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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2018, Volume 57, Issue 13, pp. 3372 - 3376
The instability of hydroxy peroxyesters, the elusive Criegee intermediates of the Baeyer–Villiger rearrangement, can be alleviated by selective deactivation of... 
peroxides | reactive intermediates | stereoelectronics | Baeyer–Villiger reaction | anomeric effects | OXIDATION | FRAGMENTATION | CHEMISTRY, MULTIDISCIPLINARY | MONOOXYGENASES | OXYGEN | KETONES | ORGANIC PEROXIDES | C-NUCLEOSIDE SYNTHESIS | LACTONES | ESTERS | HYDROGEN-PEROXIDE | Baeyer-Villiger reaction | Ketoesters | Deactivation | Stability | Hydrogen peroxide | Intermediates
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2018, Volume 57, Issue 14, pp. 3651 - 3655
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2017, Volume 139, Issue 31, pp. 10799 - 10813
The first systematic study of the intramolecular α-effect, both in the stable ground-state structures and in the high-energy intermediates, was accomplished... 
DENSITY FUNCTIONALS | KETONES | ORGANIC PEROXIDES | GEM-DIHYDROPEROXIDES | PHASE S(N)2 REACTIONS | BRIDGED 1,2,4,5-TETRAOXANES | GEMINAL BISHYDROPEROXIDES | REACTIVITY | HYDROGEN-PEROXIDE | CYCLIC PEROXIDES | CHEMISTRY, MULTIDISCIPLINARY | Carbonyl compounds | Ground state | Chemical reactions | Usage | Research | Chemical properties
Journal Article
Nature Communications, ISSN 2041-1723, 12/2017, Volume 8, Issue 1, pp. 166 - 7
The preparation of high-performance fluorinated poly(aryl thioethers) has received little attention compared to the corresponding poly(aryl ethers), despite... 
METAL-FREE SYNTHESIS | DITHIOLS | POLYMERS | POLY(ETHER KETONE)S | MULTIDISCIPLINARY SCIENCES | SULFONE)S | SOLUBILITY | SULFIDE | ThioeThers | Ethers | Fluorination | Aromatic compounds | Physical properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2017, Volume 139, Issue 9, pp. 3406 - 3416
The synergy between bond formation and bond breaking that is typical for pericyclic reactions is lost in their mechanistic cousins, cycloaromatization... 
MYERS-SAITO | BALDWIN RULES | 1,3-DIPOLAR CYCLOADDITIONS | COPE REARRANGEMENTS | GOLD CATALYSIS | DISTORTION ENERGIES | TRANSITION-STATES | COMPUTATIONAL EVIDENCE | ENYNE-ALLENES | CHEMISTRY, MULTIDISCIPLINARY | RING-CLOSURE | Usage | Analysis | Chemical bonds | Ring formation (Chemistry) | Chemical properties | Catalysis | Zwitterions
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 5, pp. 1298 - 1302
We developed the novel one‐pot synthetic method of substituted triptycenes by the reaction of ynolates and arynes. This four‐step process involves three... 
directing effect | aryne | hyperconjugation | triptycene | ynolate | KETENE SILYL ACETAL | CASCADE TRANSFORMATIONS | Z-SELECTIVE OLEFINATION | CARBONYL-COMPOUNDS | DIECKMANN CONDENSATION | CHEMISTRY, MULTIDISCIPLINARY | RADICAL CASCADES | TRACELESS DIRECTING GROUPS | SUBSTITUENT | STEREOSELECTIVE-SYNTHESIS | EFFICIENT | Chelation | Anthracene | Regioselectivity | Nucleophiles | Ring opening
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 38, pp. 11633 - 11637
This work discloses the first general solution for converting oligoalkynes into polyaromatic polycyclic systems free of pentagonal defects. The efficiency and... 
cyclizations | tin | radicals | alkynes | polycycles | CASCADE TRANSFORMATIONS | ACETYLENES | STATE | EQUIVALENTS | FRAGMENTATIONS | CHEMISTRY, MULTIDISCIPLINARY | Annealing | Transformation | Alkenes | Converting | Efficiency | Selectivity | Crafts | Hybridization | Alkynes | Defects
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2017, Volume 23, Issue 14, pp. 3225 - 3245
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 18, pp. 4955 - 4959
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 3, pp. 1165 - 1180
We report the first example of a traceless directing group in a radical cascade. The chemo- and regioselectivity of the initial attack in skipped oligoalkynes... 
DENSITY FUNCTIONALS | DISUBSTITUTED ACETYLENES | ROOM-TEMPERATURE | HYDROSTANNYLATION | STEREOSELECTIVITY | ARYL STANNANES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | RING-CLOSURE | ENYNE CYCLIZATIONS | PROPARGYLIC ALCOHOL DERIVATIVES | Butane | Chemical properties | Electric properties
Journal Article
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2017, Volume 139, Issue 45, pp. 16210 - 16221
An intramolecular oxidative C­(sp3)–H amination from unprotected anilines and C­(sp3)–H bonds readily occurs under mild conditions using t-BuOK, molecular... 
AROMATIC-HYDROCARBONS | DENSITY FUNCTIONALS | CHEMICAL-SHIFTS NICS | RADICAL STABILITY | SOMO-HOMO CONVERSION | EFFICIENT SYNTHESIS | CONNECTOR GROUPS | SINGLET OXYGEN | SYNTHETIC APPROACH | CHEMISTRY, MULTIDISCIPLINARY | INTRAMOLECULAR ADDITION
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2019, Volume 2019, Issue 2-3, pp. 512 - 518
A synergy between theory and experiments leads to a milder protocol for base‐mediated high‐temperature benzannulation of alkynylpyridine substrates.... 
Allenes | Guanidines | Benzannulation | Isomerization | Proton transfer | Alkynes | PATH | BENZYNES | DIELS-ALDER REACTIONS | MECHANISM | HETEROAROMATICS QUINOLINES | CHEMISTRY, ORGANIC | DENSITY FUNCTIONALS | REARRANGEMENT | C-C FRAGMENTATIONS | CONSTRUCTION | DYNAMICS
Journal Article