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1,2-alkyl migration (12) 12
chemistry, organic (9) 9
chemistry, multidisciplinary (6) 6
efficient synthesis (6) 6
gold (5) 5
catalysis (4) 4
cyclization (4) 4
ketones (4) 4
migration (4) 4
chemistry (3) 3
domino reactions (3) 3
highly substituted furans (3) 3
1,2-indole migrations (2) 2
1,2-migration (2) 2
4+2 benzannulation (2) 2
alder reactions (2) 2
alkaloids (2) 2
aromatic compounds (2) 2
cascade reactions (2) 2
catalyzed hydrative carbocyclization (2) 2
chemical reactions (2) 2
cyclization/oxidative cleavage reactions (2) 2
cycloisomerization (2) 2
derivatives (2) 2
divergent synthesis (2) 2
gold catalysis (2) 2
heterocycles (2) 2
molecular complexity (2) 2
naphthyl ketone derivatives (2) 2
o-alkynylbenzaldehydes (2) 2
one-pot synthesis (2) 2
química orgánica (2) 2
rearrangement (2) 2
selective 1,2-alkyl (2) 2
semipinacol rearrangement (2) 2
skeletal rearrangement (2) 2
tandem reactions (2) 2
1 2-alkyl migration (1) 1
1,2-alkyl shift (1) 1
1,2-alkyl shifts (1) 1
1,2‐alkyl migration (1) 1
1,2‐alkyl shift (1) 1
1,2‐alkyl shifts (1) 1
1,3-dipolar cycloaddition (1) 1
1-2-alkyl shift (1) 1
1-cyclobutanols (1) 1
1-cyclopropyl ketones (1) 1
2-alkyl shift (1) 1
2-iodocarbazoles (1) 1
2-norbornyl cation (1) 1
2‐iodocarbazoles (1) 1
3-silyloxy-1,5-enynes (1) 1
7-norbornyl cation (1) 1
9-alkyl-9-bbn derivatives (1) 1
access (1) 1
acetal (1) 1
acetals (1) 1
acid-mediated cycloaddition (1) 1
activation (1) 1
active carbazole alkaloids (1) 1
agents (1) 1
alkyl migration (1) 1
alkyne pi-activation (1) 1
alkynes (1) 1
alkynes - chemistry (1) 1
alpha,beta-epoxy ketones (1) 1
annulation (1) 1
aromatic enynes (1) 1
asymmetric-synthesis (1) 1
benzaldehyd (1) 1
benzaldehyde (1) 1
benzannulation (1) 1
benzene derivatives - chemical synthesis (1) 1
benzene derivatives - chemistry (1) 1
benzeneselenyl bromide (1) 1
benzo[b]carbazoles (1) 1
bonding (1) 1
boron (1) 1
bronsted acid catalysis (1) 1
brønsted acid catalysis (1) 1
c-c bond cleavage (1) 1
cannabimimetic indoles (1) 1
carbazol (1) 1
carbazole (1) 1
carbazole synthesis (1) 1
carbocations (1) 1
carbon (1) 1
cascade chemical reactions (1) 1
chemical synthesis (1) 1
chemistry, applied (1) 1
chiral dirhodium carboxylates (1) 1
cleavage (1) 1
coupling (1) 1
cross-coupling (1) 1
cross-coupling reaction (1) 1
cross-coupling reactions (1) 1
cross‐coupling (1) 1
crystal-structure (1) 1
cutting (1) 1
cyclisation (1) 1
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Chemistry – A European Journal, ISSN 0947-6539, 11/2012, Volume 18, Issue 47, pp. 15113 - 15121
A series of 2‐alkynyl carbonyl compounds that contain a cyclopentene ring or a heterocycle can be transformed into various fused dihydrobenzofurans and... 
gold | regioselectivity | ketones | tandem reactions | alkyl migration | TRANSITION-METAL CATALYSIS | CASCADE REACTIONS | EXPEDITIOUS ACCESS | HOMOGENEOUS GOLD CATALYSIS | EFFICIENT SYNTHESIS | DIVERGENT SYNTHESIS | SKELETAL REARRANGEMENT | CHEMISTRY, MULTIDISCIPLINARY | PINACOL REARRANGEMENT | MECHANISTIC INSIGHTS | 1,2-ALKYL MIGRATION | Migration
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2017, Volume 23, Issue 28, pp. 6845 - 6852
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 7/2016, Volume 14, Issue 28, pp. 6651 - 6671
Gold catalysed synthesis of carbo-/hetero-cyclic compounds is currently a topic of intense activity thanks to the unique properties bestowed upon gold by... 
CATALYZED HYDRATIVE CARBOCYCLIZATION | NAPHTHYL KETONE DERIVATIVES | 4+2 BENZANNULATION | CYCLIZATION/OXIDATIVE CLEAVAGE REACTIONS | ONE-POT SYNTHESIS | ALDER REACTIONS | O-ALKYNYLBENZALDEHYDES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | 1,2-ALKYL MIGRATION | HIGHLY SUBSTITUTED FURANS
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 07/2016, Volume 14, Issue 28, pp. 6651 - 6671
Gold catalysed synthesis of carbo-/hetero-cyclic compounds is currently a topic of intense activity thanks to the unique properties bestowed upon gold by... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2011, Volume 17, Issue 1, pp. 86 - 90
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2014, Volume 356, Issue 2‐3, pp. 374 - 382
Journal Article
Israel Journal of Chemistry, ISSN 0021-2148, 11/2013, Volume 53, Issue 11‐12, pp. 911 - 914
A formal gold(I)‐catalyzed diastereoselective [4+3] cycloaddition of oxime ethers with imines, consisting of 1,2‐alkyl migration under mild reaction... 
gold | diastereoselectivity | domino reactions | heterocycles | 1,2‐alkyl migration | Gold | Heterocycles | Domino reactions | 1 2-alkyl migration | Diastereoselectivity | POLYMERS | 1,2-alkyl migration | TANDEM | EFFICIENT SYNTHESIS | CANNABIMIMETIC INDOLES | PYRROLES | CHEMISTRY, MULTIDISCIPLINARY | PYRROLIDINE | CHEMISTRY | SYSTEMS | ALKALOIDS
Journal Article
Synthetic Communications, ISSN 0039-7911, 09/2019, Volume 49, Issue 17, pp. 2203 - 2209
A simple and practical strategy to access β-selenated cyclic ketone derivatives through the catalyst-free selenylation and semipinacol rearrangement sequence... 
selenylation | 1,2-Alkyl migration | semipinacol rearrangement | benzeneselenyl bromide | 1-(1-arylvinyl)cyclobutanols | ELECTROPHILIC CYCLIZATION | ASYMMETRIC-SYNTHESIS | RING EXPANSION | VISIBLE-LIGHT PHOTOREDOX | CHEMISTRY, ORGANIC | SELENIDES | MIGRATION SEQUENCES | TETRAHYDROQUINOLINES | KETO ACIDS | STEREOSELECTIVE-SYNTHESIS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2016, Volume 57, Issue 52, pp. 5896 - 5898
[Display omitted] •A practically usable synthetic method for pyrrolinones was established.•Acid promoted dimerization of 3-amino-2-butenamides efficiently... 
1,2-Migration | Enamide | Oxidation | Pyrrolinones | Dimerization | DESIGN | REACTIVITY | CHEMISTRY, ORGANIC | VICINAL TRICARBONYLS | PROTEASE INHIBITORS | MILD CONDITIONS | CHEMISTRY | AGENTS | SUBSTITUTED PYRROLIN-4-ONES | 1,2-ALKYL MIGRATION | CYCLIZATION
Journal Article
Heterocycles, ISSN 0385-5414, 2011, Volume 83, Issue 2, pp. 247 - 273
This account deals with our investigation of the reaction and synthetic use of indolylborates as versatile synthetic tools; 1) palladium-catalyzed... 
KETONES | Intramolecular Alkyl Migration | Boron | Indole Alkaloid | Indolylborate | OLIVACINE | Cross-Coupling Reaction | CHEMISTRY, ORGANIC | 1,2-ALKYL MIGRATION | ACCESS | 9-ALKYL-9-BBN DERIVATIVES
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 1/1995, Volume 68, Issue 1, pp. 289 - 296
α-Ethylidenecycloalkanones underwent a ring enlargement to β-alkylidenecycloalkanones upon a treatment with trimethylstannyllithium/aldehyde equivalents/Lewis... 
KETONES | GAMMA-STANNYL ALCOHOLS | SUBSTITUTION PATTERN | CYCLOPROPANATION | TRIALKYLSTANNYLMETHYLLITHIUM | CHEMISTRY, MULTIDISCIPLINARY | 1,2-ALKYL MIGRATION | DEPENDENCE
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 11/2019, Volume 2019, Issue 41, pp. 6983 - 6988
Regioselective benzannulation reaction of indol‐3‐yl‐but‐3‐yn‐2‐ols to functionaly embellished 2‐iodocarbazoles is described for the first time using iodine at... 
Benzannulation | Reaction mechanisms | Cross‐coupling | Iodocyclization | 2‐Iodocarbazoles | 2-Iodocarbazoles | HOLE-TRANSPORTING MATERIALS | ANNULATION | CHEMISTRY, ORGANIC | PROPARGYL ALCOHOLS | INDOLES | CROSS-COUPLING REACTIONS | Cross-coupling | FACILE SYNTHESIS | CARBAZOLE SYNTHESIS | SELECTIVE 1,2-ALKYL | CYCLIZATION | ALKALOIDS
Journal Article
ORGANIC CHEMISTRY FRONTIERS, ISSN 2052-4129, 04/2020, Volume 7, Issue 8, pp. 997 - 1005
Indole is a very common structural motif in alkaloids, and a number of them feature remarkable bioactive properties. Due to its relevant role in medicinal... 
DIVERGENT SYNTHESIS | CHEMISTRY, ORGANIC | CYCLOISOMERIZATION | STEP | SELECTIVE 1,2-ALKYL
Journal Article