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Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 44, pp. 14570 - 14574
The β‐borylborole 3 adds phenylacetylene in a [4+2]‐cycloaddition to give the boryl‐substituted 7‐boranorbornadiene derivative 4 b. Thermolysis (60 °C) results... 
1,1-carboboration | tetraaryldiboranes | 1,1-diboration | borole | RING EXPANSION | B-B SINGLE | UNSYMMETRICAL DIBORANE | 1,1-CARBOBORATION ROUTE | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | LEWIS-PAIR | DIBORON TETRACHLORIDE | CHEMISTRY | METAL-FREE DIBORATION | CATALYZED DIBORATION | Pyrolysis | Acetylene | Substitutes | Diborane | Cycloaddition | Phenylacetylene
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