation | Palladium | Aromatic pincer complexes | Decarboxylative cross coupling | PCN pincer ligand | Analytical Chemistry | Naturvetenskap | Kemi | Natural Sciences | Analytisk kemi | Chemical Sciences
Journal Article
Chemistry (Weinheim an der Bergstrasse, Germany), ISSN 0947-6539, 10/2019, Volume 25, Issue 59, pp. 13591 - 13597
A new generation of N-heterocyclic carbene palladium(II) complexes containing vinyl groups in different positions in the backbone of the N-heterocycle have... 
Journal Article
Polyhedron, ISSN 0277-5387, 03/2018, Volume 143, p. 132
A nickel(II) hydroxo complex (3) supported by a cyclohexyl based POC.sub.sp3OP pincer ligand (POC.sub.sp3OP = cis-1,3-Bis-(di-tert-butylphosphinito)cyclohexyl)... 
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2014, Volume 751, pp. 213 - 220
The catalytic incorporation of CO into value-added chemicals to form e.g. carboxylic acids and carbonates is highly interesting due to the abundance,... 
Carbon dioxide | Insertion | Green chemistry | Palladium | Carboxylic acids
Journal Article
ISSN 1477-9226, 10/2016, Volume 45, Issue 4, pp. 15963 - 15969
A novel electron deficient 4,6-bis(trifluoromethyl)-1,3-phenylene diphosphinite ligand 4 was developed and synthesized. Reaction of Ir precursors with ligand 4... 
Journal Article
Chemical Science, ISSN 2041-6520, 03/2015, Volume 6, Issue 3, pp. 2060 - 2067
The search for novel, atom-economic methods for the formation of C-C bonds is of crucial importance in synthetic chemistry. Especially attractive are reactions... 
FUNCTIONALIZATION | ALKANE METATHESIS | LIGANDS | COUPLING REACTIONS | TERMINAL ACETYLENES | X-RAY STRUCTURE | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | METAL-COMPLEXES | CARBENE COMPLEX | DEHYDROGENATION-OLEFIN-METATHESIS | Carbon-carbon composites | Chemical reactions | Cleavage | Activation | Formations | Carbon | Bonding | Activation analysis
Journal Article
Organometallics, ISSN 0276-7333, 08/2010, Volume 29, Issue 16, pp. 3521 - 3529
The reaction of the σ-bonded (PCP)Pd-Me complex (PCP = 2,6-bis[(di-tert-butylphosphino)methyl]phenyl) with CO2 is first-order in palladium and first-order in... 
Journal Article
Organometallics, ISSN 0276-7333, 04/2007, Volume 26, Issue 9, pp. 2426 - 2430
{2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}palladium hydroxide, PCPPdOH, undergoes a fast insertion of CO2 to give the bicarbonate complex (PCP)PdO2COH. It... 
ACTIVATION | ALKYL | LIGANDS | IRIDIUM | INSERTION REACTIONS | DIOXIDE | BONDS | CHEMISTRY, ORGANIC | X-RAY STRUCTURE | HYDROXYCARBONYL | CARBOXYLIC-ACIDS | CHEMISTRY, INORGANIC & NUCLEAR | Naturvetenskap | Organisk kemi | Natural Sciences | Kemi | Chemical Sciences | Organic Chemistry
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2015, Volume 44, Issue 12, pp. 5347 - 5353
Cyclometallated aryl-pyridine gold(III) complexes are shown to be efficient catalysts for the multicomponent reaction between N-benzyl imines, alkynes, and... 
REACTIVITY | GOLD CATALYSIS | AMINES | SCOPE | CHEMISTRY, INORGANIC & NUCLEAR | Diffraction | Imines | Catalysts | Chlorides | X-rays | Oxazole | Catalysis | Alkynes
Journal Article
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