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Chemical Communications: Chem Comm, ISSN 1359-7345, 04/2014, Volume 50, Issue 34, pp. 4416 - 4419
The branched trichlorotetrasilane PhSi(SiMe sub(2)Cl) sub(3) reacts with P sub(7)(SiMe sub(3)) sub(3 ) leading to formation of a new oligophosphane {PhSi(SiMe... 
Synthesis | Formations | Derivatives | Phosphines
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 07/2017, Volume 53, Issue 54, pp. 7620 - 7623
The parent phosphinidene SIMesPH (1) (SIMes = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene) was treated with benzyl potassium to form the metalated... 
Cage compounds | Potassium | Parents
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 11/2016, Volume 52, Issue 90, pp. 13265 - 13268
The first hybrid crown ether with two adjacent disilane fragments was synthesized through reaction of O(Si2Me4Cl)2 (3) with O(C2H4OH)2. By means of DFT... 
Complexation | Synthesis (chemistry) | Synthesis | Crown ethers | Mathematical analysis | Fragments | Silicon
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2015, Volume 2015, Issue 5, pp. 837 - 844
Monomeric N‐heterocyclic carbene (NHC)‐stabilized compounds (IMes)R2MP(H)SitBuPh2 (2: M = Al, R = Et; 3: M = Ga, R = Et; 4: M = Ga, R = iPr; 5: M = In, R = Et)... 
Cage compounds | Heterocycles | Gallium | Aluminum | CAGE | PHOSPHINE | COMPLEXES | COMPOUND | REACTIVITY | CHEMISTRY, INORGANIC & NUCLEAR | ELEMENTS | RING | RAY CRYSTAL-STRUCTURES | PHOSPHORUS COMPOUNDS | CHEMISTRY | Indium | Nuclear magnetic resonance spectroscopy | Analysis | Decomposition | X-rays | Aluminium | NMR spectroscopy | Carbenes | Phosphines
Journal Article
Dalton Transactions, ISSN 1477-9226, 05/2017, Volume 46, Issue 21, pp. 7074 - 7081
Herein we present the synthesis and characterization of the new four-membered Ga/P cycle [tBu2GaP(H)SitBu2Ph]2, which shows a cis/trans isomerization at... 
Binding | Gallium | Ambient temperature | Isomerization | Ligands | Lewis base | Bonding | Ring opening
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 78, pp. 11646 - 11648
Herein we report the synthesis of the first ionic liquids with the highly reactive and synthetically valuable phosphaethynolate (PCO-) anion. They are simply... 
SODIUM PHOSPHAETHYNOLATE | NA(OCP) | 2-PHOSPHAETHYNOLATE ANION | CHEMISTRY, MULTIDISCIPLINARY | POLYPHOSPHIDES | Anions | Liquids | Organic salts | Synthesis | Ionic liquids | Strategy | Cations | Symmetry
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2014, Volume 50, Issue 57, pp. 7709 - 7711
The synthesis of the thermally stable bicyclic diphosphasilirane O(SiiPr(2)P)(2)SiiPr(2)(4) was achieved via oxidation of the alkaline earth metal substituted... 
CHEMISTRY | RING STRAIN | CYCLOTRIPHOSPHANE | CHEMISTRY, MULTIDISCIPLINARY | AB-INITIO | PHOSPHORUS-COMPOUNDS | Alkaline earth metals | Synthesis | Impurities | Dimerization | Thermal stability
Journal Article
Dalton Transactions, ISSN 1477-9226, 03/2016, Volume 45, Issue 14, pp. 6275 - 6281
Four-membered Al/Ga-P ring systems were prepared by thermal hydrogen elimination between the primary silylphosphine H sub(2)PSitBuPh sub(2) and the metal... 
Metal hydrides | Gallium | Precursors | Stabilization | Aluminum | Hydrogen atoms | Lewis base | Carbenes
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 09/2013, Volume 2013, Issue 26, pp. 4645 - 4653
The cage compounds [E sub(2){(SiMe sub(2)) sub(2)O} sub(3)] for E = P, As, Sb, and Bi (1, 4, 5, and 6, respectively) are readily accessible in moderate yields... 
Lewis acid | Cage compounds | Parameters | Cage | Synthesis | Siloxanes | Mathematical models | Adducts
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 07/2015, Volume 2015, Issue 20, pp. 3264 - 3273
Journal Article
CHEMPHYSCHEM, ISSN 1439-4235, 10/2008, Volume 9, Issue 15, pp. 2252 - 2258
A series of oligophenylene rods of increasing lengths is synthesized to investigate the charge-transport mechanisms. Methyl groups are attached to the phenyl... 
CONDUCTANCE | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | CONFORMATION | ALKANETHIOL ANIONS | SINGLE MOLECULES | charge transport | JUNCTION | single-molecule studies | TRANSITION | molecular electronics | oligophenylenes | structure-functionality relationship | DERIVATIVES | ELECTRON-TRANSPORT
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2007, Volume 46, Issue 25, pp. 4775 - 4779
Modeled on organics: The inorganic cryptand [P2{O(SiiPr2)2}2{SiMe2(OSiMe2)2}] (see figure; C black, O orange, P red, Si blue) can be synthesized by a stepwise... 
weakly coordinating anions | silicon | cage compounds | cryptands | phosphorus | Cage compounds | Phosphorus | Cryptands | Silicon | Weakly coordinating anions | ANIONS | CRYSTAL-STRUCTURE | ION | CHEMISTRY, MULTIDISCIPLINARY | ELEMENTS | BASIS-SETS | CROWN-ETHERS | CLUSTER | BOND
Journal Article
European Archives of Psychiatry and Clinical Neuroscience, ISSN 0940-1334, 8/2015, Volume 265, Issue 5, pp. 419 - 428
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 10/2011, Volume 637, Issue 12, pp. 1777 - 1783
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 02/2012, Volume 638, Issue 2, pp. 383 - 386
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 08/2010, Volume 636, Issue 8, pp. 1522 - 1526
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 11/2009, Volume 635, Issue 13-14, pp. 2230 - 2235
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 01/2008, Volume 634, Issue 1, pp. 23 - 29
Journal Article
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