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1,3,2,5-diazadiborinine (7) 7
chemistry, multidisciplinary (6) 6
boron (5) 5
reactivity (5) 5
anions (3) 3
oxidation (3) 3
activation (2) 2
bor (2) 2
boron-compounds (2) 2
borverbindung (2) 2
chemisches reaktionsvermögen (2) 2
chemistry (2) 2
complexes (2) 2
cycloaddition (2) 2
density-functional-theory (2) 2
derivatives (2) 2
diborane (2) 2
dihydrogen (2) 2
electrons (2) 2
elektron (2) 2
iron (2) 2
nitrogen (2) 2
oxidation-reaction (2) 2
phosphane (2) 2
radical-anion (2) 2
reduction (2) 2
adduct (1) 1
adduct equilibrium (1) 1
alanes (1) 1
ammonia (1) 1
anion (1) 1
anionic dimetalloborylene complex (1) 1
aromaticity (1) 1
arylborane (1) 1
bond (1) 1
borane (1) 1
boron-stabilized carbanion (1) 1
boryl anion (1) 1
c-h bonds (1) 1
carbenes (1) 1
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chemical properties (1) 1
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chemistry, organic (1) 1
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density functional calculations (1) 1
density functional theory (1) 1
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dft-calculation (1) 1
dichalcogen activation (1) 1
dichtefunktionaltheorie (1) 1
dichtefunktionstheorie (1) 1
dimers (1) 1
dimetalloborylene complex (1) 1
divalent germanium (1) 1
eisen (1) 1
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electronic structure (1) 1
elements (1) 1
ethylene (1) 1
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isocyanides (1) 1
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kohlenstoffkomplex (1) 1
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Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 1, pp. 436 - 440
An electron‐rich monovalent boron compound is used as a Lewis base to prepare adducts with Group 13 Lewis acids using both its boron and nitrogen sites. The... 
Lewis adducts | alanes | gallanes | boron | dative bonding | COMPLEXES | REACTIVITY | COORDINATION | TERPHENYL | ADDUCT | 1,3,2,5-DIAZADIBORININE | CHEMISTRY, MULTIDISCIPLINARY | REDUCTION | CHEMISTRY | RADICAL-ANION | DERIVATIVES | Nitrogen
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2019, Volume 25, Issue 4, pp. 1098 - 1105
The synthesis of the germacalicene 7 from the reaction of the dipotassium germole dianion K2[6] with 1,2‐bis‐diisopropylamino‐3‐chlorocyclopropenyl perchlorate... 
X-ray diffraction | density functional calculations | ylides | germanium | transition metals | ACTIVATION | COMPLEXES | GERMYLENE | SILENES | 1,3,2,5-DIAZADIBORININE | CHEMISTRY, MULTIDISCIPLINARY | ELEMENTS | CYCLOADDITION | AROMATICITY | DIVALENT GERMANIUM | LONE-PAIR | Perchlorate | Anions | Perchloric acid | Crystals | Oxidation | Iron | Dimers | Cations | Chemical synthesis | Crystal structure | Carbonyls | Structural analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2017, Volume 139, Issue 32, pp. 11032 - 11035
The multielectron reduction of small molecules (e.g., CO2) is a key aspect of fuel synthesis from renewable electricity. Transition metals have been researched... 
OXIDATION | CYCLOADDITION | BORON | RADICAL-CATION | GRAPHENE | BOND | 1,3,2,5-DIAZADIBORININE | CENTERS | MAIN-GROUP ELEMENTS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Usage | Chemical properties | Ring formation (Chemistry) | Carbenes | Ethylene
Journal Article
by Su, YT and Li, YX and Ganguly, R and Kinjo, R
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 06/2018, Volume 57, Issue 26, pp. 7846 - 7849
An annulated 1,3,2,5-diazadiborinine with 14 pi electrons has been synthesized and fully characterized. Experimental and computational studies revealed that... 
N-HETEROCYCLIC CARBENE | AMMONIA | REACTIVITY | 1,3,2,5-DIAZADIBORININE | CHEMISTRY, MULTIDISCIPLINARY | main group chemistry | small-molecule activation | DIBORANE | FRUSTRATED LEWIS PAIR | HYDROGEN | isocyanides | DIHYDROGEN | electronic structure | CHEMISTRY | boron
Journal Article
Tetrahedron, ISSN 0040-4020, 2019, Volume 75, Issue 1, pp. 26 - 30
The 9,10-dimethyl-9,10-dihydro-9,10-diboraanthracene dianion salt Li2[1] instantaneously reacts with the dichalcogens O2(tBu)2, S2Me2, S2(pTol)2, Se2Ph2, and... 
Dichalcogen activation | Boron | Arylborane | Adduct equilibrium | Main-group ambiphile | ANIONS | CHEMISTRY, ORGANIC | LEWIS PAIR CHEMISTRY | SULFUR | 1,3,2,5-DIAZADIBORININE | DIBORANE | PLATFORM | DIHYDROGEN | POLYCYCLIC AROMATICS | NITROGEN | Organoboranes
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2018, Volume 54, Issue 65, pp. 9015 - 9018
A carbene-stabilised neutral boryl radical and a boryl anion are isolated via selective one- and two-electron reduction of a diamidocarbene (DAC) adduct of... 
BORYL ANION | TRIARYLBORON ANIONS | BORON-STABILIZED CARBANION | TRIMESITYLBORON | REACTIVITY | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANE | 1,3,2,5-DIAZADIBORININE | RADICAL-ANION | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 46, pp. 14450 - 14454
Stabilized borylenes (L2BH:) with weakly π‐accepting substituents L, such as phosphines, were previously believed to be unstable. In the current manuscript, we... 
iron | pincer ligands | reduction | boron | density functional theory | ACTIVATION | TRANSITION-METAL-COMPLEXES | CATALYTIC-HYDROGENATION | OXIDATIVE ADDITION | 1,3,2,5-DIAZADIBORININE | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | DIMETALLOBORYLENE COMPLEX | METALLABORATRANES | TRIMETHYLPHOSPHINE | Density functionals | Ligands | Boron
Journal Article
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