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Accounts of Chemical Research, ISSN 0001-4842, 12/2007, Volume 40, Issue 12, pp. 1357 - 1366
Asymmetric hydrogenation of heteroaromatic compounds has emerged as a promising new route to saturated or partially saturated chiral heterocyclic compounds. In... 
HOMOGENEOUS HYDROGENATION | IRIDIUM-CATALYZED HYDROGENATION | HIGHLY ENANTIOSELECTIVE HYDROGENATION | LIGANDS | REDUCTION | VERSATILE | COMPLEXES | QUINOLINES | PYRIDINES | ORGANOCATALYTIC TRANSFER HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | Analysis | Chirality | Quinoline | Ligands | Chemical properties | Research | Structure | Hydrogenation | Electric properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 15, pp. 4522 - 4526
The enantioselective conjugated addition of tritylthiol to in situ generated ortho‐quinone methides (o‐QMs) is catalyzed by an acid–base bifunctional... 
organocatalysis | ortho‐quinone methides | asymmetric catalysis | thiol addition | ortho-quinone methides | Asymmetric catalysis | Organocatalysis | Thiol addition | Thiols | Catalysis | Enantiomers | Quinone | Stereoselectivity | Solvents | Synthesis | Asymmetry | Catalysts | Mercaptans | Optical activity | Strategy | Transformations
Journal Article
ChemCatChem, ISSN 1867-3880, 01/2015, Volume 7, Issue 1, pp. 54 - 56
Frustration is key: Enantioselective hydrogenation under metal‐free conditions by using frustrated Lewis pair (FLP) catalysts is a significant breakthrough for... 
boranes | enantioselectivity | metal‐free catalysis | hydrogenation | frustrated Lewis pairs | Boranes | Enantioselectivity | Metal-free catalysis | Hydrogenation | Frustrated Lewis pairs | metal-free catalysis | ACTIVATION | IMINES | CHEMISTRY, PHYSICAL | ASYMMETRIC HYDROGENATION | BORANE | Catalysis | Enantiomers | Fine chemicals
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 4006 - 4010
The enantioselective α‐addition of deconjugated butenolides has rarely been exploited, in contrast to the well‐studied γ‐addition of deconjugated butenolides.... 
butenolides | dihydrocoumarins | ortho-quinone methides | asymmetric catalysis | nucleophilic addition | ALDOL | ACTIVATION | ASYMMETRIC-SYNTHESIS | NATURAL-PRODUCTS | CHEMISTRY, MULTIDISCIPLINARY | GAMMA-SUBSTITUTED BUTENOLIDES | ALKYLATING-AGENTS | CYCLOADDITIONS | G-QUADRUPLEX | CONJUGATE ADDITION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2014, Volume 136, Issue 21, pp. 7688 - 7700
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2010, Volume 132, Issue 26, pp. 8909 - 8911
The first highly enantioselective hydrogenation of simple indoles was developed with a Brønsted acid as an activator to form the iminium intermediate in situ,... 
HIGHLY ENANTIOSELECTIVE SYNTHESIS | KETONES | AMINATION | QUINOLINES | INDOLINES | N-H IMINES | HETEROAROMATIC-COMPOUNDS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | IRIDIUM CATALYSTS | Substrate Specificity | Catalysis | Stereoisomerism | Hydrogenation | Indoles - chemistry | Palladium - chemistry | Palladium catalysts | Substitution reactions | Chemical properties | Analysis | Indole
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2016, Volume 138, Issue 33, pp. 10413 - 10416
An efficient kinetic resolution of axially chiral 5- or 8-substituted quinoline derivatives was developed through asymmetric transfer hydrogenation of... 
BRONSTED ACID | CATALYSIS | ENANTIOSELECTIVE SYNTHESIS | COUPLING REACTIONS | BIARYL COMPOUNDS | CONSTRUCTION | C-H ACTIVATION | HETEROAROMATIC-COMPOUNDS | PHOSPHORIC-ACIDS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Quinoline | Usage | Chemical properties | Hydrogenation | Chirality | Analysis
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2017, Volume 129, Issue 14, pp. 4064 - 4068
The enantioselective α‐addition of deconjugated butenolides has rarely been exploited, in contrast to the well‐studied γ‐addition of deconjugated butenolides.... 
Asymmetrische Katalyse | Butenolide | ortho-Chinonmethide | Nukleophile Addition | Dihydrocumarine | Distortion | Synthesis | Transesterification | Asymmetry | Mathematical analysis
Journal Article
ChemSusChem, ISSN 1864-5631, 04/2017, Volume 10, Issue 7, pp. 1337 - 1340
Journal Article
Synthesis (Germany), ISSN 0039-7881, 06/2016, Volume 48, Issue 12, pp. 1769 - 1781
Enantiopure heterocyclic architectures containing two or more heteroatoms in the ring system have attracted considerable attraction due to this motif playing a... 
enantioselectivity | heteroarenes | asymmetric catalysis | heterocycles | hydrogenation | CHIRAL PHOSPHORUS LIGANDS | CHEMISTRY, ORGANIC | RUTHENIUM-CATALYZED HYDROGENATION | FRUSTRATED LEWIS PAIRS | HETEROAROMATIC-COMPOUNDS | DIPHOSPHINE LIGANDS | ENANTIOSELECTIVE HYDROGENATION | QUINOXALINES | IRIDIUM-CATALYSTS | DIAMINE CATALYSTS | CHANNEL BLOCKERS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2012, Volume 51, Issue 40, pp. 10181 - 10184
Highly efficient iridium‐catalyzed asymmetric hydrogenations of simple 2‐substituted pyridinium salts gives the chiral 2‐substituted piperidines with up to 93... 
iridium | piperidines | asymmetric synthesis | pyridines | hydrogenation | N-IMINOPYRIDINIUM YLIDES | H IMINES | NITROGEN-HETEROCYCLES | QUINOLINES | HETEROAROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY ENANTIOSELECTIVE HYDROGENATION | RING-CLOSING METATHESIS | DERIVATIVES | QUINOXALINES | Synthesis | Pyridine | Catalysis | Hydrogenation | Organic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 49, pp. 15683 - 15687
Reported herein is a novel visible‐light photoredox system with Pd(PPh3)4 as the sole catalyst for the realization of the first direct cross‐coupling of... 
cross-coupling | palladium | radicals | photochemistry | halides | ORGANIC-SYNTHESIS | DIRECT ARYLATION | GOLD CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | SUZUKI-MIYAURA | PHOTOREDOX CATALYSIS | EXCITED-STATES | CROSS-COUPLING REACTIONS | ARYL HALIDES | DUAL CATALYSIS | Palladium catalysts | Palladium | Cross coupling | Quaternary | Aromatic compounds | Bromides | Bonding | Alkylation
Journal Article