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rhodium (7) 7
alkynes (4) 4
aldehydes (3) 3
alkine (3) 3
allene (3) 3
catalysis (3) 3
isomerization (3) 3
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anions (2) 2
c-c-aktivierung (2) 2
copper (2) 2
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c−c activation (2) 2
dioxane (2) 2
functional groups (2) 2
migration (2) 2
palladium (2) 2
substrates (2) 2
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ISSN 1359-7345, 6/2018, Volume 54, Issue 5, pp. 6776 - 6779
.... Commun., 2018, 54, 6776 as latent a-alkoxyalkyl anion equivalents† Fig. 1 Csp 3 –Csp 2 cross-coupling reactions. Mitsutaka Takeda, Kenya Yabushita, Shigeo Yasuda... 
Journal Article
Angewandte Chemie, ISSN 0044-8249, 04/2018, Volume 130, Issue 17, pp. 4896 - 4896
Die Kombination eines Allenins …… mit einer zusätzlichen π‐Komponente in Gegenwart eines Rhodium(I)‐Katalysators ermöglicht einen neuartigen Ringschluss. In... 
C-C-Aktivierung | Allene | Rhodium | Cycloisomerisierungen | Alkine
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2018, Volume 54, Issue 50, pp. 6776 - 6779
The first Csp3–Csp2 cross-coupling using aldehydes as latent α-alkoxyalkyl anion equivalents has been achieved. The synergistic palladium/copper-catalyzed... 
Couplings | Cross coupling | Anions | Equivalence | Aromatic compounds | Bromides | Palladium | Catalysis | Copper | Aldehydes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 04/2018, Volume 57, Issue 17, pp. 4707 - 4711
Upon exposure to a catalytic amount of [RhCl(CO)2]2 in 1,4‐dioxane, homopropargylallene‐alkynes underwent a novel cycloisomerization accompanied by the... 
allenes | C−C activation | cycloisomerization | alkynes | rhodium | Rhodium | Migration | Isomerization | Catalysis | Substrates | Functional groups | Alkynes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2019, Volume 141, Issue 1, pp. 113 - 117
We have developed a new umpolung strategy for catalytically forming a chiral α-alkoxyalkyl anion from an aromatic aldehyde for use in asymmetric synthesis. The... 
Index Medicus
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 06/2018, Volume 54, Issue 50, pp. 6776 - 6779
The first Csp3-Csp2 cross-coupling using aldehydes as latent a-alkoxyalkyl anion equivalents has been achieved. The synergistic palladium/ copper-catalyzed... 
Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 9/2020, Volume 93, Issue 9, pp. 1065 - 1069
The KHMDS-catalyzed tertiary alkylation of aldehydes, ketones or imines using tertiary benzylic organoboronates is reported. This protocol permitted the use of... 
Transition metals | Ketones | Imines | Aldehydes | Alkylation
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 04/2018, Volume 57, Issue 17, p. 4707
Upon exposure to a catalytic amount of [RhCl(CO).sub.2].sub.2 in 1,4-dioxane, homopropargylallene-alkynes underwent a novel cycloisomerization accompanied by... 
Dioxane | Rhodium
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 04/2018, Volume 57, Issue 17, pp. 4804 - 4804
The combination of an allenyne with an additional π‐component in the presence of a rhodium(I) catalyst constitutes a new approach for ring closure. In their... 
allenes | C−C activation | cycloisomerization | alkynes | rhodium
Journal Article
Angewandte Chemie, ISSN 0044-8249, 04/2018, Volume 130, Issue 17, pp. 4797 - 4801
Upon exposure to a catalytic amount of [RhCl(CO)2]2 in 1,4‐dioxane, homopropargylallene‐alkynes underwent a novel cycloisomerization accompanied by the... 
C-C-Aktivierung | Allene | Rhodium | Cycloisomerisierungen | Alkine | Migration | Isomerization | Catalysis | Functional groups | Substrates | Alkynes
Journal Article
Angewandte Chemie, ISSN 0044-8249, 04/2018, Volume 130, Issue 17, p. 4797
Upon exposure to a catalytic amount of [RhCl(CO).sub.2].sub.2 in 1,4-dioxane, homopropargylallene-alkynes underwent a novel cycloisomerization accompanied by... 
Dioxane | Rhodium
Journal Article
Angewandte Chemie, ISSN 0044-8249, 04/2018, Volume 130, Issue 17, pp. 4896 - 4896
Die Kombination eines Allenins …… mit einer zusätzlichen π‐Komponente in Gegenwart eines Rhodium(I)‐Katalysators ermöglicht einen neuartigen Ringschluss. In... 
Rhodium | Isomerization | Alkynes
Journal Article
Chemical communications (Cambridge, England), ISSN 1364-548X, 2018, Volume 54, Issue 50, pp. 6776 - 6779
The first Csp 3 –Csp 2 cross-coupling using aldehydes as latent α-alkoxyalkyl anion equivalents has been achieved. The first Csp 3 –Csp 2 cross-coupling using... 
Journal Article
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