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Chemical science, ISSN 2041-6520, 04/2019, Volume 10, Issue 16, pp. 4394 - 4401
Through relatively subtle changes in reaction conditions, we have been able to isolate four distinct Rh/Sn cluster compounds, [Rh@Sn ] , [Rh@Sn ] , [Rh @Sn ]... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2016, Volume 138, Issue 1, pp. 369 - 374
Herein we describe the first enantioselective Rh-catalyzed carboacylation of oximes (imines) via C–C activation. In this transformation, the benzocyclobutenone... 
FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | RHODIUM | REAGENTS | OLEFIN INSERTION | COMPLEXES | CHEMISTRY | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | CYCLOBUTENONES | ALKALOIDS
Journal Article
Organic Letters, ISSN 1523-7060, 04/2018, Volume 20, Issue 8, pp. 2160 - 2163
Rh­(III)-catalyzed cascade C–H activation of benzoylacetonitriles and annulation with sulfoxonium ylides was realized, leading to selective synthesis of... 
DIRECTING GROUPS | SULFOXONIUM YLIDES | CHEMISTRY, ORGANIC | MANSONONE-F | DIAZO-COMPOUNDS | BOND-CLEAVAGE | N-OXIDES | CASCADE OXIDATIVE ANNULATION | ACCESS | CYCLIZATION | CARBENOID FUNCTIONALIZATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 6, pp. 2200 - 2203
A range of Rh­(III)-catalyzed ortho-C–H functionalizations have been developed; however, extension of this reactivity to remote C–H functionalizations through... 
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ROOM-TEMPERATURE | PHENOLS | ALKYLATION | ARYLATION | ARENES | BOND ACTIVATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Usage | Rhodium | Analysis | Chemical bonds | Ligands | Catalysis | Chemical properties
Journal Article
Fuel, ISSN 0016-2361, 12/2018, Volume 234, pp. 1165 - 1172
Theoretical rate constants and parameters of RH + O2 = R + HO2 (RH = C1–C14 normal alkanes) have been obtained at UM06-2X/cc-pvdz level with canonical... 
Fuel combustion | First-principle | Long alkane | Kinetics
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 6, pp. 1111 - 1115
A Rh‐catalyzed unique and direct approach for constructing a series of 5‐arylimidazo[1,2‐c]quinazolines in moderate to excellent yields from simple and readily... 
amidation | Rhodium catalysis | dioxazolones | annulation | quinazolines | ACTIVATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | COBALT(III) | FUNCTIONALIZATION | AMINATION | HETEROCYCLES | DIOXAZOLES | CHEMISTRY, APPLIED | DERIVATIVES | Catalysis | Hydrogen bonds | Organic chemistry | Chemical reactions
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2012, Volume 77, Issue 7, pp. 3017 - 3024
The Rh­(III)-catalyzed C–H functionalizations of benzamide derivatives with olefin were studied by DFT calculations to elucidate the divergent pathways... 
DENSITY FUNCTIONALS | MOLECULAR CALCULATIONS | RHODIUM | EFFECTIVE CORE POTENTIALS | CHEMISTRY, ORGANIC | BOND FORMATION | ARYL | ISOQUINOLONE SYNTHESIS | REDUCTIVE ELIMINATION | PROTON-ABSTRACTION MECHANISM | CATALYZED DIRECT ARYLATION | Usage | Rhodium | Olefins | Analysis | Chemical bonds | Density functionals | Amides | Chemical properties | Elimination reactions
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2019, Volume 361, Issue 14, pp. 3318 - 3323
A novel aldehydic C−H functionalization reaction between salicylaldehydes and sulfoxonium ylides has been developed under rhodium(III) catalysis, affording... 
sulfoxonium ylides | aldehydic C−H activation | carbene insertion | rhodium(III) catalyzed | salicylaldehydes | ACYLMETHYLATION | ALKENE | ACTIVATION | CATALYZED ANNULATION | CHEMISTRY, ORGANIC | METAL CARBENE | CHROMONES | BONDS | CHEMISTRY, APPLIED | aldehydic C-H activation | HYDROACYLATION | CYCLIZATION | Flavonoids | Catalysis | Flavones | Bioflavonoids | Rhodium | Dehydration
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2013, Volume 19, Issue 1, pp. 358 - 364
The mechanism of the [(Cp*MCl2)2] (M=Rh, Ir)‐catalyzed oxidative annulation reaction of isoquinolones with alkynes was investigated in detail. In the first... 
iridium | reaction mechanisms | CH activation | oxidative annulation | rhodium | C-H activation | COUPLING/CYCLIZATION | COMPLEXES | CARBON-HYDROGEN BONDS | INTERNAL ALKYNES | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED ARYLATION | N BOND FORMATION | Mineralogy
Journal Article
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 22, pp. 6040 - 6043
The asymmetric total synthesis of clovan-2,9-dione with a [6.3.1.01,5]­dodecane skeleton has been achieved. The synthesis features a Rh­(I)-catalyzed [3 + 2 +... 
REARRANGEMENT | BIOTRANSFORMATION | FORMAL SYNTHESIS | STEREOSPECIFIC SYNTHESES | STEREOCHEMISTRY | CARYOPHYLLENE OXIDE | CHEMISTRY, ORGANIC | CLOVANE | DERIVATIVES | SESQUITERPENOIDS
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 10/2019, Volume 17, Issue 38, pp. 8706 - 8710
In this paper, a novel and sustainable synthesis of the hitherto unreported 5H-benzo[c]imidazo[1,2-a]azepine-6-carboxylic acids via the cascade reactions of... 
ACTIVATION | ACIDS | H BOND FUNCTIONALIZATIONS | CHEMISTRY, ORGANIC | 2-ARYLINDOLES | DIVERSITY | ACCESS
Journal Article
Organic Letters, ISSN 1523-7060, 08/2010, Volume 12, Issue 16, pp. 3708 - 3711
An enantioselective formal synthesis of (−)-englerin A (1) is reported. Key to the strategy is a Rh-catalyzed [4 + 3] cycloaddition reaction between furan 10... 
CHEMISTRY, ORGANIC | STATISTICS
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2015, Volume 51, Issue 27, pp. 5868 - 5871
Here we report a new and mild Rh(III)-catalyzed and alcohol-involved carbenoid C-H insertion into N-phenoxyacetamides using alpha-diazomalonates. This reaction... 
OXIDIZING DIRECTING GROUP | FACILE SYNTHESIS | RHODIUM(III)-CATALYZED ORTHO-ALKENYLATION | METAL CARBENE | INTERNAL OXIDANT | EFFICIENT SYNTHESIS | BOND FORMATION | DIAZO-COMPOUNDS | INDOLE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | DIAZOCARBONYL COMPOUNDS | Phenyls | Insertion | Tolerances | Carbon | Substrates | Functional groups | Rings (mathematics)
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 04/2015, Volume 51, Issue 27, pp. 5868 - 5871
Here we report a new and mild Rh(III)-catalyzed and alcohol-involved carbenoid C-H insertion into N-phenoxyacetamides using α-diazomalonates. This reaction... 
Azo Compounds - chemistry | Malonates - chemistry | Stereoisomerism | Phenoxyacetates - chemistry | Molecular Structure | Catalysis | Methanol - chemistry | Carbon - chemistry | Rhodium - chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 10/2017, Volume 19, Issue 19, pp. 5256 - 5259
Sulfoxonium ylides act as an efficient carbene precursor in rhodium­(III)-catalyzed C–H acylmethlyation of a variety of arenes assisted by different chelating... 
ACTIVATION | ARYL BORONIC ACIDS | HETEROCYCLES | MIGRATORY INSERTION | CATALYZED REACTIONS | ALKYLATION | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | DIAZO-COMPOUNDS | INDOLES | N-TOSYLHYDRAZONES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2019, Volume 141, Issue 1, pp. 76 - 79
Rh(III)-catalyzed meta-C-H functionalization reactions are still rare. Herein, we report the first example of Rh(III)-catalyzed meta-C-H alkenylation with... 
DIRECTING GROUP | CATALYSIS | ACTIVATION | OLEFINATION | ALKYLATION | ARYLATION | ARENES | BOND FUNCTIONALIZATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION
Journal Article
Applied Catalysis A: General, ISSN 0926-860X, 05/2006, Volume 305, Issue 2, pp. 204 - 210
The interaction between Rh and CeO over the Rh-CeO /Al O catalyst was investigated for the reaction of methane reforming with CO . It was shown that the... 
Redox couples | Rh-CeO | reforming | CO | catalyst
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2013, Volume 135, Issue 25, pp. 9271 - 9274
Journal Article