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Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 35, pp. 12290 - 12294
We report the direct production of 1,3‐butadiene from the dehydration of 2,3‐butandiol by using alumina as catalyst. Under optimized kinetic reaction... 
catalysis | alumina | dehydration | 1,3-butadiene | 2,3-butanediol | 3-butanediol | 3-butadiene | CONVERSION | BIOMASS | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS | Petroleum chemicals industry | Butadiene | Butanediol | Aluminum oxide | Catalysts | Methyl ethyl ketone | Reaction kinetics | Amphoterics | Selectivity | Catalysis | Dehydration
Journal Article
Catalysis Communications, ISSN 1566-7367, 03/2014, Volume 48, pp. 1 - 4
Vapor-phase catalytic dehydration of 2,3-butanediol was investigated over metal oxides such as CeO , La O , Yb O , ZrO , Al O , TiO , ZnO, Fe O , NiO, and Cr O... 
Monoclinic ZrO | 3-Buten-2-ol | 2,3-Butanediol | Dehydration
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 02/2015, Volume 491, pp. 163 - 169
Journal Article
Catalysis Today, ISSN 0920-5861, 02/2019, Volume 323, Issue -, pp. 62 - 68
[Display omitted] •Rare hearth phosphates are efficient catalysts for 2,3 butanediol dehydration.•Catalysts are stable and lead to 58% selectivity to butadiene... 
Rare earth phosphates | Dehydration | 2,3-Butanediol | 3-buten-2ol | Butadiene | ENGINEERING, CHEMICAL | CHEMISTRY, PHYSICAL | CHEMISTRY, APPLIED | 3-BUTEN-2-OL | Catalysis | Environmental and Society | Chemical Sciences | Environmental Sciences
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 02/2017, Volume 531, pp. 21 - 28
[Display omitted] •Vapor-phase dehydration of C4 unsaturated alcohols to 1,3-butadiene were performed.•1,3-Butadiene selectivity of 97.1 and 93.4% over... 
Ag-modified SiO2/Al2O3 | 1,3-Butadiene | Catalytic deactivation | C4 unsaturated alcohols | Ag-modified SiO | Al | 2,3-BUTANEDIOL DEHYDRATION | SILICA-ALUMINA | CONVERSION | DIMETHYL ETHER | CHEMISTRY, PHYSICAL | RARE-EARTH-OXIDES | ENVIRONMENTAL SCIENCES | CHEMICALS | 1,3-BUTANEDIOL | CEO2 | SELECTIVE DEHYDRATION | CATALYTIC DEHYDRATION | Dehydration (Physiology) | Butadiene
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 01/2019, Volume 570, pp. 148 - 163
Journal Article
Catalysis Communications, ISSN 1566-7367, 03/2014, Volume 48, pp. 1 - 4
Vapor-phase catalytic dehydration of 2,3-butanediol was investigated over metal oxides such as CeO2, La2O3, Yb2O3, ZrO2, Al2O3, TiO2, ZnO, Fe2O3, NiO, and... 
Monoclinic ZrO2 | 3-Buten-2-ol | Dehydration | 2,3-Butanediol | CHEMISTRY, PHYSICAL | 1,4-BUTANEDIOL | ALCOHOLS | DIOLS | SURFACE | CERIA | CEO2 | SELECTIVE DEHYDRATION | EARTH-OXIDE CATALYSTS
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 02/2016, Volume 511, pp. 156 - 167
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 01/2017, Volume 530, pp. 66 - 74
[Display omitted] •Vapor-phase dehydration of 2,3-butanediol was studied over modified monoclinic ZrO2.•3-Buten-2-ol was preferentially formed over BaO/ZrO2... 
Monoclinic ZrO2 | Alkaline earth metal oxides | 3-Buten-2-ol | Dehydration | Ca-O-Zr hetero-linkage | 2,3-Butanediol | Monoclinic ZrO | METHYL ETHYL KETONE | CHEMISTRY, PHYSICAL | STEREOSELECTIVE SYNTHESES | CO2 CAPTURE | REARRANGEMENT | ENVIRONMENTAL SCIENCES | TEMPERATURE | CITRATE PROCESS | 1,3-BUTADIENE | ZEOLITE CATALYSTS | SELECTIVE DEHYDRATION | EPOTHILONE-A
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 04/2019, Volume 575, pp. 48 - 57
[Display omitted] •Vapor-phase dehydration of butanediols was studied over Y-stabilized ZrO2 catalysts with tetragonal phase.•Unsaturated alcohols were... 
Tetragonal phase | Unsaturated alcohols | Dehydration | Butanediols | Yttria-stabilized zirconia | CHEMISTRY, PHYSICAL | 1,4-BUTANEDIOL | ADSORPTION | 3-BUTEN-1-OL | ENVIRONMENTAL SCIENCES | CONDUCTIVITY | 1,3-BUTANEDIOL | 2,3-BUTANEDIOL | PROPYLENE | SELECTIVE DEHYDRATION | EFFICIENT | Zirconium | Zirconium oxide | Catalysts | Analysis | Butanediol | Alcohols
Journal Article
Journal of Catalysis, ISSN 0021-9517, 03/2015, Volume 323, pp. 85 - 99
[Display omitted] •A noble type of dehydration-producing epoxides from vicinal diols is reported.•A Cs/SiO2 catalyst was exceptionally effective for this type... 
Vicinal diols | Dehydrative epoxidation | Dehydration | Biomass conversion | Supported alkali metal oxide | ALKALI-METAL OXIDES | CONVERSION | CHEMISTRY, PHYSICAL | ELASTIC BAND METHOD | PROTON AFFINITIES | ADSORPTION | ENGINEERING, CHEMICAL | BIOMASS | CESIUM | 2,3-BUTANEDIOL | LEWIS-ACID SITES | SILICA
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 07/2018, Volume 562, pp. 11 - 18
[Display omitted] •Vapor-phase dehydration of 3-buten-1-ol and 1,4-butanediol was performed over rare earth oxides.•Heavy rare earth oxides were effective for... 
1,4-Butanediol | 1,3-Butadiene | Yb2O3 | 3-Buten-1-ol | Rare earth oxides | 2,3-BUTANEDIOL DEHYDRATION | PHASE CATALYTIC DEHYDRATION | PHOSPHATE CATALYST | UNSATURATED ALCOHOLS | CHEMISTRY, PHYSICAL | 3-BUTEN-2-OL | ENVIRONMENTAL SCIENCES | 1,3-BUTANEDIOL | Propylene | Petroleum chemicals industry | Isomerization | Butadiene | Butanediol | Aluminum oxide
Journal Article
Applied Catalysis A: General, ISSN 0926-860X, 2014, Volume 487, pp. 226 - 233
Vapor-phase catalytic dehydration of 2,3-butanediol (2,3-BDO) was investigated over several metal oxides loaded on well-crystallized monoclinic ZrO . In the... 
Monoclinic ZrO | 3-Buten-2-ol | 2,3-Butanediol | Unsaturated alcohol | Dehydration | Supported alkaline-earth oxides | Base-acid concerted sites | CHEMISTRY, PHYSICAL | 1,4-BUTANEDIOL | BASE | ALCOHOLS | ENVIRONMENTAL SCIENCES | Monoclinic ZrO2 | CEO2 | EARTH-OXIDE CATALYSTS | EFFICIENT | 1,5-PENTANEDIOL
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 09/2017, Volume 546, pp. 96 - 102
[Display omitted] •Dehydration of 1,5-pentanediol was investigated over modified monoclinic ZrO2 at 400°C.•Stable catalytic activity of MgO/ZrO2 was observed... 
Modified monoclinic ZrO2 | Dehydration | 1,5-Pentanediol | 4-Penten-1-ol | MgO supported | Modified monoclinic ZrO | HYDROGENOLYSIS | ZIRCONIA | CHEMISTRY, PHYSICAL | 1,4-BUTANEDIOL | 3-BUTEN-1-OL | ALCOHOLS | CAO | ENVIRONMENTAL SCIENCES | 2,3-BUTANEDIOL | SELECTIVE DEHYDRATION | EARTH-OXIDE CATALYSTS | METAL-OXIDES
Journal Article
Chemistry Letters, ISSN 0366-7022, 7/2016, Volume 45, Issue 7, pp. 831 - 833
We investigated the catalyst that promotes the selective dehydration of 2,3-butanediol to 1,3-butadiene. We found that the SiO2-supported CsH2PO4 catalyst... 
Catalytic conversion | 2,3-Butanediol | Bio-based 1,3-butadiene | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Engineering Research and Design, ISSN 0263-8762, 07/2017, Volume 123, pp. 268 - 276
•We present a novel process for recovery of BD and MEK from BDO dehydration.•Purities of BD and MEK are very high over 99%.•Recovery rate of BD and MEK are... 
Process design | 1,3-Butadiene | Dehydration | 2,3-Butanediol | Methyl ethyl ketone | Azeotropic-distillation column | ENGINEERING, CHEMICAL | PATHWAY | FERMENTATION
Journal Article
Petroleum Chemistry, ISSN 0965-5441, 3/2016, Volume 56, Issue 3, pp. 230 - 236
2,3-Butanediol as a product of biomass processing is a cheap alternative raw material for synthesis of methyl ethyl ketone (MEK) and butadiene-1,3. The... 
butadiene | Chemistry | methyl ethyl ketone | zeolites | Lewis sites | Brönsted sites | 2,3-butanediol | Zr-BEA | Industrial Chemistry/Chemical Engineering | TRANSFORMATION | Bronsted sites | GLYCEROL | ACIDS | ENERGY & FUELS | CHEMISTRY, ORGANIC | CHEMISTRY, PHYSICAL | ENGINEERING, PETROLEUM | BETA | ENGINEERING, CHEMICAL | SITES | Catalysts | Butanediol | Esters | Zeolites | Butadiene | Production processes | Aluminum oxide
Journal Article
by Song, D and Yoon, YG and Seo, SK and Lee, CJ
PROCESSES, ISSN 2227-9717, 07/2019, Volume 7, Issue 7, p. 410
This study was performed to investigate the extractive distillation for 1,3-butadiene (1,3-BD) purification as a part of the 2,3-butanediol (2,3-BDO)... 
ENGINEERING, CHEMICAL | RECOVERY | METHYL ETHYL KETONE | 1-butene | 2,3-butanediol dehydration | distillation | economic feasibility | extractive distillation | CONCEPTUAL DESIGN | CATALYTIC DEHYDRATION | 1,3-butadiene | BUTADIENE PRODUCTION
Journal Article