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Journal Article
Angewandte Chemie, ISSN 1521-3757, 2018, Volume 130, Issue 27, pp. 8281 - 8285
Cysteamine dioxygenase (ADO) is a thiol dioxygenase whose study has been stagnated by the ambiguity as to whether or not it possesses an anticipated... 
Proteine | Aminosäuren | Dioxygenasen | C-H-Aktivierung | Fluor | Crosslinked polymers | Thiols | Phenols | Cysteamine | Nuclear magnetic resonance spectroscopy | Amino acids | Fluorides | Mass spectrometry | Tyrosine | Fluorine | Cysteamine dioxygenase | Cysteine dioxygenase | Mass spectroscopy | Crosslinking | Biosynthesis | Proteins | Magnetic resonance spectroscopy | Fluoride | NMR spectroscopy
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2011, Volume 133, Issue 42, pp. 16774 - 16777
Lithium enolates are widely used nucleophiles with a complicated and only partially understood solution chemistry. Deprotonation of 4-fluoroacetophenone in THF... 
DIISOPROPYLAMIDE | KETONE | THF | CYCLIC DIMERS | LIGANDS | LITHIOPINACOLONATE | ALKYLATION KINETICS | ENOLIZATION | 2,2,6,6-TETRAMETHYLPIPERIDIDE | CHEMISTRY, MULTIDISCIPLINARY | MIXED AGGREGATION | Thermal properties | Usage | Analysis | Chemical bonds | Nuclear magnetic resonance spectroscopy | Chemical properties | Aldehydes | Lithium compounds | Enolates | Electric properties
Journal Article
Plant physiology (Bethesda), ISSN 1532-2548, 2019, Volume 181, Issue 1, pp. 63 - 84
Lignin provides essential mechanical support for plant cell walls but decreases the digestibility of forage crops and increases the recalcitrance of biofuel... 
SHIKIMATE ESTERASE | CELL-WALL INTEGRITY | CAFFEIC ACID 3-O-METHYLTRANSFERASE | SALICYLIC-ACID | DOWN-REGULATION | MONOLIGNOL BIOSYNTHESIS | SAPONIN BIOSYNTHESIS | COENZYME-A 3-O-METHYLTRANSFERASE | PLANT-GROWTH | DISEASE RESISTANCE | PLANT SCIENCES | BASIC BIOLOGICAL SCIENCES
Journal Article
Plant Physiology, ISSN 0032-0889, 9/2019, Volume 181, Issue 1, pp. 63 - 84
Growth defects arising from lignin modification are associated with the extent, but not the nature, of ectopic expression of defense pathways. Lignin provides... 
Journal Article
Metabolites, ISSN 2218-1989, 12/2018, Volume 8, Issue 4, p. 56
UHPLC-MS-based non-targeted metabolomics was used to investigate the biochemical basis of pecan scab resistance. Two contrasting pecan varieties, Kanza... 
Carya | Metabolomics | Flavonoids | Scab | Polyphenols | UHPLC-MS | MS/MS | Pecan | polyphenols | pecan | NUTS | scab | BIOCHEMISTRY & MOLECULAR BIOLOGY | DEATH | GAMMA-TOCOPHEROL | CORONARY HEART-DISEASE | metabolomics | PROSTATE-CANCER CELLS | flavonoids
Journal Article
Organic Letters, ISSN 1523-7060, 05/2015, Volume 17, Issue 10, pp. 2310 - 2313
Unexpectedly high rates of reaction between alkyllithium reagents and amides, compared to esters and ketones, were observed by Rapid Inject NMR and competition... 
PHENYLLITHIUM | THF | ION-PAIR | SPECTROSCOPY | ENOLATE | CHEMISTRY, ORGANIC | INTERMEDIATE | N-BUTYLLITHIUM | CHIRAL LITHIUM AMIDES | CARBOXYLIC-ACID DERIVATIVES | AGGREGATION
Journal Article
Chemical Science, ISSN 2041-6520, 2017, Volume 8, Issue 10, pp. 7152 - 7159
5-Acyl-5-phenyl-1,5-dihydro-4 -pyrazol-4-ones, accessible from arylpropargyl phenyldiazoacetates, are highly selective acyl transfer reagents for di- and... 
Journal Article
ACS catalysis, ISSN 2155-5435, 06/2019, Volume 9, Issue 6, pp. 4764 - 4776
LmbB2 is a peroxygenase-like enzyme that hydroxylates l-tyrosine to l-3,4-dihydroxyphenylalanine (DOPA) in the presence of hydrogen peroxide. However, its heme... 
heme chemistry | HYDROCARBONS | TYROSINE-HYDROXYLASE | CHEMISTRY, PHYSICAL | tyrosine hydroxylase | NUCLEOPHILIC AROMATIC-SUBSTITUTION | MEDICINAL CHEMISTRY | AXIAL LIGAND | GENE-CLUSTER | BIOSYNTHESIS | DEHALOPEROXIDASE | C-H/C-F bond cleavage | histidyl-ligated heme | DOPA | LINCOMYCIN | dehalogenation | C-F bond cleavage | C-H
Journal Article
Metabolomics, ISSN 1573-3882, 2018, Volume 14, Issue 5, p. 71
Oxygen from carbon dioxide, water or molecular oxygen, depending on the responsible enzyme, can lead to a large variety of metabolites through chemical... 
Journal Article
Langmuir, ISSN 0743-7463, 10/2007, Volume 23, Issue 22, pp. 11164 - 11167
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2018, Volume 140, Issue 12, pp. 4372 - 4379
Heme-based tryptophan dioxygenases are established immunosuppressive metalloproteins with significant biomedical interest. Here, we synthesized two mechanistic... 
OXIDATION | ACTIVATION | ENZYME | SPECTROSCOPY | KYNURENINE PATHWAY | REACTION-MECHANISM | BIOSYNTHESIS | INDOLEAMINE 2,3-DIOXYGENASE | SUPERFAMILY | N-FORMYLKYNURENINE | CHEMISTRY, MULTIDISCIPLINARY | Tryptophan | Chemical properties | Catalysis | Analysis | Amino compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 2017, Volume 139, Issue 29, pp. 9839 - 9842
The first cyclization reactions of enoldiazo compounds with nitrosoarenes have been developed. Under the catalysis of rhodium(II) octanoate, [3 +... 
NITROSOBENZENES | ISOXAZOLIDINES | CARBENE | CYCLOADDITION REACTIONS | ENANTIOSELECTIVE SYNTHESIS | NITRONES | ANNULATION | ENOL DIAZOACETATES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | Usage | Rhodium | Amides | Catalysis | Asymmetric induction (Stereochemistry) | Chemical properties | Ring formation (Chemistry) | Research
Journal Article
Analytical Chemistry, ISSN 0003-2700, 12/2016, Volume 88, Issue 23, pp. 11373 - 11383
Custom software entitled Plant Metabolite Annotation Toolbox (PlantMAT) has been developed to address the number one grand challenge in metabolomics, which is... 
GLYCOSIDES | CHEMISTRY, ANALYTICAL | SATIVA L. FLAVONOIDS | NATURAL-PRODUCTS | AERIAL PARTS | ROOTS | TRITERPENE SAPONINS | DIFFERENTIATION | TANDEM MASS-SPECTROMETRY | FRAGMENTATION | MEDIC MEDICAGO-TRUNCATULA | Metabolomics | Technology application | Chemistry, Analytic | Research
Journal Article
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