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Chemical Science, ISSN 2041-6520, 07/2016, Volume 7, Issue 8, pp. 5219 - 5223
The biosynthetic origin of a unique hydrazide moiety in the phosphonate natural product fosfazinomycin is unknown. This study presents the activities of five... 
Origins | Genes | Clusters | Labelling | Acetylation | Hydrazides | Nitrogen | Isotopes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 51, pp. 17820 - 17824
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2019
Journal Article
Nature Chemical Biology, ISSN 1552-4450, 04/2018, Volume 14, Issue 4, pp. 375 - 380
Journal Article
ACS CHEMICAL BIOLOGY, ISSN 1554-8929, 07/2019, Volume 14, Issue 7, pp. 1583 - 1592
Lanthipeptides, which belong to the super family of ribosomally synthesized and posttranslationally modified peptides (RiPPs), are associated with various... 
MYCOBACTERIUM-TUBERCULOSIS | LACTICIN-481 | AMINO-ACID | PROTEIN | BIOSYNTHESIS | BIOCHEMISTRY & MOLECULAR BIOLOGY | LABIONIN | IDENTIFICATION | MOTIF
Journal Article
ISSN 1359-7345, 8/2018, Volume 54, Issue 65, pp. 97 - 91
Substrate binding assays, in vitro proteolytic processing assays, and heterologous lasso peptide production were used to investigate the roles of conserved... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2019, Volume 17, Issue 4, pp. 822 - 829
The C-terminal domain of the dehydrophos biosynthetic enzyme DhpH (DhpH-C) catalyzes the condensation of Leu-tRNA(Leu) with (R)-1-aminoethylphosphonate, the... 
ACID | AMINOACYL-TRANSFER-RNA | ANTIBACTERIAL ACTIVITY | OLIGOPEPTIDES | RHIZOCTICINS | CHEMISTRY, ORGANIC | BOND FORMATION | AGENTS | PHOSPHONOPEPTIDES | ALAFOSFALIN | PHOSPHINOTHRICIN-TRIPEPTIDE SYNTHETASES
Journal Article
ISSN 1477-0520, 1/2019, Volume 17, Issue 4, pp. 822 - 829
The C-terminal domain of the dehydrophos biosynthetic enzyme DhpH (DhpH-C) catalyzes the condensation of Leu-tRNA Leu with ( R )-1-aminoethylphosphonate, the... 
Journal Article
Chemical Science, ISSN 2041-6520, 02/2015, Volume 6, Issue 2, pp. 1282 - 1287
Fosfazinomycin A is a phosphonate natural product in which the C-terminal carboxylate of a Val-Arg dipeptide is connected to methyl... 
GENE-CLUSTER | PATHWAY | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHONATE BIOSYNTHESIS | Linkages | Enzymes | Hydroxylation | Phosphonates | Segments | Iron | Hydrazides | Methylation
Journal Article
Proceedings of the National Academy of Sciences, USA, ISSN 0027-8424, 03/2016, Volume 113, Issue 13, pp. 3521 - 3521
Production of ribosomally synthesized and posttranslationally modified peptides (RiPPs) has rarely been reported in fungi, even though organisms of this... 
Journal Article
Chemical Science, ISSN 2041-6520, 09/2015, Volume 6, Issue 11, pp. 6270 - 6279
The final step of lanthipeptide biosynthesis involves the removal of leader peptides by dedicated proteases. In vitro characterization of LicP, a class II LanP... 
NISIN | SUBSTRATE-SPECIFICITY | SERINE PROTEASES | LEADER PEPTIDE | NATURAL-PRODUCTS | CRYSTAL-STRUCTURE | BIOSYNTHESIS | LANTIBIOTICS | SUBTILISIN BPN | PROTEINS | CHEMISTRY, MULTIDISCIPLINARY | Biotechnology | Peptides | Protease | Amino acids | Cleavage | Biosynthesis | Bonding | Crystal structure
Journal Article
ISSN 1359-7345, 12/2016, Volume 53, Issue 1, pp. 224 - 227
The role of a backbone carbonyl interaction with an engineered Cu A center in azurin was investigated by developing a method of synthesis and incorporation of... 
Journal Article
Biopolymers, ISSN 0006-3525, 11/2016, Volume 106, Issue 6, pp. 834 - 842
Journal Article
FEBS Letters, ISSN 0014-5793, 09/2012, Volume 586, Issue 19, p. 3391
a* CypM can methylate both [alpha]-N-terminal amino groups and lysine I[micro]-amino groups. a* CypM methylates a variety of cyclic peptides such as nisin and... 
Monte Carlo method | Cysteine | Dimethylformamide | Peptides | Lysine | Markov processes | Methylation | S-adenosylmethionine | Promiscuity
Journal Article
Nature, ISSN 0028-0836, 04/2013, Volume 496, Issue 7443, pp. 34 - 35
[...]in vivo experiments3, as well as in vitro incubation4 of HppE with isotopically labelled (S)-2-hydroxypropylphosphonate, ((S)-2-HPP, the enzyme's... 
Studies | Enzymes | Chemistry | Biosynthesis | Migration
Journal Article