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chemistry, inorganic & nuclear (54) 54
chemistry, organic (38) 38
chemistry (29) 29
rare earth metals (25) 25
organolanthanide complexes (23) 23
insertion (22) 22
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chemistry, multidisciplinary (20) 20
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yttrium (14) 14
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analysis (11) 11
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organic chemistry (11) 11
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Chemical Communications, ISSN 1359-7345, 06/2013, Volume 49, Issue 49, pp. 5589 - 5591
The first example of rare earth metal-catalyzed cycloaddition of terminal alkynes to azides resulting in the formation of 1,5-disubstituted 1,2,3-triazoles is... 
Lanthanoid Series Elements - chemistry | Cyclization | Triazoles - chemistry | Organometallic Compounds - chemistry | Triazoles - chemical synthesis | Alkynes - chemistry | Molecular Structure | Catalysis | Azides - chemistry
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2013, Volume 49, Issue 31, pp. 3171 - 3187
Journal Article
Tetrahedron, ISSN 0040-4020, 2011, Volume 67, Issue 20, pp. 3690 - 3697
A highly efficient and environmentally friendly method for catalytic chalcogenylation of imidazopyridines, imidazopyrimidines, indoles, and pyrrolo[2,3-... 
Azaheterocycles | Chalcogenylation | Copper(I) iodide | Air | Dichalcogenides | ONE-STEP SYNTHESIS | CHEMISTRY, ORGANIC | RECEPTOR | POTENT INHIBITORS | 2ND SULFENYLATION | INDOLE | 3-SULFENYL | BIOLOGICAL EVALUATION | FRIEDEL-CRAFTS REACTION | DERIVATIVES | DIARYL DISULFIDES | Tetrahedrons | Additives | Cleaning | Indoles | Catalysis | Catalysts
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 2019, Volume 58, Issue 13, pp. 8451 - 8459
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2017, Volume 56, Issue 4, pp. 2070 - 2077
Treatment of the yttrium dialkyl complex TpMe2Y­(CH2Ph)2­(THF) (TpMe2 = tri­(3,5 dimethylpyrazolyl)­borate, THF = tetrahydrofuran) with S8 in a 1:1 molar ratio... 
ELEMENTAL SULFUR | THIOLATE | TRANSITION-METAL-COMPLEXES | LIGANDS | DINITROSYL IRON COMPLEXES | ACTIVE-SITE | CRYSTAL-STRUCTURE | RICH LANTHANIDE CLUSTERS | CHEMISTRY | POLYSULFIDE | CHEMISTRY, INORGANIC & NUCLEAR | Sulfides | Usage | Chemical properties | Chemical synthesis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 38, pp. 11485 - 11489
Lanthanide‐catalyzed alkynyl exchange through C−C single‐bond cleavage assisted by a secondary amino group is reported. A lanthanide amido complex is proposed... 
amines | reaction mechanisms | C−C bond cleavage | alkynes | lanthanides | CROSS-METATHESIS | ACTIVATION | ONE-POT | COMPLEXES | EFFICIENT SYNTHESIS | TERMINAL ALKYNES | C-C bond cleavage | PROPARGYLIC AMINES | POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | HOMOALLYL ALCOHOLS | CYCLIZATION | Rare earth metals | Carbon-carbon composites | Exchanging | Transformation | Metathesis | Decomposition reactions | Cleavage | Dimerization | Alkynes
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2014, Volume 20, Issue 28, pp. 8551 - 8555
A lanthanide‐catalyzed sequential insertion of CN and CC into an NH bond is presented. The convenient reaction, which proceeds under mild conditions, is an... 
propargylamines | nitriles | imidazoles | CC coupling | lanthanides | C-C coupling
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 48, pp. 14452 - 14456
The first catalytic cycloamidination of aminoalkenes with nitriles has been achieved by using rare‐earth complexes. This reaction is equivalent to the desired... 
reaction mechanisms | cyclization | synthetic methods | nitrogen heterocycles | lanthanides | AMIDINES | C-N | INTRAMOLECULAR HYDROAMINATION | CHEMISTRY, MULTIDISCIPLINARY | AMINOOXYGENATION | ALKENES | HYDROAMIDATION | OLEFINS | ALIPHATIC-AMINES | ORGANOMETALLIC CATALYSIS | N-HETEROCYCLES
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2011, Volume 50, Issue 22, pp. 11813 - 11824
The structurally characterized TpMe2-supported rare earth metal monoalkyl complex (TpMe2)CpYCH2Ph(THF) (1) was synthesized via the salt-metathesis reaction of... 
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2015, Volume 71, Issue 24, pp. 4219 - 4226
A simple, cheap, efficient, and metal-free method for one-step synthesis of a library of 1,3-diheteroatom five-membered heterocycles with exocyclic C N and C C... 
Heterocycles | Metal-free | Iodocyclization | Propargylamines
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2008, Volume 73, Issue 4, pp. 1586 - 1589
A mild, versatile, and efficient method for the one-step synthesis of substituted dihydro- and tetrahydroisoquinolines has been developed by the FeCl3·6H2O... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 4, pp. 1062 - 1067
The preferential substitution of oxo ligands over alkyl ones of rare‐earth complexes is commonly considered as “impossible” due to the high oxophilicity of... 
cluster compounds | theoretical chemistry | rare-earth complexes | organometallic chemistry | oxygen atom transfer | YTTRIUM COMPLEX | ACTIVE-SITE | OXO | CO OXIDATION | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | METAL | PHENYL ISOCYANATE | SELECTIVE FORMATION | CARBON-DIOXIDE | Rare earth metals | Oxygen | Ketones | Computer applications | Clusters | Reversing | Ligands
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2014, Volume 53, Issue 4, pp. 1053 - 1056
Two new trinuclear μ3‐bridged rare‐earth metal phosphinidene complexes, [{L(Ln)(μ‐Me)}3(μ3‐Me)(μ3‐PPh)] (L=[PhC(NC6H4iPr2‐2,6)2]−, Ln=Y (2 a), Lu (2 b)), were... 
density functional calculations | phosphinidenes | CH activation | CS2 activation | rare earths | C-H activation | activation | CATALYSIS | METHYLIDENE COMPLEXES | ALKYL | PHOSPHORUS ANALOGS | TUNGSTEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | CARBON BOND FORMATION | CH activation | LIGANDS | CARBENES | CHEMISTRY | Rare earth metals | Methane | Sulfides | Ketones | Fine chemicals | Toluene | Phenyls | Pathways | Precursors | Mathematical analysis | Clusters | Activation | Carbenes
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 09/2009, Volume 50, Issue 35, pp. 4978 - 4982
An efficient procedure for the synthesis of substituted indenes through the FeCl ·6H O-catalyzed intramolecular Friedel-Crafts cyclization of aryl-substituted... 
Journal Article
Organometallics, ISSN 0276-7333, 11/2011, Volume 30, Issue 21, pp. 5809 - 5814
The synthesis, structure, and reactivity of organoyttrium phosphides toward phenyl isocyanate (PhNCO) and phenyl isothiocyanate (PhNCS) are described. Reaction... 
Journal Article
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