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Journal of Organic Chemistry, ISSN 0022-3263, 06/2019, Volume 84, Issue 12, pp. 7564 - 7574
A cobalt-catalyzed intramolecular silylperoxidation reaction was developed that allows for the conversion of unsaturated diisopropylsilyl ethers to... 
ALCOHOLS | ALKENES | RING-CLOSING METATHESIS | PEROXIDES | COMPLEXES | ALLYLATION | HYDROPEROXYSILYLATION | CHEMISTRY, ORGANIC | OLEFINS | DERIVATIVES | MOLECULAR-OXYGEN
Journal Article
Organic Letters, ISSN 1523-7060, 06/2015, Volume 17, Issue 11, pp. 2704 - 2707
The copper(I)-catalyzed oxidation of alkenes with molecular oxygen and N-hydroxyphthalimide (NHPI) or N-hydroxybenzotriazole (HOBt) provided alpha-oxygenated... 
ACTIVATION | AEROBIC DIOXYGENATION | HYDROXAMIC ACIDS | CATALYZED OXIDATION | HOMOLYTIC DECOMPOSITIONS | CHEMISTRY | CHEMISTRY, ORGANIC | N-HYDROXYPHTHALIMIDE | HYDROPEROXIDES | DIKETONES | METAL-FREE
Journal Article
ISSN 1477-9226, 7/2017, Volume 46, Issue 27, pp. 8763 - 8768
Silylenes are useful reactive intermediates for the stereoselective construction of compounds containing carbon-silicon bonds. Despite their synthetic utility,... 
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2018, Volume 83, Issue 17, pp. 10197 - 10206
Allylic Grignard reagents exhibit high reactivity and low selectivity in additions to carbonyl compounds. Additions of allylic Grignard reagents to carbonyl... 
MAGNESIUM | ELECTRON-TRANSFER | SILYL ENOL ETHERS | REACTIVITY | CHEMISTRY, ORGANIC | IRREVERSIBLE ADDITIONS | REVERSIBLE GRIGNARD | BROMIDE | ALLYLMAGNESIUM HALIDES | ALKOXY KETONES | DERIVATIVES
Journal Article
Chemical reviews, ISSN 0009-2665, 01/2020
This review describes the additions of allylmagnesium reagents to carbonyl compounds and to imines, focusing on the differences in reactivity between... 
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 08/2018, Volume 83, Issue 16, pp. 9067 - 9075
The dearomatization of aromatic compounds using cobalt­(II) acetylacetonate with triplet oxygen and triethylsilane converts furans, benzofurans, pyrroles, and... 
KETONES | ALKENES | TETRAHYDROBORATE | CHEMISTRY, ORGANIC | OLEFINS | PEROXIDATION | HYDROPEROXIDES | TRIETHYLSILANE | INTRAMOLECULAR REACTIONS | MOLECULAR-OXYGEN | CO(II)/O-2/ET3SIH
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2017, Volume 139, Issue 25, pp. 8404 - 8407
Seven-membered-ring trans-alkenes undergo rapid, uncatalyzed carboboration reactions to form trialkylboranes as single diastereomers. In contrast with other... 
HYDROBORATION | REACTIVITY | SIGMA-BONDS | RADICALS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ORGANOBORANES | AB-INITIO INVESTIGATIONS | Alkenes - chemistry | Molecular Structure | Air | Catalysis | Alkylation | Boranes - chemistry | Usage | Hydroboration | Chemical properties | Diastereomers | Olefins | Silane
Journal Article
Synlett, ISSN 0936-5214, 11/2017, Volume 28, Issue 18, pp. 2478 - 2482
Abstract Seven-membered-ring trans -alkenes containing a silicon–oxygen bond reacted rapidly with oxygen gas and electron-deficient alkenes and alkynes to give... 
cluster | silicon | strained molecules | alkenes | conjugate addition | cycloheptene | CHEMISTRY, ORGANIC | CYCLIC OLEFINS | AZIRIDINIUM IMIDE | CYCLOOCTENE | BIOCONJUGATION | RELATIVE REACTIVITY | DOUBLE-BONDS | CHEMICAL-REACTIVITY | INTERMEDIATE | STRAINED ALKENES
Journal Article
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1434-193X, 04/2016, Issue 10, pp. 1860 - 1866
A Cu-I-catalyzed oxidation of enynes using N-hydroxybenzotriazole (HOBt) or N-hydroxyphthalimide (NHPI) with molecular oxygen has been developed to yield... 
ALKENES | BOND-DISSOCIATION ENERGIES | CARBON | AEROBIC DIOXYGENATION | HYDROXAMIC ACIDS | HOMOLYTIC DECOMPOSITIONS | CHEMISTRY, ORGANIC | Enynes | Peroxides | Oxidation | RADICALS | METAL-FREE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2015, Volume 54, Issue 14, pp. 4295 - 4298
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 27, pp. 8763 - 8768
Silylenes are useful reactive intermediates for the stereoselective construction of compounds containing carbon-silicon bonds. Despite their synthetic utility,... 
ALLYLIC SILANES | ALCOHOLS | ETHERS | MECHANISM | SILACYCLOPROPANES | COMPLEXES | SILVER | COPPER | TERT-BUTYLSILYLENE TRANSFER | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 2, pp. 790 - 793
trans‐Oxasilacycloheptenes are highly reactive strained alkenes. Competition reactions showed that these seven‐membered ring trans‐alkenes underwent [4+2]... 
cycloaddition | silicon | strained molecules | cycloheptenes | alkenes | LIGATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLOOCTENE | BIOCONJUGATION | OLEFINS | AROMATIC ESTERS | ELECTROPHILES | CYCLOHEPTENE | Quinone | Olefins | Dimethyl | Competition | Quinones | Cycloaddition | Alkenes | Adducts
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2019, Volume 75, Issue 31, pp. 4118 - 4129
Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in... 
Diastereoselective | Catalysis | Peroxide | Radical | Cobalt | STABILIZATION | COBALT(II) | CHEMISTRY, ORGANIC | IONS | CATALYST | ANTIMALARIAL | ALKENES | PHENYLSILANE | REDUCTION | CARBON-CENTERED RADICALS | MOLECULAR-OXYGEN | Lactones
Journal Article
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 13, pp. 3346 - 3349
The chelation-control model explains the high diastereoselectivity obtained in additions of organometallic nucleophiles to α-alkoxy ketones but fails for... 
DIETHYL-ETHER | REAGENTS | NUCLEOPHILIC ADDITIONS | SPECTROSCOPY | CONTROLLED CARBONYL ADDITION | REACTIVITY | CHEMISTRY, ORGANIC | ALDEHYDES | LEUSTRODUCSIN-B | TETRAHYDROFURAN | GRIGNARD COMPOUNDS
Journal Article
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