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Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 38, pp. 11649 - 11652
A decarboxylative silylation of aliphatic N ‐hydroxyphthalimide (NHPI) esters using Si−B reagents as silicon pronucleophiles is reported. This C(sp 3 )−Si... 
cross-coupling | radical reactions | copper | decarboxylation | silicon | ACTIVATION | VISIBLE-LIGHT PHOTOCATALYSIS | NUCLEOPHILIC-SUBSTITUTION | BOND FORMATION | QUATERNARY CARBONS | SILICON NUCLEOPHILES | CHEMISTRY, MULTIDISCIPLINARY | NICKEL | ESTERS | ALKYL ELECTROPHILES | BORYLATION | Copper | Esters | Couplings | Cross coupling | Amines | Reagents | Amino acids | Silicon | Carboxylic acids | Substrates | Aliphatic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 36, pp. 11562 - 11565
A mild Ni-catalyzed reductive arylation of tertiary alkyl halides with aryl bromides has been developed that delivers products bearing all-carbon quaternary... 
CONCISE TOTAL-SYNTHESIS | ALPHA-ARYLATION | KETONE FORMATION | ALLYLATION | UNACTIVATED PRIMARY | SECONDARY | ORGANIC HALIDES | CARBOXYLATION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | TOSYLATES | Arylation | Usage | Chemical properties | Metal catalysts | Halides | Isomerization
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 37, pp. 12141 - 12145
A robust method for the preparation of silicon‐based magnesium reagents is reported. The MgBr 2 used in the lithium‐to‐magnesium transmetalation step is... 
cross-coupling | radical reactions | magnesium | silicon | synthetic methods | HALIDES | SUBSTITUTION | MECHANISM | COPPER | SILYLMETALATION | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | SILYLBORONATE | ALKYL ELECTROPHILES | BOND ACTIVATION | METAL | Silicon | Precipitation (Meteorology) | Chemical tests and reagents | Stocks | Cobalt | Borides | Reagents | Bromides | Chemical reactions | Lithium | Iron | High temperature | Magnesium | Coupling | Magnesium compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 43, pp. 14222 - 14225
A copper-catalyzed C(sp(3))-Si cross-coupling of aliphatic C(sp(3))-I electrophiles using a Si-B reagent as the silicon pronucleophile is reported. The... 
HALIDES | AUXILIARY BASIS-SETS | ROUTE | B BOND ACTIVATION | SILANES | ZETA VALENCE QUALITY | SECONDARY | ALLYLIC SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | BORYLATION | Usage | Analysis | Chemical bonds | Silicon | Chemical properties | Ring formation (Chemistry) | Research | Electrophiles
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2019, Volume 58, Issue 31, pp. 10723 - 10726
A new application of silicon Grignard reagents in C(sp 3 )−Si bond formation is reported. With the aid of BF 3 ⋅OEt 2 , these silicon nucleophiles add across... 
copper | magnesium | conjugate additions | silicon | asymmetric catalysis | MECHANISM | ALPHA,BETA-UNSATURATED ACCEPTORS | CONJUGATE SILYL TRANSFER | SI BOND FORMATION | 1,4-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | Silicon | Catalysis | Chemical tests and reagents | Enantiomers | Copper | Olefins | Alkenes | Reagents | Nucleophiles | Bonding | Substrates
Journal Article
Synthesis, ISSN 0039-7881, 01/2019, Volume 51, Issue 1, pp. 233 - 239
Abstract A broad range of transition-metal catalysts is shown to promote allylic substitution reactions of allylic electrophiles with silicon Grignard... 
feature | copper | Grignard reagents | silicon | allylic substitution | COMPLEXES | ALLYLATION | CHEMISTRY, ORGANIC | STEREOSPECIFIC SYNTHESIS | ALLYLSILANES | SILYLATION | ZINC | CHLOROSILANES | SILANES
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 38, pp. 11808 - 11811
Es wird über eine decarboxylierende Silylierung von aliphatischen Estern des N‐Hydroxyphthalimids (NHPI) mit Si‐B‐Reagenzien als Siliciumpronukleophile... 
Silicium | Kreuzkupplungen | Radikalreaktionen | Kupfer | Decarboxylierungen
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 38, p. 11808
Es wird uber eine decarboxylierende Silylierung von aliphatischen Estern des N-Hydroxyphthalimids (NHPI) mit Si-B-Reagenzien als Siliciumpronukleophile... 
Silicon
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 19, pp. 6440 - 6443
Robust procedures for two mechanistically distinct C(sp 3 )−Ge bond formations from alkyl electrophiles and germanium nucleophiles are reported. The germanium... 
magnesium | germanium | radical cross-coupling | nucleophilic substitution | zinc | HALIDES | SILICON | STANNYL | SUBSTITUTION-REACTIONS | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | GERMYL ANIONOIDS | CHEMISTRY | GROUP IV | ACCESS | Chemical tests and reagents | Olefins | Regioselectivity | Reagents | Bromides | Lithium | Germanium | Nickel | Magnesium | Coupling | Nucleophiles | Zinc
Journal Article
Journal of Dynamics and Differential Equations, ISSN 1040-7294, 07/2019
Journal Article
Ecological Indicators, ISSN 1470-160X, 01/2020, Volume 108, p. 105714
We established vegetation indicators of active layer thickness for the southern permafrost region in China, which can be used for monitoring permafrost... 
Community structure | Logistic regression | Active layer thickness | Indicator plant species | Permafrost degradation
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 10/2015, Volume 2, Issue 10, pp. 1411 - 1421
The formation of C-C bonds directly by catalytic reductive cross-coupling of two different electrophiles represents one of the practical synthetic protocols... 
CROSS-COUPLINGS | UNACTIVATED TERTIARY ALKYL | ARYL HALIDES | KETONE FORMATION | SECONDARY | CHEMISTRY, ORGANIC | ORGANIC HALIDES | CARBOXYLATION | BROMIDES | GRIGNARD-REAGENTS | TOSYLATES
Journal Article
Angewandte Chemie, ISSN 0044-8249, 07/2019, Volume 131, Issue 31, pp. 10833 - 10836
Es wird über eine neue Anwendung von Silicum‐Grignard‐Reagenzien in der C(sp 3 )‐Si‐Bindungsknüpfung berichtet. Mit Unterstützung von BF 3 ⋅OEt 2 addieren... 
Silicium | Konjugierte Additionen | Asymmetrische Katalyse | Magnesium | Kupfer | Olefins | Silicon
Journal Article
Angewandte Chemie, ISSN 0044-8249, 05/2019, Volume 131, Issue 19, pp. 6506 - 6509
Es wird uber robuste Reaktionsvorschriften zweier mechanistisch ungleicher C(sp.sup.3)-Ge-Bindungsknupfungen ausgehend von Alkylelektrophilen und... 
Lithium | Germanium | Magnesium
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2019, Volume 9, Issue 1, pp. 16 - 24
The combination of electrophilic and nucleophilic reaction partners can be an obvious approach toward the formation of C(sp(3))-Si bonds. Regioselectivity... 
cross-coupling | radical reactions | silicon | homogeneous catalysis | synthetic methods | VERSATILE METHOD | B BOND ACTIVATION | PALLADIUM-CATALYZED SILYLATION | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, PHYSICAL | SILICON NUCLEOPHILES | ARYL HALIDES | CONVENIENT PREPARATION | RADICAL CYCLIZATION | ORGANIC HALIDES | ELECTROPHILES
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2018, Volume 130, Issue 37, pp. 12318 - 12322
Es wird über eine widerstandsfähige Reaktionsvorschrift zur Herstellung von siliciumbasierten Magnesiumreagenzien berichtet. Das im... 
Silicium | Synthesemethoden | Kreuzkupplungen | Magnesium | Radikalreaktionen | Lithium | Borides | Silicon | Magnesium compounds
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2018, Volume 130, Issue 37, pp. 12318 - 12322
Es wird uber eine widerstandsfahige Reaktionsvorschrift zur Herstellung von siliciumbasierten Magnesiumreagenzien berichtet. Das im... 
Journal Article