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chemistry, inorganic & nuclear (12) 12
ruthenium (8) 8
ligands (7) 7
complexes (6) 6
chemistry, organic (5) 5
clusters (5) 5
crystallography (5) 5
hydrogenation (5) 5
nmr (5) 5
acetylides (4) 4
alkynes (4) 4
gold (4) 4
reactivity (4) 4
structure (4) 4
alkyne (3) 3
chelating phosphide (3) 3
chelating phosphinidene (3) 3
chemical properties (3) 3
chemistry (3) 3
crystal-structures (3) 3
crystals (3) 3
derivatives (3) 3
dft calculations (3) 3
fluorine substituted diphosphines (3) 3
heteronuclear clusters (3) 3
iron (3) 3
ruthenium carbonyl (3) 3
x-ray diffraction (3) 3
2-pyridylimine compounds (2) 2
acetylide (2) 2
alkyne insertion (2) 2
analysis (2) 2
and pt (2) 2
benzyne (2) 2
bond (2) 2
carbonyl clusters (2) 2
catalysis (2) 2
crystal-structure (2) 2
dimethylacetylene dicarboxylate (2) 2
diphosphine (2) 2
dynamic process (2) 2
mercaptopyridine (2) 2
molecular-structures (2) 2
osmium (2) 2
palladium (2) 2
ru312 (2) 2
ruthenium clusters (2) 2
tetraruthenium cluster (2) 2
transition metal compounds (2) 2
x-ray structures (2) 2
1,2-bisethane (1) 1
acetonitrile (1) 1
acetylene (1) 1
acetylenes (1) 1
activation (1) 1
ag (1) 1
alkyne derived ligands (1) 1
analogs (1) 1
approximation (1) 1
atoms (1) 1
azo compounds (1) 1
behavior (1) 1
benzyne complexes (1) 1
bond-forming reactions (1) 1
bonds (1) 1
c-13 (1) 1
c-h activation (1) 1
c3 symmetry (1) 1
carbon-monoxide cleavage (1) 1
carbonyl cluster (1) 1
carbonyls (1) 1
catalysts (1) 1
center-dot (1) 1
chemistry, multidisciplinary (1) 1
chloride (1) 1
chromium (1) 1
cleavage (1) 1
cluster chemistry (1) 1
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complex (1) 1
coordination chemistry (1) 1
copper (1) 1
crystal structure (1) 1
cyclic voltammetry (1) 1
cytokinins (1) 1
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di-2-pyridylmethane (1) 1
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dimethylformamide (1) 1
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energy (1) 1
enynes (1) 1
ethylene polymerization (1) 1
ethylene polymerization catalysts (1) 1
h bond activation (1) 1
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Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2014, Volume 751, pp. 826 - 829
The cluster [{Os (μ-H)(CO) } {1,3,5-(μ-SCH ) C H }] has been prepared by the reaction of [Os (CO) (NCMe) ] with 1,3,5-tris(mercaptomethyl)benzene under mild... 
Cyclic voltammetry | Osmium clusters | Thiolato complexes | C3 symmetry | Crystal structure
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 06/2019, Volume 492, pp. 8 - 17
The reaction of acetylide complexes [(μ-H)M (CO) (CCR)] (M = Ru, Os), R = SiMe , SiPh ) with tertiary phosphines can produce carbonyl substitution complexes or... 
Substitutes | Cleavage | Ruthenium | Phosphines | Structural analysis
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2011, Volume 696, Issue 25, pp. 4070 - 4078
The reaction of compound [Ru (CO) (μ–Cl)(μ–AuPPh )] ( ) with terminal alkynes HC CR; (R = C H –4–CH , C H –2,5–(CH ) , C H –2,4,5–(CH ) , C(CH ) = CH , Si(CH )... 
Gold | Ruthenium | Heteronuclear clusters | Acetylides | Alkynes
Journal Article
Polyhedron, ISSN 0277-5387, 10/2016, Volume 117, p. 453
The synthesis and structural characterization of rhodium(III) complexes of general formula [Rh(L.sup.n)Cl.sub.3] derived from { D... 
Chemical properties | Structure | Acetonitrile | Crystals | Cytokinins | Dimethylformamide | Surface active agents | Hydrogen | Analysis | Nuclear magnetic resonance spectroscopy | Hydrogen bonding
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 06/2009, Volume 694, Issue 13, pp. 1949 - 1958
Title Full: The hydrogenation reaction of [Ru (CO) (C F ) P(CH ) P(C F ) ]: Migration of a C F group from a phosphorus to a ruthenium atom. X-ray crystal... 
Ruthenium carbonyl | Fluorine substituted diphosphines | Chelating phosphinidene | Hydrogenation | Chelating phosphide
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 01/2016, Volume 801, pp. 157 - 170
The bridge diphosphine triruthenium clusters [Ru (μ-κ , -diphosphine)(CO) ] [diphosphine = dppe, dfppe and dppm, respectively] react with 3,5-... 
Sulfide | Diphosphine | Thiol | Ruthenium clusters | Phosphide
Journal Article
INORGANICA CHIMICA ACTA, ISSN 0020-1693, 06/2019, Volume 492, pp. 8 - 17
This work describes the reactions of [(mu-H) M-3(CO)(9)(CCSiMe3)] (M = Ru, Os) with phosphines L (L = PMe3, PMe2Ph, PMePh2, and PPh3) which produce... 
RUTHENIUM CLUSTERS | IRON | MECHANISM | KINETICS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Polyhedron, ISSN 0277-5387, 03/2019, Volume 161, pp. 251 - 260
Six series of parallel acetylene and perpendicular acetylide ruthenium trinuclear carbonyl and phosphine clusters have been synthesized. All complexes were... 
Clusters | Acetylenes | Ruthenium | Phenylphosphines | Acetylides | SUBSTITUTION | HYDROGENATION | BEHAVIOR | COMPLEXES | CRYSTAL-STRUCTURES | IRON | CRYSTALLOGRAPHY | CHEMISTRY, INORGANIC & NUCLEAR | LIGANDS | CHEMISTRY | METAL-CLUSTERS | COBALT
Journal Article
Polyhedron, ISSN 0277-5387, 02/2013, Volume 50, Issue 1, pp. 289 - 296
Synthesis and structural characterization of cis-dichlorocomplexes derived from 2-pyridylmethyl-N-methylimine (1), 2-pyridylmethyl-N-ethylimine (2), and... 
X-ray diffraction | 2-Pyridylimine compounds | NMR | Pd | and Pt | complexes
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 12/2011, Volume 696, Issue 25, pp. 4070 - 4078
The reaction of compound [Ru (CO) (μ-Cl)(μ- AuPPh )] (1) with terminal alkynes HCCR; (R = C H -4-CH , C H -2,5-(CH ) , C H -2,4,5-(CH ) , C(CH ) = CH , Si(CH )... 
Gold | Ruthenium | Acetylides | Heteronuclear clusters | Alkynes
Journal Article
Polyhedron, ISSN 0277-5387, 03/2013, Volume 52, pp. 170 - 182
The reaction of compound [Ru (CO) (NCMe ) ] with terminal alkynes HC CR, [R = C H -4-CH ( ), C H -2,5-(CH ) ( ), C H -2,4,5-(CH ) ( ), C H -4- Bu ( ), C H... 
Clusters | Ruthenium | Acetylides | Acetylene | RU-3(CO) | RU3(CO)12 | MODE | CRYSTAL-STRUCTURES | CRYSTALLOGRAPHY | ALKYNE | DERIVATIVES | CHEMISTRY, INORGANIC & NUCLEAR | Chemical properties
Journal Article
Polyhedron, ISSN 0277-5387, 02/2013, Volume 50, Issue 1, pp. 289 - 296
The synthesis and structural characterization of - and s-chelate complexes of Ni, Pd, and Pt of general formula [M {(C H N)–C(H) NR} Cl ] is described.... 
X-ray diffraction | NMR | 2-Pyridylimine compounds | NiII, PdII and PtII complexes
Journal Article
Polyhedron, ISSN 0277-5387, 05/2002, Volume 21, Issue 11, pp. 1105 - 1115
A series of alkyne parallel μ -η (//) substituted trinuclear cluster derivatives has been synthesized, containing the alkynes (HC≡ CR, R = SiMe , SiPh and tBu)... 
Acetylide | Ruthenium | Clusters | Osmium | Alkyne
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2008, Volume 130, Issue 51, pp. 17351 - 17361
A series of three-coordinate Cr(II) complexes sharing the common molecular fragment “(nacnac)Cr” (nacnac− = [ArNC( t Bu)]2CH, Ar = 2,6- i Pr2C6H3) were... 
H BOND ACTIVATION | CARBON-MONOXIDE CLEAVAGE | IMIDO COMPLEXES | MECHANISTIC INVESTIGATIONS | ORGANOMETALLIC COMPOUNDS | HYDROCARBON ACTIVATION | RAY CRYSTAL-STRUCTURES | TRANSITION-METAL | ETHYLENE POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | REVERSIBLE 1,2-RH-ELIMINATION
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 10/2002, Volume 660, Issue 2, pp. 153 - 160
The pyrolysis reaction of [Ru (CO) (dppe)], compound 1, in toluene yields as the main product [Ru (CO) (μ-CO)μ4-η - PCH CH P(C H )2(μ -η -C H'4)], compound 2.... 
Tetraruthenium cluster | Dynamic process | Benzyne
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2011, Volume 696, Issue 3, pp. 748 - 757
The thermally unstable adduct Tp Ir(C H )(DMAD), which was generated “in situ” by the reaction of DMAD with Tp Ir(C H ) ( ) at low temperature, reacted with... 
Dimethylacetylene dicarboxylate | Alkyne insertion | C–H activation | Tp Me2 iridium complexes | DFT calculations
Journal Article
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