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1. Full Text Recent Progress in Coupling of Two Heteroarenes
by Zhao, Dongbing and You, Jingsong and Hu, Changwei
Chemistry – A European Journal, ISSN 0947-6539, 05/2011, Volume 17, Issue 20, pp. 5466 - 5492
The biheteroaryl structural motif is prevalent in polymers, advanced materials, liquid crystals, ligands, molecules of medicinal interest, and natural... 
arenes | cross‐coupling | heteroaryls | heterocycles | cross-coupling | HETEROAROMATIC CARBOXYLIC-ACIDS | ROOM-TEMPERATURE | AZINYLPYRIDINIUM N-AMINIDES | PD-PEPPSI-IPENT | UNACTIVATED ARENES | CHEMISTRY, MULTIDISCIPLINARY | C-H ARYLATION | ARYL BOND FORMATION | ELECTRON-RICH HETEROCYCLES | THIOPEPTIDE ANTIBIOTICS | CATALYZED DIRECT ARYLATION | Biological Products - chemistry | Molecular Structure | Catalysis | Heterocyclic Compounds - chemistry | Palladium - chemistry | Pharmaceutical Preparations - chemistry | Natural products | Ligands | Coupling (molecular) | Halides | Chemical reactions | Transformations | Polymers | Bonding
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2. Full Text Cu-Catalyzed Direct C6-Arylation of Indoles
by Yang, Youqing and Li, Ruirui and Zhao, Yue and Zhao, Dongbing and Shi, Zhuangzhi
Journal of the American Chemical Society, ISSN 0002-7863, 07/2016, Volume 138, Issue 28, pp. 8734 - 8737
The first example of direct and site-selective arylation of indoles at the C6 position has been reported. The key to this high regioselectivity is the... 
FUNCTIONALIZATION | MILD | ROOM-TEMPERATURE | ACTIVATION | ARENES | H BOND ARYLATION | DIARYLIODONIUM SALTS | N-PIVALOYLINDOLES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Arylation | Research | Chemical properties | Catalysis | Copper | Indole
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3. Full Text Ruthenium–NHC‐Catalyzed Asymmetric Hydrogenation of Flavones and Chromones: General Access to Enantiomerically Enriched Flavanones, Flavanols, Chromanones, and Chromanols
by Zhao, Dongbing and Beiring, Bernhard and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2013, Volume 52, Issue 32, pp. 8454 - 8458
Two to four! Readily available flavones and chromones were efficiently converted into four valuable chiral classes of O‐heterocycles—flavanones, chromanones,... 
ruthenium | asymmetric catalysis | N‐heterocyclic carbenes | hydrogenation | chromanols | N-heterocyclic carbenes | GLYCOSIDES | HIGHLY ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHORUS LIGANDS | ALKENES | KINETIC RESOLUTION | ENONES | LIPASE | INHIBITORS | CONJUGATE ADDITION | Chromones - chemistry | Catalysis | Flavones - chemistry | Hydrogenation | Ruthenium - chemistry | Ruthenium | Enrichment | Asymmetry | Carbenes | Flavanols
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4. Full Text Enantioselective Hydrogenation of Isoquinolines
by Zhao, Dongbing and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2013, Volume 52, Issue 37, pp. 9616 - 9618
N‐H2eterocycles: Significant advances have been made in the development of the enantioselective partial or full hydrogenation of substituted isoquinolines and... 
heteroarenes | isoquinolines | asymmetric synthesis | pyridines | hydrogenation | CATALYZED ASYMMETRIC HYDROGENATION | HETEROAROMATIC-COMPOUNDS | SALTS | CHEMISTRY, MULTIDISCIPLINARY | Synthesis | Pyridine | Enantiomers | Hydrogenation | Organic compounds | Piperidine
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5. Full Text Cobalt(III)‐Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π‐Systems
by Zhao, Dongbing and Kim, Ju Hyun and Stegemann, Linda and Strassert, Cristian A and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 15, pp. 4508 - 4511
The first highly efficient and scalable cobalt‐catalyzed directed CH functionalization with carbene precursors is presented. This methodology provides a... 
carbenes | CH activation | cobalt | π‐systems | heterocycles | Heterocycles | π-systems | C-H activation | Carbenes | Cobalt
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6. Full Text Rhodium(III)‐Catalyzed Cyclative Capture Approach to Diverse 1‐Aminoindoline Derivatives at Room Temperature
by Zhao, Dongbing and Vásquez‐Céspedes, Suhelen and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 5, pp. 1657 - 1661
A RhIII‐catalyzed C–H activation/cyclative capture approach, involving a nucleophilic addition of C(sp3)–Rh species to polarized double bonds is reported. This... 
indolines | directing groups | heterocycles | C–H functionalization | rhodium | Heterocycles | Rhodium | C-H functionalization | Indolines | Directing groups | DIRECTING GROUP | CINNOLINIUM SALTS | INTERNAL ALKYNES | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | UNSYMMETRICAL AZO-COMPOUNDS | OXIDATIVE OLEFINATION | FUNCTIONALIZATION | REGIOSELECTIVE SYNTHESIS | BOND ACTIVATION | Alkenes - chemistry | Quantum Theory | Temperature | Catalysis | Hydrogen - chemistry | Indoles - chemistry | Carbon - chemistry | Rhodium - chemistry | Analysis | Chemical properties | Fasteners | Activation | Derivatives | Catalysts
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7. Full Text Intermolecular σ‐Bond Cross‐Exchange Reaction between Cyclopropenones and (Benzo)silacyclobutanes: Straightforward Access towards Sila(benzo)cycloheptenones
by Zhao, Wen‐Tao and Gao, Fang and Zhao, Dongbing
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 21, pp. 6329 - 6332
Described herein is the first intermolecular σ‐bond exchange reaction between the C−C bond of cyclopropenones and C−Si bond of (benzo)silacyclobutanes and it... 
silanes | palladium | strained molecules | heterocycles | ring expansion | Exchanging | Palladium | Nickel | Chemical synthesis
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8. Full Text Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C-H bond addition cascade using a CpRhIII catalystElectronic supplementary information (ESI) available. CCDC 1864795 and 1864796. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc08792j
by Li, Ruirui and Ju, Cheng-Wei and Zhao, Dongbing
ISSN 1359-7345, 1/2019, Volume 55, Issue 5, pp. 695 - 698
Three-component C-H bond additions across two different coupling partners remain underdeveloped. Herein, we report the first three-component Rh III -catalyzed... 
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9. Full Text Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C–H bond addition cascade using a CpRhIII catalyst
by Li, Ruirui and Ju, Cheng-Wei and Zhao, Dongbing
Chemical Communications, ISSN 1359-7345, 01/2019, Volume 55, Issue 5, pp. 695 - 698
Three-component C–H bond additions across two different coupling partners remain underdeveloped. Herein, we report the first three-component RhIII-catalyzed... 
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10. Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C–H bond addition cascade using a CpRhIII catalyst (Electronic supplementary information (ESI) available. CCDC 1864795 and 1864796. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc08792j)
by Ruirui Li and Cheng-Wei Ju and Dongbing Zhao
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2019, Volume 55, Issue 5, pp. 695 - 698
Three-component C–H bond additions across two different coupling partners remain underdeveloped. Herein, we report the first three-component RhIII-catalyzed... 
Rhodium | Hydrogen bonds | Catalysis | Aldehydes | Dienes | Crystallography | Alcohols
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11. Full Text Palladium(II)-Catalyzed Oxidative C−H/C−H Cross-Coupling of Heteroarenes
by Xi, Peihua and Yang, Fan and Qin, Song and Zhao, Dongbing and Lan, Jingbo and Gao, Ge and Hu, Changwei and You, Jingsong
Journal of the American Chemical Society, ISSN 0002-7863, 02/2010, Volume 132, Issue 6, pp. 1822 - 1824
An efficient methodology for the synthesis of unsymmetrical biheteroaryl molecules has been developed via Pd(II)-catalyzed oxidative C−H/C−H cross-coupling of... 
FUNCTIONALIZATION | ACTIVATION | ARYL BOND FORMATION | HETEROCYCLES | MECHANISM | N-OXIDES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | DISCOVERY | CATALYZED DIRECT ARYLATION | Heterocyclic Compounds - chemistry | Oxidation-Reduction | Molecular Conformation | Models, Molecular | Catalysis | Hydrogen - chemistry | Palladium - chemistry | Carbon - chemistry | Electrons | Palladium catalysts | Pyridine | Analysis | Heterocyclic aromatic compounds | Oxidation-reduction reaction | Chemical properties | Structure | Electric properties
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12. Full Text Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acidsElectronic supplementary information (ESI) available. CCDC 1852875 and 1852877. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc02182e
by Zhang, Yun and Chen, Gong and Zhao, Dongbing
ISSN 2041-6520, 8/2019, Volume 1, Issue 34, pp. 7952 - 7957
Herein, we report three-component vicinal-diarylation of non-conjugated alkenes initiated by transmetalation of arylboronic acids, which provides complementary... 
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13. Full Text Recent Progress in σ-Bond Cross-Exchange Reactions to Access Diverse Silacycles
by Zhao, Wen-Tao and Gao, Fang and Zhao, Dongbing
Synlett, ISSN 0936-5214, 12/2018, Volume 29, Issue 20, pp. 2595 - 2600
Abstract The σ-bond cross-exchange reaction, which involves cleavage and subsequent exchange between different nonpolar σ-bonds, constitutes an attractive... 
synpacts | silacycles | heterocycle | metal catalysis | σ-bond | exchange reaction
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14. Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids (Electronic supplementary information (ESI) available. CCDC 1852875 and 1852877. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc02182e)
by Yun Zhang and Gong Chen and Dongbing Zhao
Chemical Science, ISSN 2041-6520, 01/2019, Volume 10, Issue 34, pp. 7952 - 7957
Herein, we report three-component vicinal-diarylation of non-conjugated alkenes initiated by transmetalation of arylboronic acids, which provides complementary... 
Carbonyl compounds | Alkenes | Palladium | Catalysis | Enantiomers | Crystallography | Carbonyls
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15. Full Text Cobalt(III)-Catalyzed Directed C-H Coupling with Diazo Compounds: Straightforward Access towards Extended pi-Systems
by Zhao, DB and Kim, JH and Stegemann, L and Strassert, CA and Glorius, F
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 04/2015, Volume 54, Issue 15, pp. 4508 - 4511
The first highly efficient and scalable cobalt-catalyzed directed CH functionalization with carbene precursors is presented. This methodology provides a... 
DIRECT FUNCTIONALIZATION | carbenes | AROMATIC IMINES | cobalt | ORGANIC SEMICONDUCTORS | CHEMISTRY, MULTIDISCIPLINARY | FIELD-EFFECT TRANSISTORS | N-TOSYLHYDRAZONES | DIRECT ALKYLATION | CH activation | heterocycles | systems | METAL CARBENE | BOND ACTIVATION | CATALYZED DIRECT ARYLATION | Solid state | Wavelengths | Methodology | Precursors | Hydrocarbons | Emission | Joining | Modular | Carbenes
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16. Full Text Rh(iii)-catalyzed C-H functionalization/aromatization cascade with 1,3-dienes: A redox-neutral and regioselective access to isoquinolines
by Zhao, Dongbing and Lied, Fabian and Glorius, Frank
Chemical Science, ISSN 2041-6520, 2014, Volume 5, Issue 7, pp. 2869 - 2873
An efficient rhodium(III)- catalyzed redox- neutral C-H activation/cyclization/isomerization strategy to prepare isoquinolines with complete regioselectivity... 
MEDIATED ELECTROPHILIC CYCLIZATION | IRIDIUM-CATALYZED HYDROGENATION | OLEFINATION | VERSATILE | TERMINAL ALKYNES | BOND FORMATION | ASYMMETRIC HYDROGENATION | PYRIDINES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | RING-CLOSURE
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