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Catalysis Communications, ISSN 1566-7367, 07/2015, Volume 70, pp. 6 - 11
ε-Caprolactam was synthesized directly from cyclohexanol via a tandem catalytic process using [n-C 16 H 33 N(CH 3 ) 3 ]H 2 PW 12 O 40 as a catalyst. The highly... 
Polyoxometalates | ε-Caprolactam | Direct synthesis | Cyclohexanol
Journal Article
AIChE Journal, ISSN 0001-1541, 10/2012, Volume 58, Issue 10, pp. 3156 - 3160
Journal Article
AIChE Journal, ISSN 0001-1541, 07/2014, Volume 60, Issue 7, pp. 2724 - 2730
The Beckmann rearrangement of cyclohexanone oxime in oleum as a fast exothermic reaction model is carried out in an adiabatic multiphase microchemical system.... 
gas | ε‐caprolactam | mass transfer | Beckmann rearrangement | microchemical system | Gas | ε-caprolactam | Microchemical system | Mass transfer | ENGINEERING, CHEMICAL | PHASE BECKMANN REARRANGEMENT | CYCLOHEXANONE OXIME | epsilon-caprolactam | DROPLET | Amplification | Coalescing | Agitation | Adiabatic flow | Exothermic reactions | Droplets | Selectivity | Dispersions
Journal Article
AIChE Journal, ISSN 0001-1541, 03/2012, Volume 58, Issue 3, pp. 925 - 931
A microstructured chemical system, constructed with a microsieve dispersion mixer, a delay loop and a microhydrolyzer is designed to carry out the Beckmann... 
selectivity | ϵ‐caprolactam | microstructured chemical system | Beckmann rearrangement | conversion | ε-caprolactam | Selectivity | Microstructured chemical system | Conversion
Journal Article
Journal of Molecular Catalysis A: Chemical, ISSN 1381-1169, 11/2012, Volume 363-364, pp. 41 - 48
The amorphous SiO -Al O supported Co O catalysts were prepared by impregnation method and characterized by SEM, BET, XRD, XPS, NH -TPD and FT-IR. The... 
ε-Caprolactam | catalyst | Cyclohexane | SiO | Al | Nitrosation | Preparation conditions
Journal Article
Polymer Chemistry, ISSN 1759-9954, 09/2015, Volume 6, Issue 35, pp. 6297 - 6304
Polyamide 6/SiO2 hybrid materials were produced by a coupled polymerization reaction of three monomeric components namely 1,1',1 '',1... 
NANOCOMPOSITES | POLYMER SCIENCE | GLASS-FIBER | ROUTES | BEHAVIOR | DEGRADATION | CRYSTAL | SILICA | MORPHOLOGICAL PROPERTIES | MECHANICAL-PROPERTIES | INORGANIC COMPOSITE-MATERIALS
Journal Article
Macromolecular Materials and Engineering, ISSN 1438-7492, 04/2016, Volume 301, Issue 4, pp. 423 - 428
Journal Article
Advanced Materials Research, ISSN 1022-6680, 08/2014, Volume 1015, pp. 463 - 466
Nylon 6/66 copolymer with 0-10wt% content of hexamethylene adipamide salt (AH-salt) was prepared by melt polycondensation. It was found that the comprehensive... 
ε-caprolactam | Melt polycondensation | Hexamethylene adipamide salt
Journal Article
Applied Catalysis B: Environmental, ISSN 0926-3373, 04/2015, Volume 165, pp. 87 - 93
•Caprolactam was synthesized via one-step liquid phase ammoximation and Beckmann rearrangement over Nb-MCM-41 catalysts.•The influence of temperature,... 
Cyclohexanoneoxime | Ammoximation | Nb-MCM-41 | ɛ-Caprolactam | Cyclohexanone | Beckmann rearrangement | ε-Caprolactam | NIOBIUM | epsilon-Caprolactam | AMMONIA | SELF-CONDENSATION | REACTIVITY | CHEMISTRY, PHYSICAL | MOLECULAR-SIEVES | ENGINEERING, CHEMICAL | KETONES | SPECTROSCOPY | ENGINEERING, ENVIRONMENTAL | OXIME | OXIDES | Heterogeneous catalysis | Reduction | Catalysts | Ethanol | Caprolactam | Ethyl alcohol | Silicon | Catalysis | Niobium
Journal Article
Polymers for Advanced Technologies, ISSN 1042-7147, 07/2015, Volume 26, Issue 7, pp. 851 - 854
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 10/2013, Volume 51, Issue 20, pp. 4474 - 4480
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 09/2013, Volume 54, Issue 38, pp. 5181 - 5184
Herein, we report the DBU ring opening reactions with imidazolide which can be a facile method to generate the library of ε-caprolactam derived carbamates and... 
Carbonyldiimidazole | Carbamates | Amides | ε-Caprolactam | DBU | MILD | KETONES | epsilon-Caprolactam | ANTICANCER AGENTS | BAYLIS-HILLMAN REACTION | CHEMISTRY, ORGANIC | ACCELERATED GREEN CHEMISTRY
Journal Article
Materials Letters, ISSN 0167-577X, 12/2014, Volume 136, pp. 388 - 392
The synthesis and use of plastic materials in several industrial areas has been increasing rapidly in the last century. Among the known plastics, the... 
Mechanical properties | Anionic polymerization | ε-Caprolactam | Synthesis | Sodium | Catalysts | Low pressure | Wear resistance | Conversion | Tensile strength
Journal Article
Chinese Journal of Catalysis, ISSN 1872-2067, 01/2017, Volume 38, Issue 1, pp. 58 - 64
Na2WO4-acidic ionic liquid was used as a simple, ecofriendly, recyclable and efficient catalytic system for the one-pot conversion of cyclohexanol to... 
One-pot synthesis | Acidic ionic liquid | ɛ-Caprolactam | Cyclohexanone oxime | Cyclohexanol | ε-Caprolactam
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 01/2014, Volume 52, Issue 1, pp. 96 - 103
ABSTRACT A 12‐membered cyclic diamide monomer for nylon 64 was successfully synthesized in fairly high yield (∼45%). The synthesis conditions were varied to... 
block copolymers | cyclic diamide | polyamides | cyclic lactams | macrocyclics | ε‐caprolactam | hydrolytic polymerization | anionic polymerization | ε-caprolactam | POLYMER SCIENCE | ACID | OMEGA-LAUROLACTAM | POLYMERIZATION | epsilon-caprolactam | LACTAMS | TRANSITIONS | NYLON-11 | Surface active agents | Polymerization | Block copolymers | Amides
Journal Article
AIChE Journal, ISSN 0001-1541, 06/2019, Volume 65, Issue 6, pp. e16603 - n/a
ε‐Caprolactam (CPL) is mainly produced through Beckmann rearrangement of cyclohexanone oxime catalyzed by oleum in industry nowadays, which suffers the... 
mixed acids | trifluoroacetic acid | ε‐caprolactam | oleum | Beckmann rearrangement | ENGINEERING, CHEMICAL | EFFICIENT CATALYST | CAPROLACTAM | TRIFLUOROACETIC-ACID | HETEROGENEOUS CATALYST | epsilon-caprolactam | Analysis | Sulfuric acid | Viscosity | Parameters | Cyclohexanone | Acids | Trifluoroacetic acid | Caprolactam | Sulfur trioxide | Selectivity | Catalysis | Heat transfer
Journal Article