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1,3-diol acetonides (273) 273
chemistry, organic (261) 261
stereochemistry (89) 89
index medicus (86) 86
aldehydes (72) 72
chemistry, multidisciplinary (56) 56
stereoisomerism (49) 49
organic-synthesis (46) 46
stereoselective synthesis (44) 44
molecular structure (42) 42
stereoselective-synthesis (41) 41
alcohols (39) 39
1,3-diol (37) 37
chemistry (37) 37
ketones (37) 37
reduction (37) 37
aldol reactions (34) 34
synthesis (34) 34
asymmetric-synthesis (30) 30
anti 1,3-diol monoesters (29) 29
research (29) 29
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enantioselective synthesis (27) 27
analysis (25) 25
beta-hydroxy ketones (25) 25
chemical properties (22) 22
lactones (22) 22
aldol reaction (21) 21
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acid (18) 18
macrolides - chemical synthesis (18) 18
animals (17) 17
stereocontrolled synthesis (17) 17
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secondary alcohols (15) 15
chemical synthesis (14) 14
derivatives (14) 14
macrolides - chemistry (14) 14
chemistry, physical (13) 13
k ee chemistry, organic (13) 13
letter (13) 13
polypropionate synthesis (13) 13
porifera - chemistry (13) 13
ring-closing metathesis (13) 13
article (12) 12
asymmetric synthesis (12) 12
chemistry, inorganic & nuclear (12) 12
olefin metathesis (12) 12
oxidation (12) 12
aldehydes - chemistry (11) 11
conversion (11) 11
lactones - chemical synthesis (11) 11
polyols (11) 11
1,3-asymmetric induction (10) 10
aldol-tishchenko reaction (10) 10
analogs (10) 10
antineoplastic agents - chemical synthesis (10) 10
beta-hydroxyketones (10) 10
chemistry, medicinal (10) 10
lactones - chemistry (10) 10
magnetic resonance spectroscopy (10) 10
pi-face selectivity (10) 10
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2-directional chain synthesis (9) 9
acyclic stereoselection (9) 9
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alcohols - chemistry (8) 8
amphotericin-b (8) 8
antibiotics (8) 8
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ethers (8) 8
homoallylic alcohols (8) 8
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alkenes - chemistry (7) 7
allylic alcohols (7) 7
amides - chemical synthesis (7) 7
chondromyces-crocatus (7) 7
construction (7) 7
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diastereoselective reduction (7) 7
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Tetrahedron Letters, ISSN 0040-4039, 2006, Volume 47, Issue 26, pp. 4397 - 4401
The scope of the Prins cyclisation, the higher stereoselective synthesis of multisubstituted tetrahydropyrans from aldehydes and homoallylic alcohols, is... 
Polyketide | 1,3-Diol | Prins cyclisation | Tetrahydropyrans | LEUCASCANDROLIDE-A | KEY STEP | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | polyketide | SEDUM ALKALOIDS | CHEMISTRY, ORGANIC | 1,3-diol | SEDAMINE | DIASTEREOSELECTIVE SYNTHESIS | ALLYLIC ALCOHOLS | tetrahydropyrans | ANODIC-OXIDATION | Polyketides
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 03/2015, Volume 13, Issue 12, pp. 3575 - 3584
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2017, Volume 58, Issue 25, pp. 2465 - 2467
Journal Article
Tetrahedron, ISSN 0040-4020, 05/2016, Volume 72, Issue 19, pp. 2481 - 2490
Two iterative vinylogous Mukaiyama aldol reactions (VMAR) have been applied in order to selectively install three contiguous stereocenters at C37, C38 and C39,... 
Aldol | Lagunamide A | Mukaiyama | Vinylogous | ACID-DERIVATIVES | E,E-VINYLKETENE SILYL N,O-ACETAL | CHEMISTRY, ORGANIC | 1,3-DIOL ACETONIDES | DEPSIPEPTIDES | CYANOBACTERIUM LYNGBYA-MAJUSCULA | KHAFREFUNGIN | Southern Hemisphere | Synthesis (chemistry) | Synthesis | Asymmetry | Strategy | Segments | Aldehydes | Fragmentation
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 03/2009, Volume 15, Issue 12, pp. 2874 - 2914
Journal Article
Organic Letters, ISSN 1523-7060, 05/2011, Volume 13, Issue 9, pp. 2506 - 2509
Hoiamide C was synthesized in 16 steps with an overall yield of 1.8% starting from homoallylic alcohol 18, unambiguously confirming its structure. 
OXIDATION | ALCOHOLS | REAGENT | STEREOISOMERS | POLYPROPIONATE | CYANOBACTERIA | ACIDS | CHEMISTRY, ORGANIC | 1,3-DIOL ACETONIDES | TRIACETOXYBOROHYDRIDE | ALDEHYDES | Molecular Structure | Stereoisomerism | Esters - chemical synthesis | Lipopeptides - chemical synthesis | Index Medicus
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 09/2017, Volume 82, Issue 17, pp. 9191 - 9197
The total synthesis and structural revision of (+)-cryptoconcatone H are described. Guided by computational studies for the final structure assignment, the... 
NMR | COMPLEX | ABSOLUTE-CONFIGURATION | ALCOHOL | CARBONYL ALLYLATION | ASSIGNMENT | CHEMISTRY, ORGANIC | 1,3-DIOL ACETONIDES | STEREOSELECTIVE-SYNTHESIS | ACETATE | OXIDATION LEVEL | Allylic compounds | Synthesis | Asymmetric induction (Stereochemistry) | Research | Chemical properties | Organic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2016, Volume 138, Issue 22, pp. 7130 - 7142
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2018, Volume 2018, Issue 25, pp. 3352 - 3364
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2018, Volume 59, Issue 2, pp. 160 - 162
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2017, Volume 58, Issue 28, pp. 2685 - 2689
A convergent and stereoselective approach for the synthesis of C1-C11, C12-C22, and C23-C28 fragments of cytotoxic natural products cruentaren A and B are... 
Resorcylic acid lactones | Alder-Rickert reaction | Sharpless epoxidation | Pirrung-Heathcock’s aldol | Pirrung-Heathcock's aldol | METABOLITES | RADICICOL | MACROLIDE | CHEMISTRY, ORGANIC | ALCOHOLS | INHIBITION | BYSSOVORAX-CRUENTA | CHEMISTRY | 1,3-DIOL ACETONIDES | STEREOCHEMICAL ASSIGNMENT | Synthesis | Organic compounds | Butylene | Lactones
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2018, Volume 59, Issue 30, pp. 2893 - 2895
A stereoselective approach for the total synthesis of lactone (5 ,7 ,9 )-7,9-dihydroxy-5-decanolide is described. The sequence of synthetic reactions involves... 
Bartlett–Smith halocyclization | Oxidative lactonization | Total synthesis | Lactones | ALKOXY ALDEHYDES | STEREOCHEMISTRY | PROTOCOL | CHEMISTRY, ORGANIC | 1,3-DIOL ACETONIDES | DIACETATE | Bartlett-Smith halocyclization
Journal Article
Organic Letters, ISSN 1523-7060, 03/2005, Volume 7, Issue 7, pp. 1303 - 1305
A total synthesis of (+)-peloruside A has been successfully achieved. The strategy was highlighted by a late stage aldol coupling of two complex fragments... 
AGENT | CHEMISTRY, ORGANIC | MACROLIDE PELORUSIDE-A | 1,3-DIOL ACETONIDES | SEGMENT | Lactones - chemical synthesis | Animals | Cyclization | Stereoisomerism | Molecular Structure | Porifera - chemistry | Bridged Bicyclo Compounds, Heterocyclic - chemical synthesis | Index Medicus
Journal Article
Heterocycles, ISSN 0385-5414, 2015, Volume 90, Issue 1, pp. 579 - 599
A stereocontrolled synthesis of the C13-C29 segment of amphidinolide N, a marine macrolide natural product that is extremely potent cytotoxic, is described. 
Total Synthesis | REDUCTION | TETRAHYDROFURANS | Marine Dinoflagellate | CARIBENOLIDE-I STRUCTURES | ASYMMETRIC EPOXIDATION | DINOFLAGELLATE | CHEMISTRY, ORGANIC | 1,3-DIOL ACETONIDES | Macrolide | METATHESIS | Amphidinolide N
Journal Article
Organic Letters, ISSN 1523-7060, 03/2013, Volume 15, Issue 6, pp. 1338 - 1341
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 02/2016, Volume 2016, Issue 6, pp. 1215 - 1226
The convergent total synthesis of Sch725674 has been accomplished by starting from ( R )‐1,2‐epoxyheptane and assembling five modules in a highly... 
Asymmetric synthesis | Macrocycles | Natural products | Hydrolytic kinetic resolution | Metathesis | STRATEGY | STEREOCHEMISTRY | LIBRARY | CHEMISTRY, ORGANIC | OLEFIN METATHESIS | ORIENTED SYNTHESIS | MACROLACTONES | ASSIGNMENT | 1,3-DIOL ACETONIDES | GLOEOSPORONE | Explosives | Synthesis | Enantiomers | Organic compounds
Journal Article
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