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1,1,3,3-tetramethyldisiloxane (24) 24
chemistry, organic (14) 14
hydrosilylation (12) 12
reduction (11) 11
catalysis (6) 6
organic chemistry (6) 6
complexes (5) 5
chemical sciences (4) 4
chemistry (4) 4
chemistry, inorganic & nuclear (4) 4
chemistry, multidisciplinary (4) 4
cycloaddition (4) 4
1,3-bis-1,1,3,3-tetramethyldisiloxane (3) 3
activation (3) 3
aldehydes (3) 3
alkynes (3) 3
bonds (3) 3
chemoselective reduction (3) 3
conversion (3) 3
cross-linking (3) 3
derivatives (3) 3
ethers (3) 3
gold nanoparticles (3) 3
homogeneous catalysis (3) 3
hydrosilanes (3) 3
organic-synthesis (3) 3
poly (3) 3
selective hydrosilylation (3) 3
selective reduction (3) 3
silicon (3) 3
siloxanes (3) 3
terminal alkynes (3) 3
1,1,3,3‐tetramethyldisiloxane (2) 2
3-tetramethyldisiloxane (2) 2
adducts (2) 2
alkylation (2) 2
brønsted acid (2) 2
carbonyl compounds (2) 2
carbonyl-compounds (2) 2
carboxylic acids (2) 2
catalysts (2) 2
catalytic-activity (2) 2
chemistry, physical (2) 2
dehydrogenation (2) 2
double silylation (2) 2
efficient (2) 2
functionalization (2) 2
gold (2) 2
hydrosilation (2) 2
ketones (2) 2
mechanism (2) 2
nanoparticles (2) 2
nanoporous gold catalyst (2) 2
nitriles (2) 2
olefins (2) 2
platinum (2) 2
polybutadiene (2) 2
semihydrogenation (2) 2
tio2 (2) 2
triphenylphosphine oxide (2) 2
vanadium (2) 2
1 2 4-triazole (1) 1
1 3-bis-1 1 3 3-tetramethyldisiloxane (1) 1
1 h -benzotriazole (1) 1
1,1,3,3-tetramethyidisiloxane (1) 1
1,2,4 - triazole (1) 1
1,2,4-triazole (1) 1
1,2,4-triazoles derivatives (1) 1
1,3,4-oxadiazoles (1) 1
1,4-disilacyclohexa-2,5-dienes (1) 1
1,9-decadiene (1) 1
1h-benzotriazole (1) 1
3-amino-1 2 4-triazole (1) 1
3-amino-1,2,4-triazole (1) 1
4,6-o-benzylidene acetals (1) 1
4-vinyl-1,2-epoxycyclohexane (1) 1
[chim.orga]chemical sciences/organic chemistry (1) 1
acetal (1) 1
acetals (1) 1
acid (1) 1
acids (1) 1
additions (1) 1
additiv (1) 1
additive (1) 1
alcohol (1) 1
alcohols (1) 1
aliphatic compounds (1) 1
aliphatic methanesulfonates (1) 1
alkene (1) 1
alkenes (1) 1
alkoxysilan (1) 1
alkoxysilane (1) 1
alkylidene (1) 1
allen (1) 1
allene (1) 1
allenes (1) 1
allyl chloride (1) 1
allyl ethers (1) 1
amides (1) 1
amination (1) 1
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Organic Letters, ISSN 1523-7060, 09/2015, Volume 17, Issue 18, pp. 4538 - 4541
The first example of Au-catalyzed hydrosilylation of allenes is presented using recyclable gold nanoparticles as catalyst, without the requirement of any... 
ORGANIC-SYNTHESIS | CYCLOADDITION | ACTIVATION | COMPLEXES | BONDS | SYN-INSERTION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | 1,1,3,3-TETRAMETHYLDISILOXANE | SELECTIVE HYDROSILYLATION | DERIVATIVES
Journal Article
Organic Letters, ISSN 1523-7060, 07/2018, Volume 20, Issue 13, pp. 4086 - 4089
Supported Au nanoparticles on TiO2 catalyze the insertion of carbenes from α-diazocabonyl compounds into hydrosilanes. It is proposed that the transformation... 
HYDROGENATION | MECHANISM | BONDS | HYDROSILYLATION | DIAZO ESTERS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | NANOPOROUS GOLD CATALYST | 1,1,3,3-TETRAMETHYLDISILOXANE | ALKYNES | SI-H INSERTION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2019, Volume 25, Issue 39, pp. 9170 - 9173
Journal Article
Journal of Catalysis, ISSN 0021-9517, 03/2019, Volume 371, pp. 27 - 34
[Display omitted] •TM-catalyzed hydrosilylation of polybutadiene was studied.•Complex [{Rh(µ-Cl)(COD)}2] proved to be the most active catalyst in that... 
Polymer functionalization | Rubber | In-situ FT-IR | Homogeneous catalysis | Dehydrogenative silylation | DIENE-BASED POLYMERS | COMPLEXES | CROSS-LINKING | CHEMISTRY, PHYSICAL | COPOLYMERS | FUNCTIONALIZATION | ENGINEERING, CHEMICAL | 1,1,3,3-TETRAMETHYLDISILOXANE | DERIVATIVES | Silicon | Catalysis | Chemical tests and reagents | Analysis | Elastomers
Journal Article
ARKIVOC, ISSN 1551-7004, 2015, pp. 38 - 51
Gold nanoparticles supported on TiO2 (1 mol%) catalyze the reduction of a series of functionalized quinolines into 1,2,3,4-tetrahydroquinolines using... 
ACTIVATION | ACID | gold nanoparticles | HYDROSILYLATION | CHEMISTRY, ORGANIC | hydrosilanes | ALKYNES | NITROARENES | NABH4 | CHEMOSELECTIVE HYDROGENATION | 1,1,3,3-TETRAMETHYLDISILOXANE | Catalysis | reduction | quinolines | TIO2 | SEMIHYDROGENATION
Journal Article
European Journal of Lipid Science and Technology, ISSN 1438-7697, 01/2014, Volume 116, Issue 1, pp. 74 - 79
“High oleic” sunflower oil was converted into the respective triether using InBr3 or GaBr3 as catalysts and triethylsilane or 1,1,3,3‐tetramethyldisiloxane... 
Renewable | InBr3 | High oleic sunflower oil | Triglycerides | GaBr3 | Glyceryl triether | 1,1,3,3‐tetramethyldisiloxane | 1,1,3,3-tetramethyldisiloxane | ALIPHATIC METHANESULFONATES | CONVERSION | CATALYTIC-SYSTEM | ALKYLATION | FOOD SCIENCE & TECHNOLOGY | 3-tetramethyldisiloxane | NUTRITION & DIETETICS | LACTONES | ESTERS | CARBOXYLIC-ACIDS | Oils & fats
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2010, Volume 51, Issue 15, pp. 1939 - 1941
An efficient reduction of the nitro group with a catalytic amount of Fe(acac) 3 and TMDS in THF at 60 °C affording the corresponding amine is described. 
1,1,3,3-Tetramethyldisiloxane | Reduction | Nitro | Iron catalyst | Amines | AMINATION | HYDROSILYLATION | COMPLEXES | CHEMISTRY, ORGANIC | Nitro compounds | Organic chemistry | Chemical Sciences
Journal Article
NEW JOURNAL OF CHEMISTRY, ISSN 1144-0546, 12/2019, Volume 43, Issue 46, pp. 18141 - 18145
In this paper, an efficient method for the preparation of new silsesquioxanes with mixed functional groups of general formula... 
SPHEROSILICATES | HYDROSILYLATION | CROSS-LINKING | NANOSCALE | 1,1,3,3-TETRAMETHYLDISILOXANE | SILOXIDE COMPLEXES | CATALYTIC-ACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | HYBRID | CUBIC SILSESQUIOXANES | POSS DERIVATIVES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2014, Volume 55, Issue 1, pp. 23 - 26
A simple and convenient method for the chemoselective reduction of nitriles into aldehydes using a 1,1,3,3-tetramethyldisiloxane... 
1,1,3,3-Tetramethyldisiloxane (TMDS) | Nitriles | Reduction | Aldehydes | Vanadium | Organic chemistry | Chemical Sciences
Journal Article
Organometallics, ISSN 0276-7333, 04/2015, Volume 34, Issue 8, pp. 1597 - 1600
The Au/TiO2-catalyzed reaction between 1,1,2,2-tetramethyldisilane and terminal alkynes yields substituted 1,4-disila-2,5-cyclohexadienes... 
DOUBLE SILYLATION | CYCLOADDITION | 1,4-DISILACYCLOHEXA-2,5-DIENES | CYCLIC CROSS-HYPERCONJUGATION | HYDROSILYLATION | COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | 1,1,3,3-TETRAMETHYLDISILOXANE | CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 10/2018, Volume 872, pp. 73 - 78
In this paper, we propose an efficient method for the synthesis of new organosilicon compounds based on hydrosilylation of functional olefins with monohydrido... 
Organosilicon | Silsesquioxanes | Hydrosilylation | Siloxanes | Homogeneous catalysis | POLYMERS | POLYHEDRAL OLIGOSILSESQUIOXANE | CROSS-LINKING | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | FUNCTIONALIZATION | NANOCOMPOSITES | SILICONE-RUBBER | OLIGOMERIC SILSESQUIOXANE POSS | 1,1,3,3-TETRAMETHYLDISILOXANE | CATALYTIC-ACTIVITY | DERIVATIVES | Catalysis
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 08/2017, Volume 643, Issue 14, pp. 916 - 921
Recently, Brønsted acids, such as phosphoric acids, carboxylic acids, and triflic acid, were found to catalyze the reduction of phosphine oxides to the... 
Reduction | Triphenylphosphine oxide | Brønsted acid | 1,1,3,3-Tetramethyldisiloxane | Inorganic Chemistry | Poly(methylhydrosiloxane)
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2014, Volume 70, Issue 36, pp. 6106 - 6113
1,1,3,3-Tetramethyldisiloxane (TMDS) is a highly reactive reducing reagent in the Au/TiO2-catalyzed hydrosilylation of carbonyl compounds relative to... 
Carbonyl compounds | Heterogeneous catalysis | 1,1,3,3-Tetramethyldisiloxane | Hydrosilylation | Gold nanoparticles | ACTIVATION | PALLADIUM COMPLEXES | HYDROSILANES | CHEMISTRY, ORGANIC | SELECTIVE HYDROSILYLATION | KETONES | CYCLOADDITION | REDUCTION | ORGANOSILANES
Journal Article
ChemCatChem, ISSN 1867-3880, 03/2018, Volume 10, Issue 5, pp. 980 - 983
In contrast to monohydrosilanes (R3SiH), which in the presence of supported gold nanoparticles primarily undergo typical β‐(E)‐hydrosilylation reactions with... 
gold nanoparticles | dehydrogenative disilylation | alkynes | dihydrosilanes | ORGANIC-SYNTHESIS | TRANSITION-METAL-COMPLEXES | HYDROSILANES | CHEMISTRY, PHYSICAL | CARBONYL-COMPOUNDS | TERMINAL ALKYNES | SELECTIVE HYDROSILYLATION | ELEMENT-ELEMENT ADDITIONS | BONDS | 1,1,3,3-TETRAMETHYLDISILOXANE | SEMIHYDROGENATION | Nanoparticles | Catalysis
Journal Article
TETRAHEDRON LETTERS, ISSN 0040-4039, 01/2014, Volume 55, Issue 1, pp. 23 - 26
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2011, Volume 52, Issue 12, pp. 1281 - 1283
A simple and practical procedure for the reduction of acetals to ethers is described. It is based on the use of a 1,1,3,3-tetramethyldisiloxane (TMDS)–Pd/C... 
1,1,3,3-Tetramethyldisiloxane (TMDS) | Acetal | Reduction | Pd/C | 4,6-O-BENZYLIDENE ACETALS | CHEMISTRY, ORGANIC | SELECTIVE REDUCTION | EFFICIENT | Tetrahedrons | Ethers | Acetals
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2010, Volume 51, Issue 16, pp. 2092 - 2094
A mild method for the reduction of amides to aldehydes using 1,1,3,3-tetramethyldisiloxane/titanium(IV) isopropoxide reducing system is described. The reaction... 
Titanium | Amides | 1,1,3,3-Tetramethyldisiloxane | Reduction | Aldehydes | PRIMARY CARBOXAMIDES | KETONES | CONVERSION | HYDRIDES | TERTIARY AMIDES | CHEMISTRY, ORGANIC | SELECTIVE REDUCTION | Organic chemistry | Chemical Sciences
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 08/2017, Volume 643, Issue 14, pp. 916 - 921
Recently, Brønsted acids, such as phosphoric acids, carboxylic acids, and triflic acid, were found to catalyze the reduction of phosphine oxides to the... 
Brønsted acid | 1,1,3,3-Tetramethyldisiloxane | Reduction | Poly(methylhydrosiloxane) | Triphenylphosphine oxide | 1,1,3,3‐Tetramethyldisiloxane | CATALYTIC WITTIG REACTION | ROOM-TEMPERATURE | Bronsted acid | MOLECULAR-STRUCTURE | SECONDARY | CRYSTAL | BORANES | CHEMISTRY, INORGANIC & NUCLEAR | ZU PHOSPHINEN
Journal Article
Russian Journal of Organic Chemistry, ISSN 1070-4280, 9/2018, Volume 54, Issue 9, pp. 1383 - 1388
The major and minor products of the reaction of imidazole with bis(iodomethyl)tetramethyldisiloxane have been identified, and their main fragmentation pathways... 
Chemistry | Organic Chemistry | SOLAR-CELLS | 1,3-BIS(IODOMETHYL)-1,1,3,3-TETRAMETHYLDISILOXANE | MECHANISM | DESORPTION/IONIZATION | SILICON | CHEMISTRY, ORGANIC | BENZIMIDAZOLE FRAGMENT | SILANONES | SILOXANES
Journal Article
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