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Chemical Communications, ISSN 1359-7345, 04/2014, Volume 50, Issue 33, pp. 4344 - 4346
Synthesis of guanidine-linked NHC can be achieved easily through reacting amino-NHC with carbodiimide. Subsequently, guanidine-NHC Ag and Cu complexes were... 
SILVER(I) | BEARING | N-HETEROCYCLIC CARBENES | CATALYZED BORYLATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | GOLD(I) | Synthesis (chemistry) | Hydroboration | Synthesis | Catalysts | Guanidines | Catalysis | Carbodiimides | Alkynes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2018, Volume 140, Issue 23, pp. 7088 - 7091
Bis­(arylimido)­Cr­(VI) dialkyls lacking β-hydrogen decompose by α-hydrogen abstraction and, upon trapping with triphenylphosphine, yield isolable alkylidene... 
NOBEL LECTURE | MOLYBDENUM | TUNGSTEN ALKYLIDENE | COMPLEXES | CRYSTAL-STRUCTURES | OLEFIN-METATHESIS | LIGAND | C-H ACTIVATION | ETHYLENE POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-CARBON BONDS
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 07/2019, Volume 141, Issue 30, pp. 12128 - 12138
Porous molecular solids are promising materials for gas storage and gas separation applications. However, given the relative dearth of structural information... 
HYDROGEN | MOLECULAR-DYNAMICS | ISOPHTHALATE LINKERS | METAL-ORGANIC FRAMEWORKS | POLYHEDRAL FRAMEWORKS | CRYSTAL-STRUCTURE | METHANE STORAGE | FORCE-FIELD | ADSORPTION | CHEMISTRY, MULTIDISCIPLINARY | POWDER-DIFFRACTION
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2014, Volume 50, Issue 20, pp. 2579 - 2581
The quintuply bonded [(LCr)-L-H-Cr-iPr](2) reacts with various small molecules, revealing a pattern of two kinds of transformations. Unsaturated molecules that... 
METAL-METAL DISTANCES | CRYSTAL-STRUCTURE | COMPLEXES | BRIDGES | REACTIVITY | IMIDO | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | 3-COORDINATE | ELECTRONIC-STRUCTURE | Binding | Chromium | Cleavage | Activation | Dimers | Transformations | Oxidation | Bonding
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2013, Volume 42, Issue 25, pp. 9198 - 9210
The chromium(I) dinitrogen complex [(i-Pr2Ph)2nacnacCr]2(μ-η(2):η(2)-N2) catalyzes the selective trimerization of ethylene to 1-hexene at ambient pressure and... 
Organometallic Compounds - chemical synthesis | Models, Molecular | Polymerization | Organometallic Compounds - chemistry | Molecular Structure | Chromium - chemistry | Ethylenes - chemistry | Catalysts | Ethylene | Cleaning | Catalysis | Proposals | Catalytic converters | Conversion | Pressure | Oligomerization
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 08/2019, Volume 55, Issue 64, pp. 9527 - 9530
To leverage the structural diversity of metal-organic frameworks, the ability to controllably terminate them for the isolation of porous coordination cages is... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 02/2015, Volume 44, Issue 5, pp. 2340 - 2347
Despite their versatility, only a few single-crystal X-ray structures of lead carboxylates exist, due to difficulties with solubility. In particular, the... 
PB-207 NMR | PB(II) LONE-PAIR | LIQUID-CRYSTALLINE | NUCLEAR-MAGNETIC-RESONANCE | MAGIC-ANGLE | X-RAY | N-ALKANOATES | OIL PAINTINGS | METAL SOAPS | CHEMICAL-SHIFT TENSORS | CHEMISTRY, INORGANIC & NUCLEAR | Single crystals | Diffraction | X-rays | Consistency | Nuclear magnetic resonance | Subgroups | Carboxylates | Dichotomies
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2019, Volume 58, Issue 3, pp. 1728 - 1732
Novel mixed-ligand rhodium(II) paddle-wheel complexes incorporating tethered axial thioether ligands have been synthesized and characterized. The thioether... 
CARBENE | DECOMPOSITIONS | DONOR/ACCEPTOR | CRYSTAL-STRUCTURE | KINETICS | CHEMISTRY | BOND | STRUCTURAL DIVERSITY | TETRA(TRIFLUOROACETATE) | SOLID-STATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 17, pp. 5406 - 5409
A one-pot protocol for the assembly of diversely functionalized tetrahydro-, hexahydrofuro-, hexahydropyrano-, and tetrahydrobenzofuroquinolines from... 
CATALYZED ASYMMETRIC HYDROGENATION | HIGHLY ENANTIOSELECTIVE HYDROGENATION | LEWIS-ACID | DIELS-ALDER REACTION | CHEMISTRY, ORGANIC | QUINOLINE DERIVATIVES | CYCLOPENTADIENE | HYDROAMINATION/ASYMMETRIC TRANSFER HYDROGENATION | HETEROAROMATIC-COMPOUNDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2018, Volume 140, Issue 32, pp. 10169 - 10178
The metal-to-ligand charge transfer excited states of [Ru­(bpy)3]2+ (bpy = 2,2′-bipyridine) may be deactivated via energy transfer or electron transfer with... 
Thermodynamics | Electron Transport | Organometallic Compounds - chemistry | Metallocenes - chemistry | Kinetics | Spectrum Analysis | Hydrogen-Ion Concentration
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 04/2019, Volume 58, Issue 8, pp. 5134 - 5144
Mononuclear Mo and W enzymes require a unique ligand known as molybdopterin (MPT). This ligand binds the metal through a dithiolene chelate, and the dithiolene... 
CHEMISTRY | COMPLEX | PYRANOPTERIN | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ChemBioChem, ISSN 1439-4227, 04/2019, Volume 20, Issue 7, pp. 963 - 967
The preferred conformations of peptides and proteins are dependent on local interactions that bias the conformational ensemble. The n→π* interaction between... 
conformation analysis | peptides | stereoelectronic effects | hyperconjugation | amino acids | Carbonyl compounds | Capping | Peptides | Chlorine | Enthalpy | Crystallography | Hydrogen bonding | Magnetic resonance spectroscopy | Proteins | Organic chemistry | Hydrogen bonds | Computer applications | Polyproline | NMR spectroscopy | Bonding | Hydrogen ion concentration | Carbonyls | Conformation | Electrons
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2009, Volume 131, Issue 21, pp. 7230 - 7231
Herein, we provide crystallographic and computational evidence that Hashimoto’s Rh2(S-PTTL)4 catalyst adopts a “chiral crown” conformation with a reactive... 
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 04/2019, Volume 58, Issue 8, pp. 5042 - 5050
Journal Article
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