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Journal of the American Chemical Society, ISSN 0002-7863, 08/2012, Volume 134, Issue 33, pp. 13565 - 13568
A Rh-catalyzed intermolecular coupling of diazomalonates with arene C–H bonds is reported. The reaction is initiated by electrophilic C–H activation, which is... 
PALLADIUM | ACTIVATION | INSERTION | CROSS-COUPLING REACTION | ARYL | ALDEHYDES | STEREOSELECTIVE-SYNTHESIS | N-CHLOROAMINES | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | DIAZOESTERS
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 18, pp. 5889 - 5893
An asymmetric Rh­(I)-catalyzed functionalization of the 3-C­(sp3 )–H bond of benzofuranones with α-diazoesters has been developed, providing a new strategy for... 
QUATERNARY STEREOCENTER | 3-SUBSTITUTED BENZOFURAN-2(3H)-ONES | CARBENE INSERTION | CHEMISTRY | CHEMISTRY, ORGANIC | DIAZO-COMPOUNDS | STEREOSELECTIVE FUNCTIONALIZATION | CATALYST | C-H BONDS | ENANTIOSELECTIVE INSERTION | MICHAEL ADDITION
Journal Article
Organic Letters, ISSN 1523-7060, 04/2018, Volume 20, Issue 7, pp. 1720 - 1724
Rh (III)-catalyzed C–H activation of benzoylacetonitriles in coupling with diazo compounds was developed to synthesize diversified substituted... 
COMPOUNDS ACCESS | BENZAMIDES | ANNULATION | CHEMISTRY, ORGANIC | PROPARGYL ALCOHOLS | BOND ACTIVATION | INTERNAL ALKYNES | DERIVATIVES | ARYLNITRONES | INDOLES | CARBENOID FUNCTIONALIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 04/2013, Volume 15, Issue 8, pp. 1814 - 1817
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 1, pp. 42 - 45
A Rh­(III)-catalyzed unsymmetrical C–H alkylation and amidation of N-phenoxyacetamides with diazo compounds has been developed under mild and redox-neutral... 
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 44, pp. 5618 - 5621
Herein we demonstrate that an alkylation of indoles could be accessed through C–H bond functionalization with α,α-difluorovinyl tosylate. The key aspect for... 
Fluorides | Indoles | Hydrogen bonds | Fluorine | Alkylation
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 44, pp. 5618 - 5621
Herein we demonstrate that an alkylation of indoles could be accessed through C-H bond functionalization with alpha,alpha-difluorovinyl tosylate. The key... 
FUNCTIONALIZATION | ACTIVATION | ALPHA-FLUOROALKENYLATION | COUPLING REACTIONS | N BOND | FLUORINE | GEM-DIFLUOROSTYRENES | STEREOSELECTIVE-SYNTHESIS | NUCLEOPHILIC-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS
Journal Article
Thoracic Cancer, ISSN 1759-7706, 11/2018, Volume 9, Issue 11, pp. 1354 - 1360
Journal Article
by Hu, QY and Zhang, RH and Chen, D and Guo, YF and Zhan, W and Luo, LM and Zhou, XW
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, ISSN 0360-3199, 06/2019, Volume 44, Issue 31, pp. 16287 - 16296
The structure-activity relationship between the morphology and composition of Pd-based nanocatalysts is an important fundamental issue in direct methanol fuel... 
ELECTROCHEMISTRY | Electrocatalyst | ONE-POT SYNTHESIS | ENERGY & FUELS | Pd-Rh alloy | Netlike structure | GRAPHENE | ELECTROOXIDATION | CHEMISTRY, PHYSICAL | Methanol oxidation reaction | CATALYST | HYDROTHERMAL SYNTHESIS | NANOPARTICLES | OXYGEN REDUCTION | ELECTROCATALYTIC PROPERTIES | ETHANOL | NANOWIRES | Palladium catalysts | Oxidation-reduction reaction | Palladium | Fuel cells | Alloys | Methanol
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2015, Volume 51, Issue 27, pp. 5868 - 5871
Here we report a new and mild Rh(III)-catalyzed and alcohol-involved carbenoid C-H insertion into N-phenoxyacetamides using alpha-diazomalonates. This reaction... 
OXIDIZING DIRECTING GROUP | FACILE SYNTHESIS | RHODIUM(III)-CATALYZED ORTHO-ALKENYLATION | METAL CARBENE | INTERNAL OXIDANT | EFFICIENT SYNTHESIS | BOND FORMATION | DIAZO-COMPOUNDS | INDOLE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | DIAZOCARBONYL COMPOUNDS | Phenyls | Insertion | Tolerances | Carbon | Substrates | Functional groups | Rings (mathematics)
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 04/2015, Volume 51, Issue 27, pp. 5868 - 5871
Here we report a new and mild Rh(III)-catalyzed and alcohol-involved carbenoid C-H insertion into N-phenoxyacetamides using α-diazomalonates. This reaction... 
Azo Compounds - chemistry | Malonates - chemistry | Stereoisomerism | Phenoxyacetates - chemistry | Molecular Structure | Catalysis | Methanol - chemistry | Carbon - chemistry | Rhodium - chemistry
Journal Article
Physical Review B - Condensed Matter and Materials Physics, ISSN 1098-0121, 10/2015, Volume 92, Issue 14
Magneto-optical Kerr effect, normally found in magnetic materials with nonzero magnetization such as ferromagnets and ferrimagnets, has been known for more... 
PHYSICS, CONDENSED MATTER | FILMS | FARADAY | ALLOYS | SURFACE | DEPENDENCE | MULTILAYERS | Antiferromagnetism | Magnetization | Condensed matter | Kerr effects | Preserves | Magnetic materials | Ferromagnetism | Symmetry
Journal Article
Organic Letters, ISSN 1523-7060, 06/2017, Volume 19, Issue 11, pp. 2777 - 2780
A Rh­(III)-catalyzed tandem C–H alkylation/intramolecular decarboxylative cyclization of azoxy compounds with diazoesters for the synthesis of... 
PALLADIUM | AZOXYBENZENES | ONE-POT | AZOBENZENES | INDAZOLES | CHEMISTRY, ORGANIC | 1H-INDAZOLES | H BOND FUNCTIONALIZATION | CARBENE MIGRATORY INSERTION | ORTHO-ACYLATION | DERIVATIVES
Journal Article
Organic Letters, ISSN 1523-7060, 10/2017, Volume 19, Issue 19, pp. 5256 - 5259
Sulfoxonium ylides act as an efficient carbene precursor in rhodium­(III)-catalyzed C–H acylmethlyation of a variety of arenes assisted by different chelating... 
ACTIVATION | ARYL BORONIC ACIDS | HETEROCYCLES | MIGRATORY INSERTION | CATALYZED REACTIONS | ALKYLATION | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | DIAZO-COMPOUNDS | INDOLES | N-TOSYLHYDRAZONES
Journal Article
Organic Letters, ISSN 1523-7060, 12/2016, Volume 18, Issue 23, pp. 6144 - 6147
Quinazoline N-oxides have been prepared from simple ketoximes and 1,4,2-dioxazol-5-ones via Rh­(III)-catalyzed C–H activation–amidation of the ketoximes and... 
Journal Article
Organic Letters, ISSN 1523-7060, 01/2014, Volume 16, Issue 2, pp. 592 - 595
An unprecedented Rh(III)-catalyzed direct intermolecular C–H amidation with N-hydroxycarbamates has been developed. Different directing groups, such as... 
ACTIVATION | BENZAMIDES | ARENES | CHLOROAMINES | BOND FUNCTIONALIZATION | DIRECT ADDITION | CHEMISTRY, ORGANIC | CATALYZED DIRECT AMINATION | INTERNAL ALKYNES | BENZOIC-ACIDS | Nitrogen - chemistry | Stereoisomerism | Amides - chemistry | Molecular Structure | Catalysis | Carbamates - chemistry | Rhodium - chemistry
Journal Article
Chinese Journal of Chemistry, ISSN 1001-604X, 05/2016, Volume 34, Issue 5, pp. 473 - 476
Rh(I)‐Catalyzed synthesis of 1,1‐difluoro‐2,2‐diarylalkenes from trifluoromethylketone N‐tosylhydrazones and arylboronates is presented in this communication.... 
metal carbene | migratory insertion | β‐fluoride elimination | Rh(I)‐catalysis | Rh(I)-catalysis | β-fluoride elimination | DIFLUOROCARBENE | CATALYZED REACTIONS | GEM-DIFLUOROOLEFINATION | DIAZO-COMPOUNDS | ALDEHYDES | CARBENE MIGRATORY INSERTION | CHEMISTRY, MULTIDISCIPLINARY | beta-fluoride elimination | METHODOLOGY | DIFLUOROMETHYL 2-PYRIDYL SULFONE | BOND | Catalysis
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 04/2018, Volume 24, Issue 19, pp. 4815 - 4819
We developed an efficient synthesis of biaryls by a dirhodium(II)-catalyzed aromatic C-H arylation with diazo quinones. The new biaryl synthesis can be... 
carbenoids | C−H activation | arenes | biaryls | rhodium | GOLD CATALYSIS | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | ARYL-ALPHA-DIAZOACETATES | FUNCTIONALIZATION | C-H activation | PHENOLS | ALKYLATION SUBUNIT | CARBENE INSERTION | DIRHODIUM CARBENE | DERIVATIVES | DIAZIDES
Journal Article
Chemical communications (Cambridge, England), 08/2015, Volume 51, Issue 65, p. 12966
A new Ru(II)Rh(III) structural motif [(bpy)2Ru(dpp)RhCl(tpy)](4+) with one halide on the Rh(III) center demonstrates light-driven proton reduction ability,... 
Journal Article
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