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1,1,3-triaryl-2-azaallyl anions (22) 22
regioselective arylation (13) 13
chemistry, organic (10) 10
article (9) 9
chemistry, multidisciplinary (9) 9
catalyzed regioselective arylation (8) 8
catalysis (7) 7
derivatives (7) 7
index medicus (7) 7
aryl chlorides (5) 5
c-h arylation (5) 5
anions (4) 4
enantioselective synthesis (4) 4
imines (4) 4
palladium (4) 4
allylic alkylation (3) 3
alpha-arylation (3) 3
anion (3) 3
aromatic compounds (3) 3
arylation (3) 3
arylierung (3) 3
asymmetric-synthesis (3) 3
bromides (3) 3
chemical synthesis (3) 3
chemistry, applied (3) 3
coupling (3) 3
decarboxylative generation (3) 3
halides (3) 3
ketones (3) 3
molecular structure (3) 3
palladium - chemistry (3) 3
photoredox catalysis (3) 3
stereoselective-synthesis (3) 3
synthesis (3) 3
umpolung (3) 3
2-aminopyrimidines (2) 2
activation (2) 2
alkynes (2) 2
allylation (2) 2
amines (2) 2
amino-acids (2) 2
aza compounds - chemistry (2) 2
aza-cope rearrangement (2) 2
biomimetic transamination (2) 2
bond functionalization (2) 2
bond-forming reactions (2) 2
bonding (2) 2
bonds (2) 2
bronsted acid (2) 2
c-h functionalization (2) 2
carbodiimide (2) 2
cascade annulation (2) 2
catalysts (2) 2
chemical properties (2) 2
chemical reactions (2) 2
conjugate addition (2) 2
cross-couplings (2) 2
diaryliodonium salts (2) 2
diarylmethanes (2) 2
direct alpha-arylation (2) 2
direct beta-arylation (2) 2
directing groups (2) 2
electrons (2) 2
esters (2) 2
ethers - chemistry (2) 2
functionalisation (2) 2
funktionalisierung (2) 2
hydrogen shift (2) 2
iridium (2) 2
methyl sulfones (2) 2
multidisciplinary sciences (2) 2
one-pot synthesis (2) 2
organic-synthesis (2) 2
palladium catalysts (2) 2
phase-transfer catalyst (2) 2
pyridines - chemical synthesis (2) 2
pyridines - chemistry (2) 2
reductive elimination (2) 2
relay catalysis (2) 2
site-selective sp (2) 2
α-arylation (2) 2
2-azaallyl (1) 1
2-azaallyl anion (1) 1
2‐azaallyl anion (1) 1
acetat (1) 1
acetates (1) 1
acid (1) 1
acid derivatives (1) 1
aerobic oxidation (1) 1
albumin (1) 1
alkenes (1) 1
alkylation (1) 1
alkylierung (1) 1
all-cis (1) 1
allyl compounds (1) 1
allyl diphenylglycinate imines (1) 1
allylic amination reactions (1) 1
allylierung (1) 1
alpha,beta-diamino acids (1) 1
alpha-allylation (1) 1
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Organic Letters, ISSN 1523-7060, 05/2015, Volume 17, Issue 9, pp. 2042 - 2045
Condensation between the tetrabutylammonium salt of 2,2-diphenylglycine and aldehydes results in a decarboxylative Erlenmeyer reaction, affording... 
CATALYZED REGIOSELECTIVE ARYLATION | ALLYL DIPHENYLGLYCINATE IMINES | 1,1,3-TRIARYL-2-AZAALLYL ANIONS | STABILIZED AZOMETHINE YLIDES | HOMOALLYLIC AMINES | SCHIFF-BASES | ESTERS | AMINATIVE UMPOLUNG | CHEMISTRY, ORGANIC | VICINAL DIAMINES | STEREOSELECTIVE 1,3-DIPOLAR CYCLOADDITION
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 17, pp. 5423 - 5426
A highly regioselective and diastereoselective addition of 2-azaallyl anions to N-tert-butanesulfinylimines is reported. This methodology affords the... 
CATALYZED REGIOSELECTIVE ARYLATION | 1,1,3-TRIARYL-2-AZAALLYL ANIONS | TERT-BUTANESULFINYL IMINES | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | AMINO-ACIDS | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | ALPHA,BETA-DIAMINO ACIDS | DERIVATIVES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 06/2016, Volume 358, Issue 12, pp. 1910 - 1915
An umpolung synthesis of diarylmethylamine derivatives is presented. This reaction entails a palladium‐catalyzed arylation of 1,3‐diaryl‐2‐azaallyl anions, in... 
regioselectivity | 2‐azaallyl anion | diarylmethylamines | NIXANTPHOS | umpolung | 2-azaallyl anion | DIARYLMETHANES | IMINES | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | REGIOSELECTIVE ARYLATION | 1,1,3-TRIARYL-2-AZAALLYL ANIONS | CHEMISTRY, APPLIED | AMINE DERIVATIVES | Palladium catalysts | Isomerization | Palladium | Anions | Synthesis | Gloves | Aromatic compounds | Coupling | Derivatives | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 40, pp. 13103 - 13106
Here we report an iridium-catalyzed asymmetric umpolung allylation of imines as a general approach to prepare 1,4-disubstituted homoallylic amines, a... 
1,1,3-TRIARYL-2-AZAALLYL ANIONS | VINYLOGOUS MANNICH REACTION | CARBON | ACID | AZA-COPE REARRANGEMENT | BOND-FORMING REACTIONS | ALLYLIC ALKYLATION | REGIOSELECTIVE ARYLATION | AMINOALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | DECARBOXYLATIVE GENERATION | Schiff bases | Usage | Amines | Chemical properties | Iridium | Chemical compounds
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 02/2017, Volume 53, Issue 12, pp. 1985 - 1988
A novel Ir/PTC (phase-transfer catalyst) cooperatively catalyzed asymmetric umpolung allylation of simple α-imino esters is developed and it provides facile... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 12, pp. 1985 - 1988
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 02/2018, Volume 115, Issue 8, pp. 1730 - 1735
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2018, Volume 54, Issue 84, pp. 11881 - 11884
In the past years, the activations of aromatic nitriles for radical arylations under photoirradiation have been developed. We here report the first example of... 
CATALYZED REGIOSELECTIVE ARYLATION | 1,1,3-TRIARYL-2-AZAALLYL ANIONS | C(SP)-H BONDS | ORGANIC ELECTRON-DONORS | BISPYRIDINYLIDENE | C-H ARYLATION | REDUCTION | INHIBITORS | CHEMISTRY, MULTIDISCIPLINARY | RADICAL REACTIONS | PHOTOREDOX CATALYSIS
Journal Article
Synlett, ISSN 0936-5214, 2017, Volume 28, Issue 16, pp. 2051 - 2056
The discovery and development of an Ir-catalyzed asymmetric umpolung allylation of imines is discussed here. This method produces 1,4-disubstituted homoallylic... 
enantioselectivity | iridium | allylation | imine | umpolung | TRANSITION-METAL CATALYSIS | ENANTIOSELECTIVE SYNTHESIS | AZA-COPE REARRANGEMENT | BOND-FORMING REACTIONS | CHEMISTRY, ORGANIC | ALLYLIC AMINATION REACTIONS | CHIRAL PHOSPHORIC-ACID | INTRAMOLECULAR DEAROMATIZATION | DECARBOXYLATIVE GENERATION | 1,1,3-TRIARYL-2-AZAALLYL ANIONS | ALPHA-ALLYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 12/2015, Volume 17, Issue 23, pp. 5788 - 5791
A direct C–H functionalization approach to produce aryl­(azaaryl)­methylamines from azaarylmethylamines without directing groups is described. Under conditions... 
HALIDES | 1,1,3-TRIARYL-2-AZAALLYL ANIONS | CROSS-COUPLINGS | CHEMISTRY, ORGANIC | SITE-SELECTIVE SP | REGIOSELECTIVE ARYLATION | C(SP)-H ARYLATION | BROMIDES | ARYL CHLORIDES | SUBSTITUTED PYRIDINES | DIRECT ALPHA-ARYLATION | Aza Compounds - chemistry | Methylamines - chemical synthesis | Molecular Structure | Catalysis | Methylamines - chemistry | Palladium - chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 05/2016, Volume 18, Issue 10, pp. 2371 - 2374
Journal Article