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ACS Catalysis, ISSN 2155-5435, 09/2014, Volume 4, Issue 9, pp. 3152 - 3159
This perspective article focuses its attention on the most recent advances in hydrodefluorination processes catalyzed by late transition metal complexes, a... 
Hydrodefluorination | Catalysis | Transition metal complexes | C-F activation | Fluorinated compounds
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2018, Volume 24, Issue 7, pp. 1732 - 1738
The hydride complex [Ru(IPr)2(CO)H][BArF4], 1, reacts with InMe3 with loss of CH4 to form [Ru(IPr)2(CO)(InMe)(Me)][BArF4], 4, featuring an unsupported Ru−In... 
indium | density functional calculations | heterometallic complexes | ruthenium | gallium | COORDINATION CHEMISTRY | N-HETEROCYCLIC CARBENE | AB-INITIO | H-2 ACTIVATION | TRANSITION-METALS | CHEMISTRY, MULTIDISCIPLINARY | PLATINUM COMPLEXES | ZETA VALENCE QUALITY | LEWIS-ACIDS | POLARIZATION FUNCTIONS | GAUSSIAN-BASIS SETS | Indium | Analysis | Ruthenium | Methane | Aromatic compounds
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 13, pp. 4518 - 4523
[Ru-3(CO)(12)] reacts at room temperature with N-alkyl substituted 6-membered ring N-heterocyclic carbenes (6-NHC) to form [Ru-3(6-NHC)(CO)(10)] (6-NHC =... 
GOLD(I) CATIONS | C-H BOND | CATALYTIC GLYCEROL DEHYDROGENATION | TRIOSMIUM CARBONYL CLUSTERS | RAY CRYSTAL-STRUCTURES | NEUTRON-DIFFRACTION | N-HETEROCYCLIC CARBENES | BIS(N-HETEROCYCLIC CARBENE) | POLYHYDRIDE CLUSTER | TRIRUTHENIUM CLUSTERS | CHEMISTRY, INORGANIC & NUCLEAR | Clusters | Ruthenium | Catalysis | Carbenes | Acylation
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 10/2019, Volume 48, Issue 37, pp. 14000 - 14009
The reaction of [Ru(PPh3)(3)Cl-2] with excess ZnMe2 led to P-C/C-H bond activation and P-C/C-C bond formation to generate a chelating diphenylphosphinobenzene... 
DEPROTONATION | ACTIVATION | TRANSITION-METAL | P-C | REACTIVITY | RICH BINUCLEAR HYDRIDE | C-13 NMR | RING CONTRIBUTIONS | ALKYLS | DOUBLE-BOND | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 01/2018, Volume 47, Issue 3, pp. 769 - 782
Bromide abstraction from the three-coordinate Ni(i) ring-expanded N-heterocyclic carbene complex [Ni(6-Mes)(PPh3)Br] (1; 6-Mes =... 
Density functional theory | Cations | Toluene | T shape | Sodium salts | Diamagnetism
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 02/2019, Volume 48, Issue 13, pp. 4176 - 4189
The ruthenium-zinc heterobimetallic complexes, [Ru(IPr)2(CO)ZnMe][BArF4] (7), [Ru(IBiox6)2(CO)(THF)ZnMe][BArF4] (12) and [Ru(IMes)'(PPh3)(CO)ZnMe] (15), have... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 2019, Volume 48, Issue 13, pp. 4176 - 4189
The ruthenium-zinc heterobimetallic complexes, [Ru(IPr)(2)(CO)ZnMe][BAr4F] (7), [Ru(IBiox6)(2)(CO)(THF)ZnMe][BAr4F] (12) and [Ru(IMes)(PPh3)(CO)ZnMe] (15),... 
H-H | HYDROGENATION | METAL-BORANE | RHODIUM(I) COMPLEXES | BOND-ACTIVATION REACTIONS | RICH BINUCLEAR HYDRIDE | LEWIS-ACIDS | LIGAND | H-2 | CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 3, pp. 745 - 752
The photophysical properties of four, two-coordinate, linear diamidocarbene copper(I) complexes, [(DAC)(2)Cu][BF4] (1), (DAC) CuOSiPh3 (2), (DAC) CuC6F5 (3)... 
LIGHT-EMITTING-DIODES | N-HETEROCYCLIC CARBENE | SOLAR-CELLS | QUANTUM YIELDS | INORGANIC EXCIPLEXES | PHOTOPHYSICAL PROPERTIES | MLCT EXCITED-STATES | CU(I) COMPLEXES | H ACTIVATION | SINGLET | CHEMISTRY, INORGANIC & NUCLEAR | Solid state | Oxygen | Synthesis | Emission | Ligands | Phosphorescence | Crystal structure | Quenching
Journal Article
ChemCatChem, ISSN 1867-3880, 04/2019, Volume 11, Issue 7, pp. 1893 - 1897
Studies on alkyne hydrophosphination employing nickel‐NHC catalysts (NHC=N‐heterocyclic carbene) revealed that the free N‐alkyl substituted NHCs themselves... 
N-heterocyclic carbene | reaction mechanisms | density functional calculations | homogeneous catalysis | hydrophosphination | ACTIVATION | CARBON | AMMONIA | CHEMISTRY, PHYSICAL | MAIN-GROUP ELEMENTS | ALKENES | PHOSPHINES | BONDS | LIGAND | C-H | Heterocyclic compounds | Catalysis
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2018, Volume 57, Issue 21, pp. 13749 - 13760
The major product of the reaction between Ru­(IMe4)2(PPh3)2H2 (1; IMe4 = 1,3,4,5-tetramethylimidazol-2-ylidene) and P­(C6F5)3 (PCF) is the five-coordinate... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2015, Volume 44, Issue 45, pp. 19597 - 19605
The room temperature reaction of C6F6 or C6F5H with [Ru(IEt2Me2)(2)(PPh3)(2)H-2] (1; IEt2Me2 = 1,3-diethyl-4,5- dimethylimidazol-2-ylidene) generated a mixture... 
FLUOROARENES | RHODIUM | NICKEL | BIFLUORIDE COMPLEXES | REACTIVITY | SOLUTION DYNAMICS | METAL | CARBENE COMPLEXES | HYDRODEFLUORINATION | FLUORIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 10/2014, Volume 33, Issue 20, pp. 5882 - 5887
The two-coordinate ring-expanded N-heterocyclic carbene copper(I) complexes [Cu(RE-NHC)(2)](+) (RE-NHC = 6-Mes, 7-o-Tol, 7-Mes) have been prepared and shown to... 
BACKBONE SYNTHESIS | PALLADIUM COMPLEXES | HYDROSILYLATION REACTIONS | STABLE CARBENES | REACTIVITY | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | BEARING | N-HETEROCYCLIC CARBENES | C-H ACTIVATION | 3+2 CYCLOADDITION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2018, Volume 57, Issue 21, pp. 13749 - 13760
The major product of the reaction between Ru(IMe ) (PPh ) H (1; IMe = 1,3,4,5-tetramethylimidazol-2-ylidene) and P(C F ) (PCF) is the five-coordinate complex... 
Journal Article
ISSN 1477-9226, 3/2019, Volume 48, Issue 13, pp. 4176 - 4189
The ruthenium-zinc heterobimetallic complexes, [Ru(IPr) 2 (CO)ZnMe][BAr F 4 ] ( 7 ), [Ru(IBiox6) 2 (CO)(THF)ZnMe][BAr F 4 ] ( 12 ) and [Ru(IMes)′(PPh 3... 
Journal Article
ISSN 1477-9226, 3/2018, Volume 47, Issue 13, pp. 4518 - 4523
[Ru 3 (CO) 12 ] reacts at room temperature with N -alkyl substituted 6-membered ring N-heterocyclic carbenes (6-NHC) to form [Ru 3 (6-NHC)(CO) 10 ] (6-NHC = 6-... 
Journal Article
Polyhedron, ISSN 0277-5387, 01/2016, Volume 103, pp. 121 - 125
The activity of ring-expanded N-heterocyclic carbene complexes of zinc for the ring-opening polymerisation of -lactide has been probed alongside that of the... 
Polymerisation | Crystal structures | Zinc complexes | Polylactide | N-heterocyclic carbenes | STEREOSELECTIVE POLYMERIZATION | ALKOXIDES | ZIRCONIUM COMPLEXES | CRYSTALLOGRAPHY | RAC-LACTIDE | TITANIUM | OPENING POLYMERIZATION | CHEMISTRY, INORGANIC & NUCLEAR | MAGNESIUM | LIGANDS | INITIATORS
Journal Article
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